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Critical parameters in order

Summary Conditions for Obtaining Gas Blockage. Thus, we arrive at the following set of critical parameters, in order of importance, for characterizing gas-blocking foams in the laboratory ... [Pg.340]

In order to assess whether the proposed model described above is capable of generating results similar to those obtained by Feitz et al. (Environ, ScL TechnoL submitted), we have defined a hypothetical system similar to that examined by Feitz et al. and varied critical parameters in order to simulate the conditions used. Concentrations of the various species present have then been determined (for the range of system conditions of interest) using the ACUCHEM computer program (10). The ACUCHEM input file used for these calculations is given in the Appendix and features of the hypothetical system used are described below. [Pg.384]

Low recoveries for fortified sample may denote signal suppression, while high recoveries may indicate memory effects and/or matrix-related interferences. Further investigation is therefore necessary to identify the critical parameters in order to eliminate contamination and/or matrix effect (see Section 29.3.4). [Pg.634]

The chlorinated level increase should fall within 70%-130% of the true increase. If the result falls outside this range, then the accuracy of the method diminishes and is matrix related. Further investigation is therefore necessary to identify the critical parameters in order to eliminate contamination and/or matrix effect (see Section 29.3.4). If the fortified sample continues to fall outside the control range despite the identification of the critical parameters and the positive results of quality control, then the results related to the unfortified sample under investigation should be labeled as suspect due to matrix effect. [Pg.638]

Given the unique physiology of the CSF compartment, as well as the well-defined kinetic/radio-chemical properties of monoclonal antibodies, RIT delivered through the CSF can be optimized. An optimization model will help understand the complex dynamics of antibody and radiation dose delivered to tumor cells and to normal brain, and provide a tool to define the critical parameters in order to improve effectiveness and safety of I-MoAb RIT administered through the CSF. In addition, since different isotopes have distinct microdosimetric properties, their biologic effect in CSF RIT can be simulated and compared. These critical parameters of CSF dynamics and mAb pharmacokinetics can... [Pg.278]

For example, 0 describes the temperature dependence of composition near the upper critical solution temperature for binary (liquid + liquid) equilibrium, of the susceptibility in some magnetic phase transitions, and of the order parameter in (order + disorder) phase transitions. [Pg.395]

Thus we can consider (kcJKM) as an apparent second-order rate constant. This constant is the most critical parameter in determining the specificity of... [Pg.137]

A critical parameter in all models of DMS chemistry in the marine atmosphere is tne sea-to-air flux. Although the sea surface concentrations of DMS nave been measured in a wide variety of environments (14). the flux has never been measured directly. Instead, it has been calculated using observed concentrations and various models of gas transfer across the air sea interface. All of the models parameterize die transfer as a first order loss, as follows... [Pg.343]

In this way, the absolute normalized sensitivities A (7r,max, 0) as a function of any model parameter, e.g., consequently defines the critical limit for this parameter in order to guarantee an explosion-free operation. [Pg.83]

Determination of pure component parameters. In order to use the EOS to model real substances one needs to obtain pure component below its critical point, a technique suggested by Joffe et al. (18) was used. This involves the matching of chemical potentials of each component in the liquid and the vapour phases at the vapour pressure of the substance. Also, the actual and predicted saturated liquid densities were matched. The set of equations so obtained was solved by the use of a standard Newton s method to yield the pure component parameters. Values of exl and v for ethanol and water at several temperatures are shown in Table 1. In this calculation vH and z were set to 9.75 x 10"6 m3 mole"1 and 10, respectively (1 ). The capability of the lattice EOS to fit pure component VLE was found to be quite insensitive to variations in z (6[Pg.90]

These observations justify the conjecture that there is a better chance to find a quantum critical point in the U(Pt,Pd)3 system with the Pd concentration as the control parameter. In order to verify these suggestions, accurate neutron diffraction and pSR experiments have been performed in the composition range close to x = 0.006 where superconductivity disappears and long-range magnetic order starts to develop. We subdivide the discussion in compounds with 0 < x < 0.005 and with 0.006 < x < 0.01. [Pg.137]

A production of ozone occurs only by that fraction of H02 radicals entering into reaction with NO, whereas the fraction entering into reaction with 03 causes a loss of ozone. The relative probability of each of the above reaction steps is determined by the steady-state concentrations of the corresponding H02 reactions partners. Apart from the photochemical production rate, the concentrations of the radicals depend critically on the extent of the recycling reactions of H02 with NO and 03, that is, on the concentrations of ozone and nitric oxide. Since the former may be considered fixed, it is the latter that becomes a crucial parameter. In order to provide a more quantitative... [Pg.218]

Recall that many substances have similar critical compressibility values near 0.27. Therefore, charts have been developed which relate compressibility at other conditions to those at the critical point. In order to use these charts, the system parameters are normalized by dividing by the critical constants to yield reduced temperature, pressure, and volume ... [Pg.118]

Drying is also a critical parameter in the preparation of PILCs. Slow drying (or air-drying) allows the clay layers to settle down in an ordered, parallel way (face-to-face stacking). This favors the microporosity and crystallinity of the final PILC. Fast techniques, like freeze-drying, fix the random orientation of pillared clay plates or aggregates to form a card-house structure. This structure also exists for the laponite clay. PILCs dried in this way exhibit a larger meso-porosity, but are less crystalline. [Pg.281]

System upscaling is the most critical need for MECs (Logan et al., 2008 Zhang and Angelidaki, 2014). Phot-scale MECs have been built to treat domestic wastewater but the energy recovery is only around 50—70% of electricity input, and hydrogen production rate as well as COD removal rate is low (Heidrich et al., 2013 Heidrich et al., 2014). Much has to been done to optimize reactor design and operational parameters in order to make pilot-scale MECs cost-effective and efficient. [Pg.316]

In order to test the economic performance of the project to variations in the base case estimates for the input data, sensitivity analysis is performed. This shows how robust the project is to variations in one or more parameters, and also highlights which of the inputs the project economics is more sensitive to. These inputs can then be addressed more specifically. For example if the project economics is highly sensitive to a delay in first production, then the scheduling should be more critically reviewed. [Pg.325]


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