Circular dichroism spectra and

Schreiner, A. F., Hauser, P. J. Magnetic circular dichroism spectra and electronic structures of tris(dialkyldithiocarbamato)chromium(lII) molecules, Cr(R2tc)s, and others. Inorg. Chem. II, 2706 (1972). [Pg.117]

Larson, E., S. F. Mason, and G. H. Searle The Adsorption and the Circular Dichroism spectra and the Absolute Configuration of the Tris-Acetylacetonato Silicon (IV) Ion. Acta chem. Scand. 20,191—196(1966). [Pg.50]

Mori T, Inoue Y, Grimme S (2007) Quantum chemical study on the circular dichroism spectra and specific rotation of donor-acceptor cyclophanes. J Phys Chem A 111 7995-8006... [Pg.126]

The best characterized species is [Os2(N2)(NH3)10]5+ made as a bromide or as a tosylate from reaction of [0s(H20)(NH3)s]3+ with [Os(N2)(NH3)5]2+ in the presence of zinc amalgam. The stability of the mixed valence system (formally Os111 11) has been ascribed to electronic delocalization effects and an MO scheme proposed,2 0s but it is not clear why it appears to be more stable than its reduction product, [Os(N2)(NH3),0]4+. Magnetic circular dichroism spectra and cyclic voltammetry of the ion have been measured.28011 A number of other mixed homonuclear species are known, viz. [0s2(N2)(NH3)9(H20)]s+, [Os2(N2)(NH3)9C1]4+, [Os2(N2)(NH3)8C12]3+ and... [Pg.556]

Fig. 6. Circular dichroism spectra and absorption spectra of native human hemoglobin A. The ellipticities (6)...

AFGP components are in an expanded state as based on data from intrinsic viscosity, circular dichroism spectra, and diffusion by ultracentrifugation or quasi-elastic light scattering. Examination of Raman spectra... [Pg.95]

For redox and electron-transfer properties of [Os(bipy)j] + and [Os(phen)3] + see p. 539. Osmium(IIJ). Oxidation of [Os(bipy)3] + with chlorine yields the violet [Os(bipy)3] ion," "" while the red [Os(phen)3] is similarly prepared by oxidation of [Os(phen)3] +.Resolution of [Os(phen3)f + has been achieved by oxidation of Ae corresponding [Os(phen)3] species. Spectroscopic properties. The electronic absorption spectra of [Os(bipy)3] " and of [Os(phen)3] " " have been measured, as have their circular dichroism spectra " "" and also Ae spectra of [Os(4,4 -Me2bipy)3] " The lifetimes of the charge transfer (MLCT) excited states of... [Pg.538]

Protein Secondary Structures Determined by Infrared Spectral Deconvolution and Circular Dichroism Spectra and X-Ray Crystallocraphy ... [Pg.514]

Mack, J. and Stillman, M.J. (2003) Electronic structure of metal phthalocyanine and porphyrin complexes from analysis of the UV-visible absorption and magnetic circular dichroism spectra and... [Pg.268]

Aaniouche, A. Devlin, F.J. Stephens. P.J. Structure, vibrational absorption and circular dichroism spectra, and absolute configuration of Troger s base. J. Am. Chem. Soc. 2000, 122, 2346-2354. [Pg.1523]

Peptides fall on the borderline between this section and the next one. I wish to mention one example of the peptide work here. Bjdrneras and co-workers studied membrane interaction properties of two single residue variants of the 17-amino acid neuropeptide dynorphin A. Along with circular dichroism spectra and other NMR data, the authors reported PRE results caused by two paramagnetic probes (a nitroxide and the Mn(ii) ion) and were able to demonstrate large differences between the two variants interacting with phospholipid bicelles. [Pg.286]

Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...