DEFLAGRATION TO DETONATION

Deflagration to Detonation Transition A reaction front that starts out with velocities below the speed of sound and subsequently accelerates to velocities higher than the speed of sound in the unreacted material is said to have undergone a Deflagration to Detonation Transition. The possibility of transition is enhanced by confinement/turbulence generators in the path of the reaction front. 

If a large amount of a volatile flammable material is rapidly dispersed to the atmo vapor cloud forms. If this cloud is ignited before the cloud is diluted below its lower flammability limit, a UVCE occurs which can damage by overpressure or by thermal radiation. Rarely are UVCEs detonations it is believed that obstacles, turbulence, and possibly a critical cloud size are needed to transition from deflagration to detonation. 

An in-line detonation flame arrester must be used whenever there is a possibility of a detonation occurring. This is always a strong possibility in vent manifold (vapor collection) systems, where long pipe runs provide sufficient run-up distances for a deflagration-to-detonation transition to occur. Figure 3-3 shows the installation of in-line arresters of the detonation type in a vent manifold system. 

Deflagration-to-Detonation Transition (DDT) The transition phenomenon resulting from the acceleration of a deflagration flame to detonation via flame-generated turbulent flow and compressive heating... 

Lee, J. H. S., and I. O. Moen. 1980. The mechanism of transition from deflagration to detonation in vapor cloud explosions. Prog. Energy Combust. Sci. 6 359-389. 

Although the status of many 3D codes makes it possible to carry out detailed scenario calculations, further work is needed. This is particularly so for 1) development and verification of the porosity/distributed resistance model for explosion propagation in high density obstacle fields 2) improvement of the turbulent combustion model, and 3) development of a model for deflagration to detonation transition. More data are needed to enable verification of the model in high density geometries. This is particularly needed for onshore process plant geometries. 

VI. Preparation VII. Detonation Characteristics VIII. Thermal Decomposition IX. Combustion DDT (deflagration-to-detonation transition) X. References. The major emphasis will be placed on Sections VII, VIII and IX... 

Macek (Ref 5) used Pentolite (and DINA) to study the transition from deflagration to detonation (DDT). He found that in Pentolite,... 

Detonation in SP is initiated by shock or by DDT (deflagration to detonation transition). Let us first examine shock initiation, ie, initiation by in-contact or close-by detonation of HE... 

In 1957, a flame propagating in a long tube under conditions resulting in a deflagration to detonation transition (DDT) was given the name "tulip" by Salamandra et al. [7]. This term was subsequently commonly applied in detonation studies to describe this typical shape [8,9]. Figure 5.3.2 shows a few... 

The transition of deflagration to detonation in mixtures was studied with respect to mixing ratio, pressure and spark energy [1], A study of TNT equivalences in propylene oxide fuel/air explosives is made [2],... 

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