Cathodic paints

Comparative data showing the flux versus time performance of the XM50 membrane versus that of the newly developed "charged" membranes on cathodic paint (PPG). The designation Xj and X2 refer to different "charge density" levels... 

Figure 3.63 Effect of "charged" membrane on long term flux decay with cathodic paint.

Figure 3.87 UF of electrocoat paint-stability of cathodic paint with CXM membrane (positively charged).

Figure 2.16 Ultrafiltration of cathodic paint using charged membranes (X1/X2) and a standard hollow-fibre membrane element. Source Romicon.

Cobalt is used as a blue phosphor in cathode ray tubes for television, in the coloration of polymers and leather goods, and as a pigment for oil and watercolor paints. Organic cobalt compounds that are used as colorants usually contain the azo (51) or formazon (52) chromophores. 

At first sight, the answer would seem to be to increase the thickness of the zinc layer. This is not easily done, however, because the hot dipping process used for galvanising is not sufficiently adjustable and electroplating the zinc onto the steel sheet increases the production cost considerably. Painting the sheet (for example, with a bituminous paint) helps to reduce the loss of zinc considerably, but at the same time should vastly decrease the area available for the cathodic protection of the steel and if a scratch penetrates both the paint and the zinc, the exposed steel may corrode through much more quickly than before. 

The anodic oxidation of the iron is usually localized in surface pits and crevices which allow the formation of adherent rust over the remaining surface area. Eventually the lateral extension of the anodic area undermines the rust to produce loose flakes. Moreover, once an adherent film of rust has formed, simply painting over gives but poor protection. This is due to the presence of electrolytes such as iron(II) sulfate in the film so that painting merely seals in the ingredients for anodic oxidation. It then only requites the exposure of some other portion of the surface, where cathodic reduction can take place, for rusting beneath the paint to occur. 

To avoid galvanic problems, different materials of con-stmction may have to be electrically isolated or at least the electrical resistance between them increased to a level sufficient to reduce the corrosion current to an acceptable value. In some instances it is more practical to paint or otherwise coat the more cathodic of the two parts of the couple. The anodic material should not be coated, since even more rapid penetration would occur at any breaks in the coating. 

Saponification Paints are most commonly used to protect steel from corrosion by seawater in marine applications and soil in the case of buried structures. Additional protection is often supplied by the application of cathodic protection to the steel. Any paint coating used in conjunction with cathodic protection must be resistant to the alkali which is produced on the steel at defect sites in the coating. The amount of alkali generated depends on the potential to which the steel is polarized. Some paint binders such as alkyds and vinyl ester are very susceptible to saponification, and should not be used on cathodically protected structures. Cathodic disbondment testing should be undertaken if the relevant information is not available. 

Epoxy based primer systems remain the best suited for the corrosion protection of magnesium. Cathodic epoxy electrophoretic paints , chromate inhibited epoxy-polyamide primers and high temperature stoving epoxy sealers are used to provide protection up to 180°C. For higher temperature applications up to 300°C, epoxy silicone or polyimide based systems can be used. 

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