Cyclohexyl ethyl amine

CjH, Cyclohexyl-ethyl-amin Cyclohexyl-diethyl-amin —... 

Benzyl-methyl-amtn Methyl- (2-phenyl-ethyl) -amin Cyclohexyl-methyl-amin Hexyl-methyl-amin... 

AIBN = 2,2 -azobisisobutyronitrile 9-BBN = 9-borabicyclo [3.3.1]nonane Bn = benzyl BOC = f-butoxycarbonyl Bz = benzoyl CAN = ceric anunoninm nitrate Cp = cyclopenta-dienyl Cy = cyclohexyl DAST = diethylaminosnllur trifln-oride DBA = l,3-dibromo-5,5-dttnethylhydantoin DDQ = 2,3-dichloro-5,6-dicyano-l,4-benzoquinone DET = diethyl tartrate DIAD = diisopropyl acetylene dicarboxylate DIBAL-H = diisobutylalummum hydride DIPEA = diisopropyl ethyl amine DMDO = dimethyldioxirane HMPA = hexamethylphosphortriamide EDA = lithium diisopropy-lamide Ms = methylsulfonyl MOM = methoxymethyl NBS = iV-bromosuccmimide NMO = A-methylmorpholine iV-oxide PDC = pyridinium dichromate PMP = p-methoxyphenyl THP = tetrahydropyranyl TIPS = trisiso-propylsilyl TMANO = trimethylamine A-oxide TBDMS = t-butyldimethylsilyl Tf = trifluoromethanesulfonyl TMP = 2,2,6,6-tetramethylpiperidyl TMS = trimethylsilyl Ts = p-toluenesulfonyl. 

BTA-OCHgyBTAB Choline Amines Amines, prim., Alkylamines Methyl-y Ethyl-, Propyl-, Butyl-, tert-Butyl-y Cyclohexyl-, Benzyl-amine... 

Several N-substituted pyrroHdinones eg, ethyl, hydroxyethyl and cyclohexyl, are used primarily in specialized solvent appHcations where their particular physical properties are advantageous. For example, mixtures of l-cyclohexyl-2-pyrroHdinone and water exhibit two phases at temperatures above 50°C below that temperature they are miscible in aH proportions. This phenomenon can be used to facHitate some extractive separations. Mixtures of 1-alkyl-pyrroHdinones that are derived from coconut and taHow amines can be used at lower cost in certain appHcations where they may be used instead of the pure l-dodecyl-2-pyrroHdinone and l-octadecyl-2-pyrroHdinone. 

An Arbuzov reaction of triethyl phosphite with A-chloroamines RNHC1 (R = i-Pr, cyclohexyl or PhCH2), prepared from the corresponding amines and aqueous sodium hypochlorite, leads to the phosphoramides 357 with the elimination of ethyl chloride395. 

The reactions of NP with different aliphatic amines (ethyl-, n-propyl-, n-butyl-, cyclohexyl-, and benzylamines) and amino acids have... 

Other alkylamines can be made in similar fashion from the alcohol and ammonia (Fig. 4). Methyl, ethyl, isopropyl, cyclohexyl, and combination amines have comparatively small markets and are usually made by reacting the correct alcohol with anhydrous ammonia in the vapor phase. 

Hamstoff 3-Cyclohexyl-l-methyl-E4, 354 (H2N-CN + Amin) Hydrazin 2-Cyclohexyliden-l-(2-hydroxy-ethyl)- El6a, 516 (Hydrazon-Bild.)... 

Morpbolin 2,2-Dimethyl-4-ethyl-3-methylen- VI/4, 539 Nitron N-(l-Ethyl-cyclohexyl)-E14b, 1485 (Amin + R —NO)... 

A somewhat different mechanism was deduced by Baker and Bailey 4f) from their own studies of the systems phenyl isocyanate and ethyl p-aminobenzoate (benzocaine) cyclohexyl isocyanate and aniline phenyl isocyanate and aniline p-methoxyphenyl isocyanate and aniline. While Craven postulates one complex. Baker and Bailey assume two complexes of the isocyanate one with the amine, and one with the product urea. 

N-Cyclohexylformamide, prepared by slowly adding ethyl formate to cyclo-hexylamine with stirring and cooling, is an intermediate in an efficient method for conversion of the amine to cyclohexyl isocyanide. ... 

TV-Alkylated heterocyclic compounds can be built up in one operation by treating diol bissulfonates with primary amines. For instance, 1-cyclohexyl-piperidine, b.p. 234°, is obtained in 81% yield from 1,5-pentanediol bis-(benzenesulfonate) and cyclohexylamine, and 4-benzylmorpholine, b.p. 79°/ 2 mm, from 2,2 -oxybis(ethyl benzenesulfonate) and benzylamine.852... 

Halogenated ethers can be equally well dehydrohalogenated by W-ethyldi-(cyclohexyl)amine or ethyldiisopropylamine ethyl vinyl ether and butyl 2-chlorovinyl ether have been prepared in 80-86% yield in this way.59... 

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