Copper enrichment factor

Here [Mp] and [Mr] are the metal concentrations in particulate matter and in crustal rock, respectively, and [Alp] and [Ah] are the concentrations of aluminum (or any suitable reference element) in particulate matter and crustal rock, respectively. Table 3 lists EEs for SPM or fine sediment in contrasting estuaries. Enrichment factors are close to unity for the baseline sediment and in the pristine Lena Estuary, while the greatest EE values are encountered for cadmium in the Rhine (impacted by the production of phosphate fertilizers) and the Scheldt, and for copper in Restronguet Creek (impacted by historical mining activity). The general sequence of EEs... 

Trace metals, such as copper, nickel, cobalt, zinc, and various rare earth elements, tend to coprecipitate with or adsorb onto Fe-Mn oxides. As shown in Table 18.1, this causes these elements to be highly enriched in the hydrogenous deposits as compared to their concentrations in seawater. The degree of enrichment is dependent on various environmental factors, such as the redox history of the underlying sediments and hydrothermal activity. This makes the composition of the oxides geographically variable. 

Many of the micron-sized interplanetary dust particles (IDPs) have approximately chondritic bulk composition (see Chapter 1.26 for details). Porous IDPs match the Cl composition better than nonporous (smooth) IDPs. On an average, IDPs show some enhancement of moderately volatile and volatile elements (see Palme, 2000). Arndt et al. (1996) found similar enrichments in their suite of 44 chondritic particles (average size 17.2 1.2 p.m). The elements chlorine, copper, zinc, gallium, selenium, and rubidium were enriched by factors of 2.2-2.7. In addition, these... 

Adsorptive stripping voltammetry (ASV) is another specialised technique where the SMDE electrode is used for reducible species and carbon paste electrodes for oxidisable ones. This allows enrichment (by factors of 100-1000) of ions at the working electrode before stripping them off for measurement this improves the detection limits. This technique is rapid, sensitive (10 "M), economical and simple for trace analysis. The basic instrumentation for stripping analysis is apotentiostat (with voltammetric analyser), electrode and recorder. While voltammetry is generally very useful for compounds that do not have a chromophore or fluorophore, stripping analysis is the best analytical tool for direct, simultaneous determination of metals of environmental concern, e.g. lead, cadmium, zinc and copper in sea water. 

Differentiation of sedimentary metal phases was performed on grain size fractionated samples from the lower Rhine River by successive chemical leaching (review). Pollution affects the significant increase of nonresidual associations of chromium, cop er, lead, and zinc. Except for manganese the metal contents in most of the extracted phases decrease as the grain size increases. Phase concentration factors (PCF relative enrichment of metal content in major carrier substances) are high for chromium in moderately reducible phases (20-fold increase in clay-sized particles), for manganese and zinc in the easily reducible sediment fraction (30- and 55-fold enrichment), and for copper and zinc in the carbonates (15 or 25 times compared with total sediment). 

Contents Background and Technical Aspects of the Chemical Industry. - Air Quality and Emission Control. - Water Quality Emission Control. - Natural and Derived Sodium and Potassium Salts. - Industrial Bases by Chemical Routes. - Electrolytic Sodium Hydrocide and Chlorine and Related Commodities. -Sulfur and Sulfuric Add. - Phosphorus and Phosphoric Acid. - Ammonia, Nitric Add and their Derivatives. - Aluminium and Compounds. - Ore Enrichment and Smelting of Copper. - Production of Iron Steel. - Production of Pulp and Paper. - Fermentation Processes. - Petroleum Production and Transport. - Petroleum Refining. - Formulae and Conversion Factors. - Subject Index. 

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