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Crystal surface, roughness

NMR spectra were recorded using Bruker Biospin AV200 spectrometer (at 200 MHz for protons). Infrared spectra were recorded on a Bio-Rad FTS-40 attenuated total reflection Fourier transform IR (ATR-IR) using a horizontal ATR apparatus with a cadmium selenide crystal. Surface roughness was measured by an interferometerom-eter, which generates a 3D profile (Veeco WYKO NTllOO optical profiler). [Pg.46]

Surface Finish. As well as influencing the rate of metal removal, electrolytes also affect the quality of surface finish obtained in ECM. Depending on the metal being machined, some electrolytes leave an etched finish. This finish results from the nonspecular reflection of light from crystal faces electrochemicaHy dissolved at different rates. Sodium chloride electrolyte tends to produce a kind of etched, matte finish when used for steels and nickel aHoys. A typical surface roughness average, Ra is about 1 ]lni. [Pg.308]

Increase adhesion tension. Maximize surface tension. Minimize contact angle. Alter surfactant concentration or type to maximize adhesion tension and minimize Marangoni effects. Precoat powder with wettahle monolayers, e.g., coatings or steam. Control impurity levels in particle formation. Alter crystal hahit in particle formation. Minimize surface roughness in milhng. [Pg.1881]

The line which defines the crystal surface can have straight pieces ( facets ) as well as curved ones. The latter correspond to a rough surface, as explained in the next section. The point at which straight and curved pieces meet can be either a sharp corner or a smooth tangential connection like z [21], where x is the deviation from the contact point in the direction... [Pg.856]

It is well established that GGA gives a better description of molecular systems, crystal surfaces and surface-molecule interactions. However, there are cases where the GGA results for solids are in much worse agreement with experiment than the LDA ones (e.g., 3-22 jj has been suggested that the effect of using GGA for solids is roughly equivalent to adding uniform tensile stress, and as a result lattice constants are frequently overestimated. [Pg.22]

The texture or crystal size of phosphate coatings can conveniently be recorded by making an impression on clear cellulose tape moistened with acetone. Uniformity of crystal size is of importance for coatings which are to resist wear and assist metal working. Surface roughness may also be studied by means of a Talysurf meter. [Pg.717]

An electrochemical quartz crystal microbalance (EQCM or QCM) can be used to estimate the surface roughness of deposited lithium [43],... [Pg.345]

A drastic departure from nucleation theory was made by Sadler [44] who proposed that the crystal surface was thermodynamically rough and a barrier term arises from the possible paths a polymer may take before crystallizing in a favourable configuration. His simulation and models have shown that this would give results consistent with experiments. The two-dimensional row model is not far removed from Point s initial nucleation barrier, and is practically identical to a model investigated by Dupire [35]. Further comparison between the two theories would be beneficial. [Pg.307]

We now describe a relatively simple MD model of a low-index crystal surface, which was conceived for the purpose of studying the rate of mass transport (8). The effect of temperature on surface transport involves several competing processes. A rough surface structure complicates the trajectories somewhat, and the diffusion of clusters of atoms must be considered. In order to simplify the model as much as possible, but retain the essential dynamics of the mobile atoms, we will consider a model in which the atoms move on a "substrate" represented by an analytic potential energy function that is adjusted to match that of a surface of a (100) face-centered cubic crystal composed of atoms interacting with a Lennard-Jones... [Pg.221]

Robinson IK. 1986. Crystal truncation rods and surface roughness. Phys Rev B 33 3830-3836. [Pg.268]


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See also in sourсe #XX -- [ Pg.844 ]




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