Carbonochloridothioates

Thioesters have been used for carbon-carbon bond formation in transition metal-catalysed Grignard reactions. In the accompanying scheme two sequential cross-coupling reactions with 5-phenvl carbonochloridothioate and Grignard reagents led to a general and efficient ketone synthesis [377,378]. [Pg.62]

S-Phenyl carbonochloridothioate, C6H5SCQ ( 1,4-Keto aldehydes or 1,4-diones. Reai... [Pg.254]

Phenyl chlorothionoformate Formic acid, chlorothio-, O-phenyl ester (8) Carbonochloridothioic acid, O-phenyl ester (9) (1005-56-7)... [Pg.125]

Carbonoohloridothioic acid, S-ethyl ester CCRIS 4642 EINECS 220-928-1 Ethyl chlorothioformate Ethyl thiochloroformate Ethylthiooarbonyl chloride Ethylthiol chloroformate Formic acid, chlorothio-, S-ethyl ester HSDB 5906 S-(Ethyl)chlorothioformic acid S-Ethyl carbonochloridothioate S-Ethyl chlorothiocarbonate UN2826,... [Pg.280]

Beilstein Handbook Reference) AI3-52665 BRN 1633747 Carbonochloridothioic acid, S-propyl ester CCRIS 6097 EINECS 237-656-4 Formic acid, chlorothio-, S-propyl ester HSDB 6155 NSC 72086 Propyl chlorothiofbrmate n-Propyl chloro-thioformate S-Propyl chlorothioformate n-Propyl thiochlorofbrmate ... [Pg.525]

Alternate Name 0-(4-chlorophenyl) carbonochloridothioate. Physical Data bp 82 °C/0.8 mmHg 114-116°C/0.8inmHg. Form Supplied in distillable liquid commercially available. Preparative Method from thiophosgene and p-chlorophenol in the presence of sodium hydroxide. ... [Pg.136]

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