Steady state continuity equation

When electrons are injected as minority carriers into a -type semiconductor they may diffuse, drift, or disappear. That is, their electrical behavior is determined by diffusion in concentration gradients, drift in electric fields (potential gradients), or disappearance through recombination with majority carrier holes. Thus, the transport behavior of minority carriers can be described by a continuity equation. To derive the p—n junction equation, steady-state is assumed, so that = 0, and a neutral region outside the depletion region is assumed, so that the electric field is zero. Under these circumstances,... 

The entry-length region is characterized by a diffusive process wherein the flow must adjust to the zero-velocity no-slip condition on the wall. A momentum boundary layer grows out from the wall, with velocities near the wall being retarded relative to the uniform inlet velocity and velocities near the centerline being accelerated to maintain mass continuity. In steady state, this behavior is described by the coupled effects of the mass continuity and axial momentum equations. For a constant-viscosity fluid,... 

The assumption that the flows in the network are in a continuously evolving steady state brings the benefit that the model is rendered much less stiff thereby. Furthermore, the resulting simultaneous equations may be solved explicity in simple flow networks. In more complex networks, however, the resulting set of nonlinear, simultaneous equations requires a more sophisticated approach in order to bring about the desired savings in model execution time. This chapter considers both... 

Simplify the equation of continuity for steady-state diffusion in one direction in rectangular coordinates and without chemical reaction. 

The drug is being administered continuously the steady-state concentration for a continuously administered drug is given by the equation in question 1. Thus... 

When the crystallizer is well mixed and operated continuously at steady state, with no attrition and breakage of the crystals at a size-independent crystal growth rate, the simplest population balance equation is... 

Formulating Material Balance Equations (Steady-State and Continuous Operation)... 

Using a procedure similar to the derivation of Equation (4.53) the working equations of the continuous penalty scheme for steady-state Stokes flow in a polar (r, 9) coordinate system are obtained as... 

MODELLING OF STEADY-STATE VISCOMETRIC FLOW -WORKING EQUATIONS OF THE CONTINUOUS PENALTY SCHEME IN CARTESIAN COORDINATE SYSTEMS... 

As already mentioned, the present code corresponds to the solution of steady-state non-isothennal Navier-Stokes equations in two-dimensional Cartesian domains by the continuous penalty method. As an example, we consider modifications required to extend the program to the solution of creeping (Stokes) non-isothermal flow in axisymmetric domains ... 

As a reactant molecule from the fluid phase surrounding the particle enters the pore stmcture, it can either react on the surface or continue diffusing toward the center of the particle. A quantitative model of the process is developed by writing a differential equation for the conservation of mass of the reactant diffusing into the particle. At steady state, the rate of diffusion of the reactant into a shell of infinitesimal thickness minus the rate of diffusion out of the shell is equal to the rate of consumption of the reactant in the shell by chemical reaction. Solving the equation leads to a result that shows how the rate of the catalytic reaction is influenced by the interplay of the transport, which is characterized by the effective diffusion coefficient of the reactant in the pores, and the reaction, which is characterized by the first-order reaction rate constant. 

Mechanism. The thermal cracking of hydrocarbons proceeds via a free-radical mechanism (20). Siace that discovery, many reaction schemes have been proposed for various hydrocarbon feeds (21—24). Siace radicals are neutral species with a short life, their concentrations under reaction conditions are extremely small. Therefore, the iategration of continuity equations involving radical and molecular species requires special iategration algorithms (25). An approximate method known as pseudo steady-state approximation has been used ia chemical kinetics for many years (26,27). The errors associated with various approximations ia predicting the product distribution have been given (28). 

Usually, diffusivity and kinematic viscosity are given properties of the feed. Geometiy in an experiment is fixed, thus d and averaged I are constant. Even if values vary somewhat, their presence in the equations as factors with fractional exponents dampens their numerical change. For a continuous steady-state experiment, and even for a batch experiment over a short time, a very useful equation comes from taking the logarithm of either Eq. (22-86) or (22-89) then the partial derivative ... 

This is an old, familiar analysis that applies to any continuous culture with a single growth-limiting nutrient that meets the assumptions of perfect mixing and constant volume. The fundamental mass balance equations are used with the Monod equation, which has no time dependency and should be apphed with caution to transient states where there may be a time lag as [L responds to changing S. At steady state, the rates of change become zero, and [L = D. Substituting ... 

A special case of the above equation applies to a continuous steady-state flow process when all of the rate terms are independent of time and the accumulation term is zero. Thus, the differential material balance for any component i in such a process is given by... 

