Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Continuous and discontinuous

SmA phases, and SmA and SmC phases, meet tlie line of discontinuous transitions between tire N and SmC phase. The latter transition is first order due to fluctuations of SmC order, which are continuously degenerate, being concentrated on two rings in reciprocal space ratlier tlian two points in tire case of tire N-SmA transition [18,19 and 20], Because tire NAC point corresponds to the meeting of lines of continuous and discontinuous transitions it is an example of a Lifshitz point (a precise definition of tliis critical point is provided in [18,19 and 20]). The NAC point and associated transitions between tire tliree phases are described by tire Chen-Lubensky model [97], which is able to account for tire topology of tire experimental phase diagram. In tire vicinity of tire NAC point, universal behaviour is predicted and observed experimentally [20]. [Pg.2560]

The parameters which characterize the thermodynamic equilibrium of the gel, viz. the swelling degree, swelling pressure, as well as other characteristics of the gel like the elastic modulus, can be substantially changed due to changes in external conditions, i.e., temperature, composition of the solution, pressure and some other factors. The changes in the state of the gel which are visually observed as volume changes can be both continuous and discontinuous [96], In principle, the latter is a transition between the phases of different concentration of the network polymer one of which corresponds to the swollen gel and the other to the collapsed one. [Pg.111]

There is a degree in the continuity and discontinuity of the orbital phase [20]. 2-Oxopropane-l,3-diyl (Scheme 10) is a hetero analog of trimethylenemethane (TMM) where the orbital phase is continuous in the triplet diradical (Sect. 2.1.5) and discontinuous in the singlet diradical (Sect. 2.1.6). The n and orbitals of carbonyl bonds are lower in energy than those of C=C bonds. The lowering strengthens the interaction of the radical orbitals (a, b) with and weakens that... [Pg.93]

The preceding theory of cyclic conjugation has led to such classification as is summarized in Scheme 15 [25]. Cyclic conjugation is first divided into the continuous and discontinuous conjugations by the donor-acceptor disposition. The stability of... [Pg.97]

As it stands this method can hardly be applied to activities of the scale of interest. Indeed, regarding temperature, pressure and volume the thresholds used are far too critical. The distinction between continuous and discontinuous techniques does not seem of any use in this context. There are a lot of situations that often arise under smaller scale conditions which are missing for instance, glass materials, activities outside working hours or unsupervised handling, etc. [Pg.157]

An emulsion separation method using hydrocyclones. The emulsion comprises a continuous phase, a discontinuous phase and fine solid particles. In the first step, the original emulsion is separated into an overflow emulsion and an underflow emulsion, in a first hydrocyclone. The overflow emulsion comprises portions of the continuous phase, the discontinuous phase and the fine solid particles. The overflow emulsion is inverted in which the continuous phase of the overflow emulsion is now a second discontinuous phase and the original discontinuous phase becomes a second continuous phase. Then, the inverted emulsion is directed to one or more subsequent hydrocyclones and the second continuous and discontinuous phases are collected. The fine solid particles remain in the second discontinuous phase. [Pg.303]

Konig (1987) Structural changes accompanying continuous and discontinuous spin state transitions [221]. [Pg.50]

Gleaves, D., Lowe, M., Snow, A. C., Green, B., Murphy-Eberenz, K. P. (2000). Continuity and discontinuity models of bulimia nervosa A taxometric investigation. Journal of Abnormal Psychology, 109, 56-68. [Pg.181]

Flat Sheets. Generally, the interface between a liquid sheet and air can be perturbed by aerodynamic, turbulent, inertial, surface tension, viscous, acoustic, or electrical forces. The stability of the sheet and the growth rate of unstable disturbances are determined by the relative magnitude of these forces. Theoretical and experimental studies 255112561 on disintegration mechanisms of flat sheets showed that the instability and wave formation at the interface between the continuous and discontinuous phases are the maj or factors leading to... [Pg.158]

Figure 2.33 Capacity development of continuous and discontinuous PET plants [2]. From manufacturer s literature published by Zimmer AG and reproduced with permission... Figure 2.33 Capacity development of continuous and discontinuous PET plants [2]. From manufacturer s literature published by Zimmer AG and reproduced with permission...
Another distinction between protein domains are continuous and discontinuous domains. A continuous domain has a consecutive region of peptide that folds up to form a single domain all the examples in Fig. 2 are continuous domains. Discontinuous domains are composed of non-consecutive regions of the peptide to form a single domain. It is not obvious that discontinuous domains, unlike continuous domains, can exist in isolation. From known structures it has been shown that slightly less than one third of structural domains are discontinuous (Jones et al., 1998). [Pg.139]

