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Density of photonic states

Simultaneous account for local field and local density of photon states enhancements in close proximity to a silver ellipsoidal nanopaiticle is found to provide up to 10 -fold Raman scattering cross-section rise up. A model of the so-called hot points in surface enhanced spectroscopy has been elaborated as local areas with high Q-factor at incident and scattered (emitted) light frequencies. Further experiments are proposed towards verification of the model in terms of transient Raman experiments to clarify incident field enhancement and scanning near-field optical mapping of local density of photon states. [Pg.164]

However there is yet another enhancement factor, namely local density of photon states effect on Raman scattering rate in mesoscopic structures including metal nanobodies as a particular example [5]. Indeed, Raman scattering rate / (number of scattered photons per second) can be written as the product of three terms... [Pg.164]

In this paper, we report on simultaneous consideration of incident field enhancement and local density of photon states enhancement near a metal particle with spherical shape as a reasonable primary model for single molecule Raman spectroscopy. Joint action of these two factors at the same point of space is found to offer up to lO -fold enhancement of Raman scattering rate. To the best of our knowledge this is the first evidence that consistent theory of single molecule Raman spectroscopy and comprehensive description of so-called hot points in surface enhanced spectroscopies can be constructed without necessarily involvement of chemical mechanisms. [Pg.165]

It was shown recently that the relative density of photonic states (photonic DOS) and the atom-vacuum-field coupling, respectively, near CNs effectively... [Pg.32]

This form for the free energy is valid when the dispersion relation is written in a form where >l-).oo(5, icon) = 1. The function p(q) is the density of photon states in momentum space", which in our derivation for transparent media, can... [Pg.146]

In Equation 6.33, there is a sum over the zero-photon excited states a (after radiative decay) as well as a sum over the polarization e and an integration over the direction Q t of the emitted photon. Qph(rfc) is the density of photon states. F( ) is generally nondiagonal, as will be illustrated in the next section. In the ills, tpj representation however, it is easy to verify from Equation 6.15 that... [Pg.137]

Valence Band Spectroscopy. Optical and electronic properties of UPD metal flms on metal electrodes have been studied in situ by means of differential- and electroreflectance spectroscopy [98], Optical absorption bands, however, reflect a combined density of electronic states at a photon energy which is the energetic difference of... [Pg.115]

Experimental data can be obtained by ultra-violet absorption spectroscopy, electron energy loss spectroscopy and photoelectron spectroscopy. UV absorption and EELs have been described briefly in Chapter 3. The former provides information only about the band-gap, while EELs gives more general information about the conduction bands. Both X-rays and UV photons can be used to generate photoelectrons these two methods are given the acronyms XPS and UPS. The energy spectrum of the emitted electrons provides information about the density of electron states in the valence bands. In principle the size of the band gap can be obtained, but care must be taken as the absolute energy... [Pg.143]

The electronic state of the switch is often read by using optical transient absorption and fluorescence emission spectroscopies. Fluorescence is a much more sensitive technique, and can be used even at the single molecule level. It also requires a much smaller density of photons to provide a stable signal however, very few charge-separated ion pair states exhibit radiative charge recombination. In these cases transient absorption is often used because it allows direct nondestructive observation of a molecule s electronic configuration. Problems with this technique... [Pg.3223]

The following restrictions have been found to the application of coupled-channel calculations for the computation of pulsed-laser ionization. The dipole approximation restricts the photon energy to < 1 keV in the current treatment. This, however, does not pose a strict condition since a partial-wave expansion of the laser field may be used, similar to as in the case of screened Coulomb potentials. In comparison to ion/atom collisions, typical photon/atom interaction times are extremely long. An upper limit of the pulse width AZp = 100 fs at intermediate laser-power densities follows from the numerically restricted density of continuum states. [Pg.32]

Photon beams incident on surfaces induce vibrational excitation of adsorbed molecules at low energies fin the meV ( 10 J) range). Photoemission of electrons from the valence band [the 5-30 eV (8-48 x 10 J) range] yields the surface density of electronic states. Photoemission of electrons from inner shells (30-104... [Pg.382]


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See also in sourсe #XX -- [ Pg.353 ]




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