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Conversion factors multistep

This is a multistep problem. The first step is to find out how many kg the client weighs. Divide 165 pounds by 2.2 conversion factor to equal 75 kg of body weight. [Pg.385]

When solving multistep xmit conversion problems, we follow the preceding procedure, but we add more steps to the solution map. Each step in the solution map should have a conversion factor with the units of the previous step in the denominator and the units of the following step in the numerator. For example, suppose we want to convert 194 cm to feet. The solution map begins with cm, and we use the relationship 2.54 cm = 1 in to convert to in. We then use the relationship 12 in. = 1 ft to convert to ft. [Pg.29]

In the presence of a large excess of PH, primary phosphines, RPH2, are formed predominantiy. Secondary phosphines, R2PH, must be either isolated from mixtures with primary and tertiary products or made in special multistep procedures. Certain secondary phosphines can be produced if steric factors preclude conversion to a tertiary product. Both primary and secondary phosphines can be substituted with olefins. After the proper selection of substituents, mixed phosphines of the type RRTH or RR R T can be made. [Pg.379]

A key aspect of metal oxides is that they possess multiple functional properties acid-base, electron transfer and transport, chemisorption by a and 7i-bonding of hydrocarbons, O-insertion and H-abstraction, etc. This multi-functionality allows them to catalyze complex selective multistep transformations of hydrocarbons, as well as other catalytic reactions (NO,c conversion, for example). The control of the catalyst multi-functionality requires the ability to control not only the nanostructure, e.g. the nano-scale environment around the active site, " but also the nano-architecture, e.g. the 3D spatial organization of nano-entities. The active site is not the only relevant aspect for catalysis. The local area around the active site orients or assists the coordination of the reactants, and may induce sterical constrains on the transition state, and influences short-range transport (nano-scale level). Therefore, it plays a critical role in determining the reactivity and selectivity in multiple pathways of transformation. In addition, there are indications pointing out that the dynamics of adsorbed species, e.g. their mobility during the catalytic processes which is also an important factor determining the catalytic performances in complex surface reaction, " is influenced by the nanoarchitecture. [Pg.81]

Alkyl and aryl nitriles readily hydrolyze when submitted to NCW conditions. The hydrolysis is a multistep sequence as shown in Fig. 9.26. For instance, Katritzky et al. have reported that benzonitrile is converted to benzamide and benzoic acid at 250°C over a period of 5 days, and they conclude that the amide and the acid were in equilibrium. Under these conditions some decarboxylation can also occur. An et al. have reported the product distribution for the hydrolysis of benzonitrile as a function of time and temperature. Specifically, the ratio of benzamide to benzoic acid varied as follows after 1 h at 250°C, the distribution was 5 4. However, at 280°C after 1 h, the ratio was 1 1, and became 1 25 when the reaction time was extended to 6 h. Alkylnitriles exhibit similar behaviors Siskin et ah reported that at 250°C for 2.5 days decanonitrile quantitatively yields two major products, decanoic acid and decanoamide. When octanenitrile was hydrolyzed to octanoic acid amide and octanoic acid, the reaction was slightly slower than that ofbenzonitrile. Only 29% conversion took place in 1 h at 290°C. The limited solubility of octanenitrile in water, even in NCW conditions, was suggested as a possible factor for the slow reaction. Again the product distribution was dependent on the residence time and the temperature. [Pg.273]

In multistep electron transfer reactions, the overall reaction rate may be limited by rates of reactant chemisorption, rates of bond breaking, or rates of molecular rearrangement. These are chemical, rather than potential, dependent factors. If the observed reaction rates are limited by chemical dependent factors, the measured transfer coefficients may be only fitting parameters, or apparent transfer coefficients. In this case, the apparent transfer coefficient will be temperature dependent (25-27). Conversely, for reactions that are limited by potential dependent factors, i.e., the rate of outer-sphere electron transfer, the transfer coefficient should be independent of temperature (25-27). [Pg.404]


See other pages where Conversion factors multistep is mentioned: [Pg.135]    [Pg.332]    [Pg.30]    [Pg.496]    [Pg.1112]    [Pg.450]    [Pg.313]    [Pg.313]    [Pg.270]    [Pg.726]    [Pg.367]    [Pg.516]    [Pg.35]    [Pg.72]    [Pg.210]    [Pg.1]    [Pg.438]    [Pg.622]   
See also in sourсe #XX -- [ Pg.29 , Pg.30 ]




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