3-Methyl 2 cyclohexen

The same authors also reported the dispersion of palladium nanoparticles in a water/AOT/n-hexane microemulsion by hydrogen gas reduction of PdClJ and its efficiency for hydrogenation of alkenes in organic solvents [79]. UV-visible spectroscopy and TEM analysis revealed the formation of Pd nanoparticles with diameters in the range of 4 to 10 nm. Three olefins (1-phenyl-l-cyclohexene, methyl trans-cinnamate, and trans-stilbene) were used as substrates for the catalytic hydrogenation experiments under 1 atm of H2 (Table 9.12). All of the Start-... 

The oxygen scavenging polymer system consists of an oxidizable resin, ethylene methyl acrylate cyclohexene methyl acrylate (EMCM) and a masterbatch containing a photoinitiator and a cobalt... 

Synonyms limonene cajeputene cinene ciene i-methyl-4-(i-methylethenyl)cyclohexene p-mentha-i,8-diene Acintene DP dipentene cyclil decene 4-isopropenyl-i-methyl-cyclohexene Dipenten DL-p-mentha-i.8-diene Eulimen isopropenyl-i-methyl-i-cyclohexene mentha-i,8-diene DL-mentha-i,8-diene menthadiene methyl-4-(i-methyletheny)cyclohexene methyl-4-isopropenyl-i-cyclohexene methyl-4-isopropenylcyclohexene monocyclic terpene hydrocarbons Nesol terpodiene 4-(i-methylethenyl)-i-methyl-cyclohexene Uses pressure stabilizer in oils solvent for lacquers, inks, polishes, etc. A... 

The first models for asymmetric induction in [2 + 2] cycloadditions are ketimines derived from precursors such as (25), which react with both cyclic and acyclic alkenes to give adducts with high enantiomeric excesses. Full details have been reported on the regio- and stereo-specificity of the addition of dichloroketene to 1-substituted cyclohexenes. Methyl (phenylthiomethyl)-ketene (26) provides a further example of a ketene which, after cycloaddition to cyclopentadiene, undergoes facile opening of the cyclobutane that is thus formed to provide vicinally substituted cyclopentene derivatives. ... 

Effects which lower the carbonyl frequency (relative to acetone) a. Direct conjugation of the carhonyl via oc, 3-unsaturation will introduce new dipolar carhonyl resonance forms that lower the effective force constant values (increase the single-hond character of the carhonyl) and thus decrease the carhonyl stretching frequency. For example, consider cyclohexene methyl ketone (I), Vc=o= 1685 cm , and acetophenone (n), Vc=o= 1687 cm and examples listed in Table 7.3. 

Methyl 6-hydroxy-3-methylhexanoate is our 1,6-difunctional target molecule. Obvious precursors are cyclohexene and cyclohexadiene derivatives (section 1.14). Another possible starting material, namely citronellal, originates from the "magic box of readily available natural products (C.G. Overberger, 1967, 1968 E.J. Corey, 1968D R.D. Clark, 1976). 

Epoxides and aziridines are also capable of electrophilic subsitution of indoles. Indolylmagncsium bromide and cyclohexene oxide react to give 3-(lrans-2-hydroxycyclohexyl)indole[14]. Reaction of indoles with epoxides also occurs in the presence of Lewis acids. For example, indole reacts with methyl 2S,3R-epoxybutanoate at C3 with inversion of configuration[15]. 

Compounds in which a chirality center is part of a ring are handled in an analo gous fashion To determine for example whether the configuration of (+) 4 methyl cyclohexene is R or S treat the right and left hand paths around the nng as if they were independent substituents... 

Photolysis of pyridazine IV-oxide and alkylated pyridazine IV-oxides results in deoxygenation. When this is carried out in the presence of aromatic or methylated aromatic solvents or cyclohexane, the corresponding phenols, hydroxymethyl derivatives or cyclohexanol are formed in addition to pyridazines. In the presence of cyclohexene, cyclohexene oxide and cyclohexanone are generated. 

