Cross diamond

Fig. 9.5. Specific molar volumes of the folded (Vf) and unfolded (Vu) states of Snase as derived from densitometric measurements [15] (crosses, diamonds), pressure perturbation calorimetry [16] (open square), and spectroscopic high-pressure unfolding experiments [14] (filled squares). Dashed lines correspond to extrapolations...

Fig. 5.5. The intensity of p polarized SHG as a function of the polarization direction of the fundamental beam before UV irradiation (open diamonds), after 2 minutes of unpolarized UV exposure (crossed diamonds), and after five minutes of the unpolarized UV exposure (solid diamonds). The value 5 = 0° corresponds to s input polarization. The solid line is a fit according to reference [50]. Inset relative decrease of the SHG intensity for 5 = 0° s — p (triangles) and S = 90° p — p (dots) as a function of irradiation time. The dashed lines are guide to the eye.

Fig. 1.23 Chemical compositions of ground water and surface water in Tono area, Gifu, Japan (Yamakawa 1991). Open triangle-, surface water, filled square-, deep ground water, cross, diamond, plus surface ground water...

Fig. 6 Radii-volatility correlation for group 4 elements and rutherfordium. The filled squares represent the radii of the outer orbital (r( fbit). top axis) the open circles show the ionic radii in solid crystals (r(cryst ), bottom axis). Included on the axis are predicted data for AHsubl(RfCU) from [44] (crossed triangle) and r(cryst.) Rf (crossed diamond) from [59]...

Venus probe. References should be consulted for the details of the optical transparency of the different type diamonds (9,14,16—19). The direct band gap for diamond is 5.47 eV. Natural diamond exhibits many colors, and color modification by irradiation and annealing is common (36). Though cubic, most natural diamonds show strain birefringence under crossed polaroids. 

In ordinary diamond (2inc-blende stmcture) the wrinkled sheets He in the (111) or octahedral face planes of the crystal and are stacked in an ABCABC sequence. In real crystals, this ABCABC sequence continues indefinitely, but deviations do occur. For example, two crystals may grow face-to-face as mirror images the mirror is called a twinning plane and the sequence of sheets crossing the mirror mns ABCABCCBACBA. Many unusual sequences may exist in real crystals, but they are not easy to study. 

Well, that is the case at the low temperature, when the rubber has a proper modulus of a few GPa. As the rubber warms up to room temperature, the Van der Waals bonds melt. (In fact, the stiffness of the bond is proportional to its melting point that is why diamond, which has the highest melting point of any material, also has the highest modulus.) The rubber remains solid because of the cross-links which form a sort of skeleton but when you load it, the chains now slide over each other in places where there are no cross-linking bonds. This, of course, gives extra strain, and the modulus goes down (remember, E = [Pg.61]

Many of the most floppy polymers have half-melted in this way at room temperature. The temperature at which this happens is called the glass temperature, Tq, for the polymer. Some polymers, which have no cross-links, melt completely at temperatures above T, becoming viscous liquids. Others, containing cross-links, become leathery (like PVC) or rubbery (as polystyrene butadiene does). Some typical values for Tg are polymethylmethacrylate (PMMA, or perspex), 100°C polystyrene (PS), 90°C polyethylene (low-density form), -20°C natural rubber, -40°C. To summarise, above Tc. the polymer is leathery, rubbery or molten below, it is a true solid with a modulus of at least 2GNm . This behaviour is shown in Fig. 6.2 which also shows how the stiffness of polymers increases as the covalent cross-link density increases, towards the value for diamond (which is simply a polymer with 100% of its bonds cross-linked. Fig. 4.7). Stiff polymers, then, are possible the stiffest now available have moduli comparable with that of aluminium. 

If the polymer is completely cross-linked (/= 1) then the modulus (Ej) is known it is that of diamond, 10 GPa. If it has no covalent bonds at all, then the modulus (E2) is that of a simple hydrocarbon like paraffin wax, and that, too, is known it is 1 GPa. 

Figure 3-34 Halpin-Tsai Calculations (Circles) versus Foye s Calculations for E2 of Rectangular Cross-Section Fibers in a Diamond Array (After Hatpin and Tsai [3-17])...