Many attempts have been made to calculate important macroscopic properties of ionic solutions without a detailed knowledge of their molecular structure. All models developed for this purpose can be classified into three categories according to the way the surrounding of the central ion is accounted for. Usually, continuous and discontinuous theories of ionic solvation are distinguished. Furthermore, it seems appropriate also to mention various attempts to apply statistical mechanics directly to ionic solutions. [Pg.11]

Galiotis, C. (1993a). A study of mechanisms of stress transfer in continuous and discontinuous fiber model composites by laser Raman spectroscopy. Composites Sci. Technol. 48, 15-28. [Pg.39]

Blends are physical mixtures of polymers. Depending on the extent and type of blend the properties may be characteristic of each blend member or may be some blend of properties. Immiscible blends are phase-separated with the phases sometimes chemically connected. They are generally composed of a continuous and discontinuous phase. HIPS is an example of an immiscible blend. Miscible blends occur when the two blended materials are compatible. Often the properties are a mixture of the two blended materials. The plastic automotive panels and bumpers are generally made from a miscible blend of PE and a copolymer of PE and PP. [Pg.233]

As noted above, the range of fibers employed does not precisely overlap with those employed for organic composites. Because the formation of the MMCs generally requires melting of the metal-matrix, the fibers need to have some stability to relatively high temperatures. Such fibers include graphite, silicon carbide, boron, alumina-silica, and alumina fibers. Most of these are available as continuous and discontinuous fibers. It also includes a number of thin metal wires made from tungsten, titanium, molybdenum, and beryllium. [Pg.255]

Haneda T, Tracz A, Saito G, Yamochi H (2011) Continuous and discontinuous water release/ intake of (BED0-TTF)2Br(H20)3 micro-crystals embedded in polymer film. J Mater Chem 21 1621-1626... [Pg.113]

Calculate axial and transverse modnli and strengths for nnidirectional, continuous and discontinuous, fiber-reinforced composites and laminate composites. Describe the structure of soft and hard biologies that give rise to their unique mechanical properties. [Pg.381]

Perhaps because of this focus on actual practice, chemists did not write much directly on the question of continuity and discontinuity. Among those who did, the most prominent in the eighteenth century was Pierre-Joseph Macquer, who attempted a system of chemistry based on a set of rules of affinity (see Chapter Eight). His third rule, which Duncan says he inherited from Stahl, reads Substances that unite together lose some of their separate properties and the compounds resulting from their union partake of the properties of the substances which serve as their principles. [Pg.207]

The error of approximation in the class of smooth coefficients. The main point of the theory is the accurate account of the accuracy of the uniform scheme (16)—(17) in the class of continuous and discontinuous functions k(x), q(x) and f(x). In preparation for this, let u(x) be an exact solution of the original problem... [Pg.159]

Many processes are used throughout the world for distilling wine into brandy. Continuous distillation in plate columns, discontinuous or batch distillation using pot stills (with and without adjunct rectifying columns), and even distillation apparatuses involving both continuous and discontinuous aspects are used. [Pg.243]

The thermodynamics of phase equilibria is reviewed in Chapter 17 and the fundamental thermodynamic differences between conserved and nonconserved order parameters are reinforced with a geometrical construction. These order parameters are used in the kinetic analyses of continuous and discontinuous phase transformations. [Pg.418]

This leads to the general classification of continuous and discontinuous transformations. [Pg.431]


See other pages where Continuous and discontinuous is mentioned: [Pg.741]    [Pg.89]    [Pg.97]    [Pg.352]    [Pg.159]    [Pg.779]    [Pg.149]    [Pg.904]    [Pg.93]    [Pg.99]    [Pg.452]    [Pg.257]    [Pg.222]    [Pg.218]    [Pg.222]    [Pg.108]    [Pg.443]    [Pg.56]    [Pg.215]    [Pg.244]    [Pg.431]    [Pg.1]    [Pg.9]    [Pg.13]    [Pg.228]    [Pg.77]    [Pg.249]   


SEARCH



Continuous and Discontinuous Transformations

Discontinuous

© 2024 chempedia.info