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Correct condition weight

It is fortunate that theory has been extended to take into account selective interactions in multicomponent systems, and it is seen from Eq. (91) (which is the expression used for the plots in Fig. 42 b) that the intercept at infinite dilution of protein or other solute does give the reciprocal of its correct molecular weight M2. This procedure is a straightforward one whereby one specifies within the constant K [Eq. (24)] a specific refractive index increment (9n7dc2)TiM. The subscript (i (a shorter way of writing subscripts jUj and ju3) signifies that the increments are to be taken at constant chemical potential of all diffusible solutes, that is, the components other than the polymer. This constitutes the osmotic pressure condition whereby only the macromolecule (component-2) is non-diffusible through a semi-permeable membrane. The quantity... [Pg.205]

We will now turn our attention from the viscosity of dilute solutions and look at the viscosity of melted polymers. The viscosity of melted polymers is important in transferring resins and in polymer processing such as determining the correct conditions to have a specific flow rate for injection processing and in determining the optimum conditions to get the necessary dimensions of extruded shapes. Fillers, plasticizers, temperature, solvents, and molecular weight are just some of the variables that influence the viscosity of polymer melts. Here we will look at the dependence of melt viscosity on polymer molecular weight. Polymer melts have viscosities on the order of 10,000 MPa (1 centipoise =0.001 Pa/sec). [Pg.77]

NH4)14(P04)4S04-53MoO., purporting to represent the composition of the precipitate formed under various conditions and it was common to use a factor to correct the weight of precipitate to the percentage of phosphorus. [Pg.535]

A correct value of the molecular weight is obtained for the charged polymer by the van t Hoff equation, provided that a large excess of indifferent electrolyte is present. These high concentrations are described as swamping electrolyte conditions. [Pg.574]

What makes the latter items particularly important is the fact that the charge and electrolyte content of an unknown polymer may not be known hence it is important to design an osmotic pressure experiment correctly for such a system. It is often easier to add swamping amounts of electrolyte than to totally eliminate all traces of electrolyte. Under the former conditions a true molecular weight is obtained. Trouble arises only when the experimenter is indifferent toward indifferent electrolyte this sort of carelessness can be the source of much confusion. [Pg.574]

Soft-foot is the condition when all four of a machine s feet do not support the weight of the machine. It is important to determine if this condition is present prior to performing shaft alignment on a piece of machinery. Not correcting soft-foot prior to alignment is a major cause of frustration and lost time during the aligning procedure. [Pg.919]


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Condition weight

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