The estimation of the diffusional flux to a clean surface of a single spherical bubble moving with a constant velocity relative to a liquid medium requires the solution of the equation for convective diffusion for the component that dissolves in the continuous phase. For steady-state incompressible axisym-metric flow, the equation for convective diffusion in spherical coordinates is approximated by... 

The above equations can be used to predict the output 1/ in the effluent from a continuous-flow gas-liquid contractor. Let the flow rate of phase a be F. Then, a macroscopic balance at a steady state leads to the equation ... 

AT is intended to include any and all of the effects of the sorption rate of monomer on the surface, steric arrangement of active species, the addition of the monomer to the live polymer chain, and any desorption needed to permit the chain to continue growing. We assume a steady state in which every mole of propylene that polymerizes is replaced by another mole entering the shell from the gas, so that all of the fluxes are equal to Ny gmol propylene reacted per second per liter of total reactor volume. The following set of equations relates the molar flux to each of the concentration driving forces. 

In a smooth muscle cell under steady state conditions, the reactions described by the set of Equations 2-6 are probably very close to equilibrium in the sense that they are not continuously held far away from equilibrium by ongoing metabolic reactions, e.g., ATP hydrolysis. The resting concentrations of the reactants of these... 

There is nothing in Equations 1-8 which is an all-or-none situation. There are no positive feedback loops which might cause some kind of flip-flop of states of operation of the system. There are some possibilities for saturation phenomena but all relationships are graded. Overall, transient or steady-state, the changes of concentration of P-myosin are continuous, monotonic functions of the intracellular Ca ion concentration. On this basis it is more appropriate to say that smooth muscle contraction is modulated rather than triggered by Ca ion. 

The time derivatives are dropped for steady-state, continuous flow, although the method of false transients may still be convenient for solving Equations (11.11) and (11.12) (or, for variable Kh, Equations (11.9) and (11.10) together with the appropriate auxiliary equations). The general case is somewhat less complicated than for two-phase batch reactions since system parameters such as V, Vg, Vh and At will have steady-state values. Still, a realistic solution can be quite complicated. 

Procedures enabling the calculation of bifurcation and limit points for systems of nonlinear equations have been discussed, for example, by Keller (13) Heinemann et al. (14-15) and Chan (16). In particular, in the work of Heineman et al., a version of Keller s pseudo-arclength continuation method was used to calculate the multiple steady-states of a model one-step, nonadiabatic, premixed laminar flame (Heinemann et al., (14)) a premixed, nonadiabatic, hydrogen-air system (Heinemann et al., (15)). 

Michaels [241], using a model pore shown in Figure 19, considered the constriction effect by solving the steady-state species continuity equations in a model pore consisting of a single constriction. The result for the pore shown in Figure 19 is given by... 

Based on the kinetic mechanism and using the parameter values, one can analyze the continuous stirred tank reactor (CSTR) as well as the dispersed plug flow reactor (PFR) in which the reaction between ethylene and cyclopentadiene takes place. The steady state mass balance equations maybe expressed by using the usual notation as follows ... 

In the previous discussion of the one- and two-compartment models we have loaded the system with a single-dose D at time zero, and subsequently we observed its transient response until a steady state was reached. It has been shown that an analysis of the response in the central plasma compartment allows to estimate the transfer constants of the system. Once the transfer constants have been established, it is possible to study the behaviour of the model with different types of input functions. The case when the input is delivered at a constant rate during a certain time interval is of special importance. It applies when a drug is delivered by continuous intravenous infusion. We assume that an amount Z) of a drug is delivered during the time of infusion x at a constant rate (Fig. 39.10). The first part of the mass balance differential equation for this one-compartment open system, for times t between 0 and x, is given by ... 

For steady-state operation of a continuous stirred-tank reactor or continuous stirred-tank reactor cascade, there is no change in conditions with respect to time, and therefore the accumulation term is zero. Under transient conditions, the full form of the equation, involving all four terms, must be employed. 

Although continuous stirred-tank reactors (Fig. 3.12) normally operate at steady-state conditions, a derivation of the full dynamic equation for the system, is necessary to cover the instances of plant start up, shut down and the application of reactor control. 

The simultaneous integration of the two continuity equations, combined with the chemical kinetic relationships, thus gives the steady-state values of both, Ca and T, as functions of reactor length. The simulation examples BENZHYD, ANHYD and NITRO illustrate the above method of solution. 

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