Caustic oxidizing media

The chemical inertness of diamond, even in hot acidic or caustic oxidizing media [81], and the possibility of making conductive CVD diamond films with resistivities down to less than 0.01 Hem [82] on a wide variety of substrates and over large areas, has in the recent years stimulated an increased interest in applications for analytical and preparative electrochemistry. In a comparative study, Swain... 

It hydrolyses in acidic medium to form HC1 and nonvolatile (solid) chlorovinylarsenious oxide, which is a less potent vesicant than ED. Hydrolysis in alkaline medium, as in decontamination with alcoholic caustic or carbonate solution, produces acetylene and trisodium arsenate (Na3AS04). 

HYDROXIDE de POTASSIUM (French) (1310-58-3) see potassium hydroxide. HYDROXY No. 253 (25154-52-3 84852-15-3) see nonylphenol. HYDROXYACETIC ACID (79-14-1) C2H4O3 Combustible solid.Dust may form explosive mixture with air (Fire Rating 1). Aqueous solution is a medium-strong organic acid. Incompatible with sulfuric acid, caustics, ammonia, aliphatic amines, isocyanates, alkylene oxides, epichloro-hydrin, strong oxidizers. In heat of decomposition (above 212°F/100°C) or fire, carbon dioxide and carbon monoxide may be formed. 

OXALIC ACID (144-62-7) CjHjO. HOOCCOOH Combustible solid heat-sensitive. (combustible <215 F/101°C. Fire Rating 1). Exposure to elevated temperatures, hot surfaces, or flames causes decomposition and the formation of toxic and flammable formic acid and carbon monoxide. Hygroscopic the solution in water is a medium-strong acid. Violent reaction with strong oxidizers, acid chlorides alkali metals bromine, furfuryl alcohol hydrogen peroxide (90%) phosphorus trichloride silver powders sodium, sodium chlorite sodium hypochlorite urea + heat (forms NHj gas, CO2 and CO may explode). Mixture with some silver compounds forms explosive salts of silver oxalate. Incompatible with caustics, mercury, urea. On small fires, use dry chemical powder (such as Purple-K-... 

SULFUROUS OXIDE (7446-09-5) SO, Noncombustible liquefied gas under pressure or liquid. Contact with air forms hydrogen chloride fumes. Violent reaction with water or steam, forming sulfurous acid, a medium-strong acid and corrosion hazard. Reacts violently with acetylene, acrolein, alcohols, aluminum powder alkali metals (i.e., potassium, sodium) amines, ammonia, bromine pentafluoride butadiene caustics, cesium acetylene carbide chlorates, chlorine trifluoride chromium powder copper or copper alloy powders chlorine, diethylzinc, fluorine, ethylene oxide lead dioxide lithium acetylene carbide diamino-, metal powders monolithium acetylide-ammonia nitryl chloride potassium acetylene carbide potassium acetylide, potassium chlorate rubidium carbide silver azide sodium acetylide staimous oxide. Decon oses in... 

ACIDO HIDROXIACETICO (Spanish) (79-14-1) Combustible solid. Dust forms an explosive mixture with air. Aqueous solution is a medium-strong organic acid. Incompatible with sulfuric acid, caustics, ammonia, aliphatic amines, isocyanates, alkylene oxides, epichlorohydrin, strong oxidizers. 

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