Chemical precipitation process

Residuals Produced Resulting metal sludges from the chemical precipitation process may require further treatment prior to disposal. The effluent pH may require an adjustment before it may be discharged. Dissolved inorganics present in the effluent may pose a problem for direct discharge. 

The presentation finally descends on the very last of the listed chemical precipitation processes, and this pertains to precipitation implemented by carbonate anions (CO-). The dissolution of carbon dioxide takes place with the formation of the weak diabasic acid, H2C03. The overall dissociation of this acid (dissociation constant, KD) is represented by ... 

The penultimate categorization of the chemical precipitation processes detailed in this chapter is reduction. The process basically involves electron transfer from different ions. The reductive precipitation may be either homogeneous (which may be ionic or non-ionic), or heterogeneous (which may be electrochemical or electrolytic). Electrolytic processes are described in Chapter 6, and no account of these need be given here. 

Essentially, Wang s innovative technology [68] is a combined biological-chemical precipitation process involving the use of the following process steps ... 

Chromic oxide/hydroxide sludges resulting from chemical precipitation processes may be dissolved in chromic acid, which is then treated, as above, to obtain a high-concentration Cr(vi) liquor ... 

Selectivity Due to the chemical nature of the precipitation process, precipitants are usually not selective for a single analyte. For example, silver is not a selective precipitant for chloride because it also forms precipitates with bromide and iodide. Consequently, interferents are often a serious problem that must be considered if accurate results are to be obtained. 

The removal of copper from the pregnant nickel solution in the Sherritt-Gordon process is an example of purification by precipitation of a fairly insoluble compound. First, in the copper boil step, ammonia is driven off by heating the solution, and some copper sulfide precipitates. The residual copper is removed by a dding hydrogen sulfide for the chemical precipitation of mote copper sulfide. 

Chemical precipitation and solvent extraction are the main methods of purifying wet-process acid, although other techniques such as crystallisa tion (8) and ion exchange (qv) have also been used. In the production of sodium phosphates, almost all wet-process acid impurities can be induced to precipitate as the acid is neutralized with sodium carbonate or sodium hydroxide. The main exception, sulfate, can be precipitated as calcium or barium sulfate. Most fluorine and siUca can be removed with the sulfate filter cake as sodium fluorosiUcate, Na2SiFg, by the addition of sodium ion and control of the Si/F ratio in the process. 

Solvent extraction—purification of wet-process phosphoric acid is based on preferential extraction of H PO by an organic solvent vs the cationic impurities present in the acid. Because selectivity of acid over anionic impurities is usually not sufficient, precipitation or evaporation steps are included in the purification process for removal. Cmde wet-process acid is typically concentrated and clarified prior to extraction to remove post-precipitated sludge and improve partition of the acid into the solvent. Concentration also partially eliminates fluoride by evaporation of HF and/or SiF. Chemical precipitation of sulfate (as Ba or Ca salts), fluorosiUcates (as Na salt), and arsenic (as sulfides) may also be used as a prepurification step preceding solvent extraction. 

Bismuth vanadate can be produced by chemical precipitation, as weU as by high temperature calciaation methods. In the wet process, the acidic solution of bismuth nitrate, Bi(N02)3, is mixed with the alkaline solution of sodium vanadate, Na VO. The gel formed is filtered off on a filter, pressed, washed, and converted to a crystalline form by calciaation at low temperatures of 200—500°C for 1 h (37,38). 

The first equation is an example of hydrolysis and is commonly referred to as chemical precipitation. The separation is effective because of the differences in solubiUty products of the copper(II) and iron(III) hydroxides. The second equation is known as reductive precipitation and is an example of an electrochemical reaction. The use of more electropositive metals to effect reductive precipitation is known as cementation. Precipitation is used to separate impurities from a metal in solution such as iron from copper (eq. 1), or it can be used to remove the primary metal, copper, from solution (eq. 2). Precipitation is commonly practiced for the separation of small quantities of metals from large volumes of water, such as from industrial waste processes. 

Chemical Precipitation. The product of the extraction processes, whether derived from acid or carbonate leach, is a purified uranium solution that may or may not have been upgraded by ion exchange or solvent extraction. The uranium ia such a solution is concentrated by precipitation and must be dried before shipment. Solutions resulting from carbonate leaching are usually precipitated directly from clarified leach Hquors with caustic soda without a concentration step, as shown ia equation 9. 

Clarifiers typically are used in chemical precipitation and biological treatment processes to remove precipitated metal soHds and suspended biological soHds. To prevent the sludge blanket from becoming too thick or heavy, part of the sludge blanket is removed continuously or intermittently from the system and thickened prior to disposal. 

In secondary operations, where chemicals are injected into hydrocarbon formations in conjunction with a chemical flooding process, polyamines are used to reduce the loss of injected chemicals to the formation by adsorption and precipitation (312). TEPA and other ethyleneamines are used with water-soluble polymeric thickeners in water—flood petroleum recovery operations to stabilize viscosity, mobiUty, and pH while imparting resistance to hydrolysis (313). 

The standard methods of drying can be classified as deposition of the moisture as either water or ice decomposition of the water chemical precipitation absorption adsorption mechanical separation and vaporization. The completeness with which dryness can be accomplished by any process depends upon the factors controlling the equilibrium conditions achieved in the operation. A brief discussion of each method is first given. 

Technology Description The function of reduction processes is to convert inorganics to a less toxic and/or more easily treated form. It also serves as a pretreatment step for inorganics in which chemical precipitation is used to remove the metal hydroxide from solution. 

Phosphorous removal is most commonly done by chemical precipitation with iron or aluminum compounds, such as ferric chloride or alum (aluminum sulfate). The solids which are produced can be settled along with other sludges, depending on where in the treatment train the process takes place. "Lime", or... 

Chemical precipitation Precipitation induced by addition of chemicals the process of softening water by the addition of lime and soda ash as the precipitants. Chloramines Compounds formed by the reaction of hypochlorous acid (or aqueous chlorine) with ammonia. 

End-of-pipe treatment refers to the application of chemical, biological, and physical processes to reduce the toxicity or volume of downstream waste. Treatment options include biological systems, chemical precipitation, flocculation, coagulation, and incineration as well as boilers and industrial furnaces (BIFs). 

Budz, J., Jones, A.G. and Mullin, J.W., 1987b. Agglomeration of potassium sulphate in an MSMPR crystallizer. In Fundamental aspects of crystallization and precipitation processes, American Institute of Chemical Engineers. Symposium Series, No. 253, 83, New York American Institute of Chemical Engineers, pp. 78-84. 

Franke, J. and Mersmann, A., 1995. The influence of the operational conditions on the precipitation process. Chemical Engineering Science, 50, 1737-1753. 

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