FIG. 4 Normalized oxygen density profile perpendicular to the surface from simulations of pure water with adsorption energies of 12, 24, 36, and 48 kJ/mol (from bottom to top). The lower curves are shifted downwards by 0.5, 1.0, and 1.5 units. The inset shows the height of the first (diamonds) and second peak (crosses) as a function of adsorption energy. Water interacts with the surface through a Morse potential. (From Ref. 98.)... 

Figure 3 Layer-resolved band energy contributions to the MAE for Cu/Fee/Cu (001) multilayers interdiffused at one of the Fe/Cu interfaces (shaded area), round symbols 30 %, cross 15 %, diamonds 0 % Only the Fe layers are numbered. For the interface layer of the Fe film (numbered by 1) only the contribution of the Fe component, whereas for the interface layer of the substrate (one layer to the left) only the contribution of the Cu component is displayed.

Hydraulic lift must also be taken into account when using diamond bits and PDC bits. The weight-on-bit varies between 0 and 100,000 lb or 0 and 50 ton-force. The end effect is due to the differential pressure between the drill collar internal pressure and the external hydrostatic pressure. This differential pressure acts on the sub internal cross-sectional area. 

Fig. 15. Tilt angles of the different molecular fragments as a function of temperature for polyphilic compound FsHnOCB aromatic core (circles), alkyl chain (crosses) and perfluoroalkyl chain (diamonds) (Ostrovskii et al. [45])...

Figure 14. Classical trajectories for the H + H2(v = l,j = 0) reaction representing a 1-TS (a-d) and a 2-TS reaction path (e-h). Both trajectories lead to H2(v = 2,/ = 5,k = 0) products and the same scattering angle, 0 = 50°. (a-c) 1-TS trajectory in Cartesian coordinates. The positions of the atoms (Ha, solid circles Hb, open circles He, dotted circles) are plotted at constant time intervals of 4.1 fs on top of snapshots of the potential energy surface in a space-fixed frame centered at the reactant HbHc molecule. The location of the conical intersection is indicated by crosses (x). (d) 1-TS trajectory in hyperspherical coordinates (cf. Fig. 1) showing the different H - - H2 arrangements (open diamonds) at the same time intervals as panels (a-c) the potential energy contours are for a fixed hyperradius of p = 4.0 a.u. (e-h) As above for the 2-TS trajectory. Note that the 1-TS trajectory is deflected to the nearside (deflection angle 0 = +50°), whereas the 2-TS trajectory proceeds via an insertion mechanism and is deflected to the farside (0 = —50°).

The TED and XRD patterns revealed that the deposit is not amorphous carbon but nanocrystalline diamond. Nonetheless, the 514-nm excited Raman spectra do not exhibit a clear diamond peak at 1332 cm though the peak due to the sp -bonded carbon network appears at 1150 cm The Raman cross section of the sp -bonded carbon network with visible excitation is resonantly enhanced [43, 48-50]. It consequently makes the 1332 cm diamond peak overlap with the peaks due to sp -bonded carbon. 

The work on carbon nitride solids is strongly related to research on diamondlike carbon (DLC) materials [5, 6]. DLC materials are thin film amorphous metastable carbon-based solids, pure or alloyed with hydrogen, which have properties similar to that of crystalline diamond (high hardness, low friction coefficient, high resistance to wear and chemical attack). This resemblance to diamond is due to the DLC structure, which is characterized by a high fraction of highly cross-linked sp -hybridized carbon atoms. To obtain this diamond-like structure... 

Figure 5.9 Plan view of the (111) plane of the diamond structure. A—Normal structure with open circles in the plane of the paper, and crossed circles in the plane above. Each pair is connected by a covalent bond. B—Partial shear of the upper plane over the lower one on the right-hand side creating a screw dislocation line with a kink in it (dashed line). C—Upper plane sheared down-ward by the displacement, b.

Figure 2. Logarithm of the scaled reactivities of iron clusters with hydrogen/deuterium from the Exxon (circles), Argonne (triangles and diamonds), and Rice (crosses) groups. The data are normalized to Feio °f the Argonne groups.

Fig. 1. Comparison of C/O ratios for programme stars (filled diamonds) with observations of Akerman et al. (2004) (crosses). Empty boxes are metal-rich stars from Israelian et al. (2004).

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