Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Coherence temperature

The estimation of the three parameters —pseudo-critical temperature, pseudo-critical pressure, and the acentric factor— should be done using the same method because these constants should be coherent. [Pg.97]

For petroleum fractions, there is a problem of coherence between the expression for liquid enthalpy and that of an ideal gas. When the reduced temperature is greater than 0.8, the liquid enthalpy is calculated starting with the enthalpy of the ideal gas. On the contrary, when the reduced temperature is less than 0.8, it is preferable to calculate the enthalpy of the ideal gas starting with the enthalpy of the liquid (... [Pg.141]

Especially with LTG GaAs, materials became available that were nearly ideal for time-resolved THz spectroscopy. Due to the low growth temperature and the slight As excess incorporated, clusters are fonned which act as recombination sites for the excited carriers, leading to lifetimes of <250 fs [45], With such recombination lifetunes, THz radiators such as dipole anteimae or log-periodic spirals placed onto optoelectronic substrates and pumped with ultrafast lasers can be used to generate sub-picosecond pulses with optical bandwidths of 2-4 THz. Moreover, coherent sub-picosecond detection is possible, which enables both... [Pg.1249]

As the spins precess in the equatorial plane, they also undergo random relaxation processes that disturb their movement and prevent them from coming together fiilly realigned. The longer the time i between the pulses the more spins lose coherence and consequently the weaker the echo. The decay rate of the two-pulse echo amplitude is described by the phase memory time, which is the time span during which a spin can remember its position in the dephased pattern after the first MW pulse. Tyy is related to the homogeneous linewidth of the individual spin packets and is usually only a few microseconds, even at low temperatures. [Pg.1576]

Surface reconstructions have been observed by STM in many systems, and the teclmique has, indeed, been used to confmn the missing row structure in the 1 x 2 reconstruction of Au(l 10) [28]. As the temperature was increased within 10 K of the transition to the disordered 1 1 phase (700 K), a drastic reduction in domain size to -20-40 A (i.e. less than the coherence width of LEED) was observed. In this way, the STM has been used to help explain and extend many observations previously made by diffraction methods. [Pg.1682]

Chronister E L and Crowell R A 1991 Time-resolved coherent Raman spectroscopy of low-temperature molecular solids in a high-pressure diamond anvil cell Chem. Phys. Lett. 182 27... [Pg.1965]

Cong P, Deuhl H P and Simon J D 1993 Using optical coherence to measure the ultrafast electronic dephasIng of large molecules In room-temperature liquids Chem. Phys. Lett. 211 367-73... [Pg.1997]

Vos M H, Jones M R, Hunter C N, Breton J and Martin J-L 1994 Coherent nuclear dynamics at room temperature in bacterial reaction centers Proc. Natl Acad. Sci. USA 91 12 701-5... [Pg.1998]

We restrict ourselves to the case of the system at zero temperature. This is not relevant from the point of view of methodology. The case of nonzero temperatures may be considered in the completely analogous fashion. At zero temperature the coherent potential is chosen so that the Gmi(z) and G /(z) averaged over phonon degrees of freedom in phonon vacuum are equal... [Pg.447]

Sintering is a thermal process through which a loose mass of particles is transformed to a coherent body. It usually takes place at a temperature equal to two-thirds the melting point, or ca 800—1000°C for nickel. The sintered nickel stmcture without active material is called a plaque and it can be prepared by either dry or wet processes (see Metallurgy, powder). [Pg.548]

Organic Solids A few organic compounds decompose before melting, mostly nitrogen compounds azides, diazo compounds, and nitramines. The processes are exothermic, classed as explosions, and may follow an autocatalytic law. Temperature ranges of decomposition are mostly 100 to 200°C (212 to 392°F). Only spotty results have been obtained, with no coherent pattern. The decomposition of malonic acid has been measured for both the solid and the supercooled liquid. The first-order specific rates at 126.3°C (259.3°F) were 0.00025/min for solid and 0.00207 for liquid, a ratio of 8 at II0.8°C (23I.4°F), the values were 0.000021 and 0.00047, a ratio of 39. The decomposition of oxalic acid (m.p. I89°C) obeyed a zero-order law at 130 to I70°C (266 to 338°F). [Pg.2122]

The insulation resistance thus measured at different intervals during the process of heating up will represent the insulation resistance of the windings at that temperature. Before plotting the curves, these test values must be collected to one reference temperature, say, 40°C, to maintain coherence in the test results. [Pg.226]


See other pages where Coherence temperature is mentioned: [Pg.203]    [Pg.290]    [Pg.344]    [Pg.348]    [Pg.373]    [Pg.191]    [Pg.229]    [Pg.2]    [Pg.353]    [Pg.407]    [Pg.58]    [Pg.282]    [Pg.343]    [Pg.350]    [Pg.162]    [Pg.203]    [Pg.290]    [Pg.344]    [Pg.348]    [Pg.373]    [Pg.191]    [Pg.229]    [Pg.2]    [Pg.353]    [Pg.407]    [Pg.58]    [Pg.282]    [Pg.343]    [Pg.350]    [Pg.162]    [Pg.218]    [Pg.1235]    [Pg.442]    [Pg.444]    [Pg.444]    [Pg.455]    [Pg.261]    [Pg.580]    [Pg.476]    [Pg.114]    [Pg.115]    [Pg.381]    [Pg.235]    [Pg.7]    [Pg.210]    [Pg.251]    [Pg.270]    [Pg.319]    [Pg.361]    [Pg.1899]    [Pg.190]    [Pg.277]   
See also in sourсe #XX -- [ Pg.349 , Pg.373 ]




SEARCH



© 2024 chempedia.info