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Coefficient process efficiency

It is worth noting that the washing of the membranes with water has a favourable effect on the process efficiency. Following this procedure, the hydraulic permeability of the membranes approached its initial value, although the elimination coefficient was slightly decreased at the beginning of the process (Figs. 8 and 9). [Pg.397]

In order to make such brute-force procedures feasible one has to make the computation of coupling coefficients very efficient. It is thereby very instructive to visualize this process using graphical representations [34] of the Cl spaces. As an example of such a graphical representation of a Cl space we consider the case with 3 electrons in 6 spinors. [Pg.312]

In [201] the correlation between heat-transfer coefficient and longitudinal mixing coefficient was revealed. This fact determines expediency of revealing of correlation of heat-transfer processes efficiency in tubular turbulent apparatus with hydrodynamic structure of reaction mixture... [Pg.24]

Heat and mass transfer coefficients can be used to interrogate the importance of external transport phenomena and how to choose reactor size. The latter controls (i) pressure drop, (ii) residence time and thus reactant conversion or flow rate and thus power generated, (iri) the effective reaction rate and thus the process efficiency, (iv) the temperature and (v) whether a system is kinetically controlled and thus ideal for extraction of catalytic kinetics. Another application of Nu and Sh is that a 2D or 3D problem can be reduced to a computationally tractable problem by approximating the transverse transport phenomena using overall transport correlations. Such pseudo-2 D models (also called heterogeneous ID models for catalytic systems) have been used to explore the stability and performance of microbumers with a significantly lower computational effort than CFD models (e.g. [23-25]). [Pg.293]

A model was developed using DynoChem to enable accurate predictions of scale-up to be made. To ensure its validity, experimental data was also fed into the model, from which the necessary scale-up parameters could be derived. RCl data was used to measure the exothermal activity during the reaction and experiments were performed to assess the saturation concentration of chlorine in the solvent mixture. Laboratory and plant scale temperature trials were carried out and the data used to derive actual heat transfer coefficients. The use of DynoChem allowed the data to be processed efficiently. [Pg.1086]

The Carnot cycle is formulated directly from the second law of thermodynamics. It is a perfectly reversible, adiabatic cycle consisting of two constant entropy processes and two constant temperature processes. It defines the ultimate efficiency for any process operating between two temperatures. The coefficient of performance (COP) of the reverse Carnot cycle (refrigerator) is expressed as... [Pg.352]

Design Methods for Calciners In indirect-heated calciners, heat transfer is primarily by radiation from the cyhnder wall to the solids bed. The thermal efficiency ranges from 30 to 65 percent. By utilization of the furnace exhaust gases for preheated combustion air, steam produc tion, or heat for other process steps, the thermal efficiency can be increased considerably. The limiting factors in heat transmission he in the conductivity and radiation constants of the shell metal and solids bed. If the characteristics of these are known, equipment may be accurately sized by employing the Stefan-Boltzmann radiation equation. Apparent heat-transfer coefficients will range from 17 J/(m s K) in low-temperature operations to 8.5 J/(m s K) in high-temperature processes. [Pg.1211]

This equation, although originating from the plate theory, must again be considered as largely empirical when employed for TLC. This is because, in its derivation, the distribution coefficient of the solute between the two phases is considered constant throughout the development process. In practice, due to the nature of the development as already discussed for TLC, the distribution coefficient does not remain constant and, thus, the expression for column efficiency must be considered, at best, only approximate. The same errors would be involved if the equation was used to calculate the efficiency of a GC column when the solute was eluted by temperature programming or in LC where the solute was eluted by gradient elution. If the solute could be eluted by a pure solvent such as n-heptane on a plate that had been presaturated with the solvent vapor, then the distribution coefficient would remain sensibly constant over the development process. Under such circumstances the efficiency value would be more accurate and more likely to represent a true plate efficiency. [Pg.451]


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