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Catalytic bond formation palladium-catalyzed cross-coupling

During the past few decades, transition metal-catalyzed cross-coupling reactions have become a powerful tool for the construction of C—C and C-heteroatom bonds [1]. This strategy allows the conceptually simple and yet powerful and reliable approach for synthesizing structurally complex pharmaceuticals and biologically active molecules. The two most vastly used transition metal catalysts in carbon-heteroatom bond formation are palladium (mainly depends on its ancillary ligands) and copper (depends on the optimization of the catalytic system as a whole copper source, solvent, base, concentrations, etc.). Besides, considerable developments have also been made with other transition metal catalysts such as nickel, iron, etc. [Pg.547]


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Bond crossing

Catalytic bond formation

Cross palladium

Cross palladium-catalyzed

Palladium bonding

Palladium coupling

Palladium-catalyzed bond formations

Palladium-catalyzed coupling

Palladium-catalyzed cross-coupling

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