The mechanism of the reaction is unknown. The stereospecificity observed with (E)- and (Z)-l-methyl-2-phenylethylene points to a one-step reaction. The very low Hammett constant, -0.43, determined with phenylethylenes substituted in the benzene ring, excludes polar intermediates. Yields of only a few percent are obtained in the reaction of aliphatic alkenes with (52). In the reaction of cyclohexene with (52), further amination of the aziridine to aminoaziridine (99) is observed. Instead of diphenylazirine, diphenylacetonitrile (100) is formed from diphenylacetylene by NH uptake from (52) and phenyl migration. 

Cyclohexene-l-carboxylic acid, 2-Kthy1, methyl ester)... 

The purity of the product was determined by the checkers by GLC analysis using the following column and conditions 3-nm by 1.8-m column, 5% free fatty acid phase (FFAP) on acid-washed chromosorb W (60-80 mesh) treated with dimethyldichlorosilane, 90 C (1 min) then 90 to 200 C (15°C per rain). The chromatogram showed a major peak for methyl 2-methyl-l-cyclohexene-l-carboxylate preceded by two minor peaks for methyl 1-cyclohexene-l-carboxylate and l-acetyl-2-methylcyclohexene. The areas of the two impurity peaks were 5-6% and 0.5-2% that of the major peak. The purity of the product seems to depend upon careful temperature control during the reaction. The total amount of the two impurities was 14-21% in runs conducted at about -15 to -20°C or at temperatures below -23°C. 

This procedure illustrates a new method for the preparation of 6-alkyl-a,g-unsaturated esters by coupling lithium dialkylcuprates with enol phosphates of g-keto esters. The procedure for the preparation of methyl 2-oxocyclohexanecarboxylate described in Part A Is based on one reported by Ruest, Blouin, and Deslongcharaps. Methyl 2-methyl-l-cyc1ohexene-l-carboxylate has been prepared by esterification of the corresponding acid with dlazomethane - and by reaction of methyl 2-chloro-l-cyclohexene-l-carboxyl ate with lithium dimethylcuprate. -... 

A similar procedure has been employed to silylate the dianion of 3-methyl-3-buten-2-ol (67% yield).In systems where such internal activation is not possible (e.g. 2-raethyl-2-cyclohexen-l-o1), dianion formation can be performed in hexane to give a 75% yield of the corresponding disilyl compound. 

Methyl-6-(W,/V-dimethylamino)-frans-4-nitro-frans-5-phenyl-cyclohexene... 

Among the cases in which this type of kinetics have been observed are the addition of hydrogen chloride to 2-methyl-1-butene, 2-methyl-2-butene, 1-mefliylcyclopentene, and cyclohexene. The addition of hydrogen bromide to cyclopentene also follows a third-order rate expression. The transition state associated with the third-order rate expression involves proton transfer to the alkene from one hydrogen halide molecule and capture of the halide ion from the second ... 

Benzene-sensitized photolysis of methyl 3-cyclohexene-1-carboxylate in acetic acid leads to addition of acetic acid to the double bond. Only the trans adducts are formed. What factor(s) is (are) responsible for the reaction stereochemistry Which of the two possible addition products, A or B, do you expect to be the major product ... 

At higher temperatures the mixture of 10 and methyl vinyl ketone yields the 1,4-carbocyclic compound as described previously. Methyl isopropenyl ketone (5), ethyl acetylacrylate (d), 2-cyclohexenone (21), and 1-acetyl-1-cyclohexene (22) also undergo this type of cyclization reaction with enamines at higher temperatures. This cycloalkylation reaction occurs with enamines made of strongly basic amines such as pyrrolidine, but the less reactive morpholine enamine combines with methyl vinyl ketone to give only a simple alkylated product (7). Chlorovinyl ketones yield pyrans when allowed to react with the enamines of either alicyclic ketones or aldehydes (23). 

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