3- Chloro-3-methylhexane

Because addition converts sp hybridized carbons to s[ hybridized carbons, however, sometimes new stereogenic centers are formed from hydrohalogenation. For example, Markovnikov addition of HCl to 2-ethyl-1-pentene, an achiral alkene, forms one constitutional isomer, 3-chloro-3-methylhexane. Because this product now has a stereogenic center at one of the newly formed sp hybridized carbons, an equal amount of two enantiomers—a racemic mixture—must form. 

What three alkenes (excluding stereoisomers) can be used to prepare 3-chloro-3-methylhexane by addition of HCI ... 

C7H15CI 3-chloro-3-methylhexane 43197-78-0 239.33 21.251 2 12214 C7H160 ethyl isopentyl ether 628-04-6 177.80" 4.137 2... 

Does 3-chloro-3-methylhexane have optical isomers Why or why not ... 

A mixture of 20.5 g (0.08 mol) of 7-benzyl-3-methylxanthine, 12.4 g (0.09 mol) of potassium carbonate and 13.61 g (0.09 mol) of above l-chloro-5-hydroxy-5-methylhexane in 300 ml of dimethylformamide is heated at 110° to 120°C for 8 hours, while stirring, and is then filtered hot and the filtrate is evaporated under reduced pressure. The residue is taken up in chloroform, the mixture is washed first with 1 N sodium hydroxide solution and then with... 

Draw formulas for all structural isomers of the mono-chloro compound produced by treating a limited quantity of CI2 with (a) 2-methylhexane and (b) 3-methylhexane. 

The product formed in largest amount by the hydrochloric acid-promoted and peroxide-induced reaction of isopentyl chloride with ethylene was also that formed by alkylation at the tertiary carbon atom, namely 1-chloro-3,3-dimethylpentane (Ig.) (Expt. 25). The remaining constituents of the reaction product were all obtained in very minor amount and were all alkyl chlorides. Among these were 4-chloro-2-methylhexane (y), 1-chlorohexane (formed by telomerization) and some chlorononanes including 5-chloro-3,3-dimethyl-heptane (3 ) formed by ethylation of 12, 4-chloro-2-methyloctane (15) and l-chloro-3-methyloctane (IT). ... 

C7H1402 tert-butyl propanoate 20487-40-5 414.55 41.093 2 11997 C7H15CI 1 -chloro-3-methylhexane 101257-63-0 424.15 35.572 1,2... 

C7H15CI 2-chloro-5-methylhexane 58766-17-9 239.33 21.251 2 12213 C7H160 2-ethoxy-2-nnethyl butane 919-94-8 177.80 4.137 2... 

When a compound that contains an asymmetric carbon undergoes a reaction, what happens to the configuration of the asymmetric carbon depends on the reaction. If the reaction does not break any of the four bonds to the asymmetric carbon, then the relative positions of the groups bonded to the asymmetric carbon will not change. For example, when (6 )-l-chloro-3-methylhexane reacts with hydroxide ion, OH substitutes for Cl. The reactant and the product have the same relative configuration because the reaction does not break any of the bonds to the asymmetric carbon. 

Name is incorrect. Numbering should go the other way (right to left), giving 3-chloro-2-methylhexane. 

Give the structures of all possible products when 2-chloro-2-methylhexane reacts by the El mechanism. 

---