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Decenes 1-decene

Butene-1 Hexene-1 Octene-1 Decene-1 decene-1 decene-1 decene-1 (lecene-1 ... [Pg.311]

DECENE, 1-DECENE, or a-DECENE (872-05-9) Forms explosive mixture with air (flash point 128°F/50°C). Violent reaction with strong oxidizers, bromine, perchlorates, per-chromates, pyridinium perchlorate, peroxyacetic acid, peroxybenzoic acid. Incompatible with strong acids. [Pg.377]

CCRIS 5718 a-Decene 1-Decene 1-n-Decene Dec-1-ene Decene, n- Decylene Dialene 10 EINECS 212-819-2 Gulftene 10 HSDB 1073 Neodene 10 NSC 62122. Used as an intermediate in the manufacture of biodegradable surfactants and specialty industrial chemicals. Liquid mp = -66.3" bp = 170-171" d = 0.7408 insoluble in H2O, freely soluble in EtOH, Et20. Shell UK Shell... [Pg.179]

In a lOOmL round-bottomed flask fitted with a magnetic stirrer is placed a mixture of palladium (II) chloride (89mg, O.Smmol), p-benzoquinone (5.94g, 55mmol) and 7 1 dimethylformamide/water (20mL). To the solution, t-decene [substitute safrole for this compound) (7.0g, 50mmc4) is added in 10 min and the mixture is stirred at room temperature for 7h. The solution is poured into cold 3 normal hydrochloric acid (lOOmL) and extracted with 5 portions of ether. The extracts are combined and washed with three portions of 10% aqueous sodium hydroxide solution and a portion of brine, and then dried After removal of the solvent, the residue is distilled to give 2-decanone [P2P] yield 6.1g (78%). [Pg.73]

In contrast to oxidation in water, it has been found that 1-alkenes are directly oxidized with molecular oxygen in anhydrous, aprotic solvents, when a catalyst system of PdCl2(MeCN)2 and CuCl is used together with HMPA. In the absence of HMPA, no reaction takes place(100]. In the oxidation of 1-decene, the Oj uptake correlates with the amount of 2-decanone formed, and up to 0.5 mol of O2 is consumed for the production of 1 mol of the ketone. This result shows that both O atoms of molecular oxygen are incorporated into the product, and a bimetallic Pd(II) hydroperoxide coupled with a Cu salt is involved in oxidation of this type, and that the well known redox catalysis of PdXi and CuX is not always operalive[10 ]. The oxidation under anhydrous conditions is unique in terms of the regioselective formation of aldehyde 59 from X-allyl-A -methylbenzamide (58), whereas the use of aqueous DME results in the predominant formation of the methyl ketone 60. Similar results are obtained with allylic acetates and allylic carbonates[102]. The complete reversal of the regioselectivity in PdCli-catalyzed oxidation of alkenes is remarkable. [Pg.30]

Furthermore, treatment of the aminopalladation product with bromine affords aziridines[176]. The aziridine 160 was obtained stereoselectively from methylamine and 1-decene in 43% yield. The aminopalladation of PdCl2 complexes of ethylene, propylene, and 1-butene with diethylamine affords the unstable ir-alkylpalladium complex 161, which is converted into the stable chelated acylpalladium complex 162 by treatment with CO[177],... [Pg.43]

Acid catalyzed hydration converts alkenes to alcohols with regioselectivity according to Markovnikov s rule Frequently however one needs an alcohol having a structure that corresponds to hydration of an alkene with a regioselectivity opposite to that of Markovnikov s rule The conversion of 1 decene to 1 decanol is an example of such a transformation... [Pg.250]

There is a pronounced tendency for boron to become bonded to the less substituted car bon of the double bond Thus the hydrogen atoms of diborane add to C 2 of 1 decene and boron to C 1 This is believed to be mainly a steric effect but the regioselectivity of addition does correspond to Markovmkov s rule m the sense that hydrogen is the neg atively polarized atom m a B—H bond and boron the positively polarized one... [Pg.251]

Write a series of equations showing how to prepare cis 5 decene from acetylene and 1 bromobutane as the source of all its carbons using any nec essary organic or inorganic reagents Hint You may find it helpful to review Sec tion 9 6)... [Pg.375]

One of the mam uses of the linear a olefins prepared by oligomerization of ethylene is in the preparation of linear low density polyethylene Linear low density polyethylene is a copoly mer produced when ethylene is polymerized in the presence of a linear a olefin such as 1 decene [H2C=CH(CH2)7CH3] 1 Decene replaces ethylene at random points in the growing polymer chain Can you deduce how the structure of linear low density polyethylene differs from a linear chain of CH2 units ... [Pg.622]

The a-methylene groups also add to double bonds eg, 1-decene at 160°C gives up to 80% of a-decylbutyrolactone (160). With photochemical initiation similar additions take place at room temperature (161). [Pg.111]


See other pages where Decenes 1-decene is mentioned: [Pg.12]    [Pg.22]    [Pg.6159]    [Pg.6799]    [Pg.242]    [Pg.74]    [Pg.129]    [Pg.23]    [Pg.23]    [Pg.469]    [Pg.250]    [Pg.251]    [Pg.251]    [Pg.251]    [Pg.375]    [Pg.618]    [Pg.618]    [Pg.626]    [Pg.635]    [Pg.783]    [Pg.783]    [Pg.1193]    [Pg.286]    [Pg.402]    [Pg.452]    [Pg.470]    [Pg.500]    [Pg.518]    [Pg.546]    [Pg.589]    [Pg.676]    [Pg.282]    [Pg.779]    [Pg.503]    [Pg.264]    [Pg.245]    [Pg.451]    [Pg.426]    [Pg.427]    [Pg.427]    [Pg.428]    [Pg.430]    [Pg.430]    [Pg.431]    [Pg.432]    [Pg.432]   
See also in sourсe #XX -- [ Pg.54 , Pg.241 ]




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1 Decene

1 Decene

1 Decene hydroboration oxidation

1- Decene dimerization

1-Decene Friedel-Crafts reaction

1-Decene Wacker process

1-Decene benzene alkylation with

1-Decene catalysts, cobalt complexes

1-Decene dihydroxylation

1-Decene metathesis

1-Decene oligomerization

1-Decene oxidation

1-Decene synthesis

1-Decene, double bond migration

1-Decene, epoxidation

1-Decene, reaction with ruthenium

1-Decene, reaction with ruthenium complexes

1-decene biphasic systems

1-decene-1,10-dicarboxylic acid

2-Decen

2-Decen

2-Decen-9-olide

2-Decenal

2-Decenal

4- Methyl-3-decen

5-Decen-2-lactone

9-decen oxidation

Alpha-Decene

Bicyclo decene

Bicyclo decene synthesis

Carbonylation 1-decene

DEC-9-ENYL BROMIDE: 1-DECENE, 10-BROMO

Decanal 2-Decenal

Decane Dehydrogenation into Decene

Decenal (revised)

Decenal, -2-, odor profile

Decenal, -6-, parsley

Decene hydroformylation

Decenes

Decenes

Decenes hydroformylation

Decenes metathesis

Decenes, addition

Decenes, oligomerization

Dimerization of 1-decene

Epoxy-2-decenal

Hydroformylations of 1-decene

L-Decene

Ozonolysis 1-decene

Trans-2-Decene

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