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Chemical reactivity ligand-exchange reactions

B.l.a. Water eocchange rates. Water-exchange rates are key guides of chemical reactivity in aqueous coordination compounds. Aqueous metal-ligand complexation reactions take place through the diffusion-limited formation of an electrostatic ion pair,... [Pg.416]

The acid-base properties of an aquo complex stem from the polarization of the coordination water (see Chapter 1). The reactivity of complexes in nucleophilic reactions such as ligand exchange and condensation is mostly controlled by the polarity of the bonds (see Chapter 2). In order to predict the likelihood of a reaction, it is useful to know the electronic density distribution in the chemical entity, which is given by the partial charges on individual atoms. [Pg.266]


See other pages where Chemical reactivity ligand-exchange reactions is mentioned: [Pg.192]    [Pg.301]    [Pg.229]    [Pg.2]    [Pg.192]    [Pg.690]    [Pg.28]    [Pg.690]    [Pg.78]    [Pg.50]    [Pg.286]    [Pg.236]    [Pg.94]    [Pg.458]    [Pg.143]    [Pg.2321]    [Pg.139]    [Pg.175]    [Pg.6209]    [Pg.21]    [Pg.354]    [Pg.131]    [Pg.6208]    [Pg.191]    [Pg.17]    [Pg.3316]    [Pg.211]    [Pg.2321]    [Pg.183]    [Pg.76]    [Pg.158]    [Pg.187]    [Pg.533]    [Pg.234]    [Pg.45]    [Pg.5762]    [Pg.1425]    [Pg.1473]    [Pg.61]    [Pg.5761]    [Pg.342]    [Pg.113]    [Pg.146]    [Pg.357]    [Pg.247]   
See also in sourсe #XX -- [ Pg.278 ]

See also in sourсe #XX -- [ Pg.278 ]




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Chemical exchange

Chemical reaction reactivity

Chemical reactions exchange

Exchange reactions chemical reactivity

Ligand exchange

Ligand exchange reactions

Ligand exchange reactivity

Ligand reactivity

Ligands ligand exchange

Ligands, chemical

Reactivation reaction

Reactive Chemical Reactions

Reactive ligands

Reactivity reaction

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