Dialkyl Sulphides determination

Franklin and Lumpkinhave used the indirect electron pact method to determine heats of formation of the radicals CH S, CgHgS, and SH. To determine /Ji3 (RS, g) they measured the appearance potential of the RS+ ion by the bombardment firstly of the dialkyl sulphide, and secondly of the dialkyl disulphide., which dissociate according to the equations... 

Kinetic parameters for the reaction of [Pt(bipy)Cl2] with diethyl sulphide were obtained in the work described in the previous paragraph, as necessary information for the comparisons with bidentate N- and S-bonding ligands. Rate constants and activation parameters for the reactions of [Pt(dien)X]+, where X = Cl, Br, or I, with dialkyl sulphides have also been determined. These results may be compared with known kinetic parameters for reactions of uncharged platinum(n) complexes with thioethers. The reactions of... 

Gas chromatography has been applied to the determination of a wide range of organic compounds in trade effluents including the following types of compounds which are reviewed in Table 15.15 aromatic hydrocarbons, carboxylic acids aldehydes, non ionic surfactants (alkyl ethoxylated type) phenols monosaccharides chlorinated aliphatics and haloforms polychlorobiphenyls chlorlignosulphonates aliphatic and aromatic amines benzidine chloroanilines chloronitroanilines nitrocompounds nitrosamines dimethylformamide diethanolamine nitriloacetic acid pyridine pyridazinones substituted pyrrolidones alkyl hydantoins alkyl sulphides dialkyl suphides dithiocaibamate insecticides triazine herbicides and miscellaneous organic compounds. 

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