Dielectric ultrasonic properties

The presence of hydrogen bonding in water is shown by its anomalous thermophysical properties and has been confirmed by more recent methods of investigating its structure such as NMR, neutron scattering, dielectric relaxation, ultrasonic absorption,... 

Barium titanate has many important commercial apphcations. It has both ferroelectric and piezoelectric properties. Also, it has a very high dielectric constant (about 1,000 times that of water). The compound has five crystalline modifications, each of which is stable over a particular temperature range. Ceramic bodies of barium titanate find wide applications in dielectric amplifiers, magnetic amplifiers, and capacitors. These storage devices are used in digital calculators, radio and television sets, ultrasonic apparatus, crystal microphone and telephone, sonar equipment, and many other electronic devices. 

Hinrichs and Thuen [28] used ultrasonic attenuation to determine the proper time for pressure application during an otherwise traditional pre-established cure cycle. Because dielectric is an electrical property, it is influenced by moisture content and temperature as well as viscosity, so it may vary quantitatively. Ultrasonic measurements are also affected by other parameters (i.e., void content), but they are a mechanical measurement rather than an electric one. The ultrasonic sensors used by Hinrichs unfortunately were less reliable than the dielectric sensors. 

Non-destructive methods include holographic interferometry, resistance transducers, stress-sensitive covers, and other similar techniques. In practice, the following physical methods of non-destructive monitoring of residual stresses are commonly used X-ray diffraction, measurement of dielectric properties, and ultrasonic control. The main purpose of these methods is to monitor the structural transformations or distortions taking place as a result of residual stresses and local deformations. However, the application of methods such as X-ray diffraction to measure distortions in unit cel dimensions, ultrasonics to measure elastic wave propagation velocities, etc., all encounter numerous experimental problems. Therefore, in ordinary laboratory conditions only quantitative estimations of residual stresses can be obtained. 

The study of molecular interactions in liquid mixtures is of considerable importance in the elucidation of the structural properties of molecules. Interactions between molecules influence the structural arrangement and shape of molecules. Dielectric relaxation of polar molecules in non-polar solvents using microwave absorption has been widely employed to study molecular structures and molecular interactions in liquid mixtures [81]. Ever since Lagemann and Dunbar developed a US velocity approach for the qualitative determination of the degree of association in liquids [82], a number of scientists have used ultrasonic waves of low amplitude to investigate the nature of molecular interactions and the physico-chemical behaviour of pure liquids and binary, ternary and quaternary liquid mixtures, and found complex formation to occur if the observed values of excess parameters (e.g. excess adiabatic compressibility, intermolecular free length or volume) are negative. These parameters can be calculated from those for ultrasonic velocity (c) and density (p). Thus,... 

Many studies have been performed on optical properties of doped fluoroperovskite lattices searching for new tunable lasers. Dielectric-loss and ultrasonic measurements on KZnFs Li have revealed that the Li+ impurity sits in a <100> off-centre position approximately 0.15 A from a normal K+ site [234]. In the case of Cu in the cubic KMgp3 lattice, from the temperature dependence of the absorption spectra and from MCD measurements a clear indication of the off-centre configuration of Cu ion replacing a K+ ion was obtained [235]. 

Peercy PS, Fritz IJ, Samara GA (1975) Temperature and pressure dependences of the properties and phase transition in paratellurite (Te02) ultrasonic, dielectric and Raman and Brillouin scattering results. J Phys Chem Solids 36 1105-1122... 

Chief among the interfacial properties of aqueous systems that suggest the occurrence of thermal anomalies are the following index of refraction, density, activation energy for ionic conductance, rates of surface reactions, surface tension, surface potentials, membrane potentials, heats of immersion, zeta potentials, rate of nucleation, viscous flow, ion activities, proton spin lattice relaxation times, optical rotation, ultrasonic velocity and absorption, sedimentation rates, coagulation rates, and dielectric properties. 

Convection of heat via blood depends primarily on the local blood flow in the tissue and the vascular morphology of the tissue. Thermal diffusion is determined by thermal conductivity in the steady state, and thermal diffusivity in the unsteady state. In addition to these transport parameters, we need to know the volumes and geometry of normal tissues and tumor. In general, tumor volume changes as a function of time more rapidly than normal tissue volume. In special applications, such as hyperthermia induced by electromagnetic waves or radiofrequency currents, we need electromagnetic properties of tissues—the electrical conductivity and the relative dielectric constant. In the case of ultrasonic heating, we need to specify the acoustic properties of the tissue—velocity of sound and attenuation (or absorption) coefficient. 

I. Equilibrium Physical Properties, II. Dielectric and Ultrasonic Relaxation Studies," Polymer, 28... 

Li Z, Grimsditch M, Xu X, Chan SK (1993) The elastic, piezoelectric and dielectric constants of tetragonal PbTiOs single crystals. Ferroelectrics 141 313-325 MarraSP, Ramesh KT, Douglas AS (1999) The Mechanical properties of lead-titanate/polymer 0-3 composites. Compos Sci Technol 59 2163-2173 Materials Data Sheets of APC International, Tokin, Ferroperm, Morgan Matroc, Siemens Mattiat OE (1971) Ultrasonic transducer materials. Plenum Press, Tokyo McLachlan DS, Blaszkiewicz M, Newnham RE (1990) Electrical resistivity of composites. J Am Ceram Soc 73 2187-2203... 

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