Ethyl chlorothioformate

Ethanol amine dinitrate Ethyl chlorothioformate Ethylene chlorohydrin... 

The extended (two-term) Grunwald-Winstein equation has been applied to the solvolyses of ethyl chloroformate (117) and ethyl chlorothioformate (118). For each substrate, there is evidence for two competing reaction channels. " Solvolysis... 

Molinate (27) (65USP3198786) is simply made from perhydroazepine and 5-ethyl chlorothioformate, while the recently introduced pyrazolate (28) (75GEP2513750) is synthesized from l,3-dimethylpyrazol-5-one, itself easily made from methylhydrazine and ethyl acetoacetate. Reaction of the pyrazolone with 2,4-dichlorobenzoyl chloride takes place on carbon at the 4-position, and then treatment with toluene-p-sulfonyl chloride gives pyrazolate. Difenzoquat (29) (75USP3922161) is readily available from 3,5-diphenylpyrazole by methylation. Ethofumesate (30) (69GEP1926139) is synthesized from p-benzoquinone (Scheme 8). 

Thiadiazine-2,4,6-triones can be prepared by ring closure of A-(aminothiocarbonyl)-dithiocarbamates with ethyl chlorothioformate (see Section 6.18.10.2.3.ii), and by treating 1,3,5-oxadiazine-2,4,6-trione with hydrogen sulfide (see Section 6.18.11.2). Condensation of 1-chloro- or... 

ETHYL CHLOROTHIOFORMATE (2941-64-2) Forms explosive mixture with air (flash point 86°F/19°C). Reacts with moisture in air, forming hydrogen chloride fumes. Reacts slowly with water or steam, forming hydrochloric acid, carbon dioxide gas, and ethanol. Violent reaction with alkali metals, dialkylzincs, dimethyl formamide, dimethyl sulfoxide, ethers, ethylene glycol diethyl ether, strong oxidizers. Incompatible with strong bases. Corrodes metals in the presence of moisture. Attacks some plastics, rubber, and coatings. 

Carbonoohloridothioic acid, S-ethyl ester CCRIS 4642 EINECS 220-928-1 Ethyl chlorothioformate Ethyl thiochloroformate Ethylthiooarbonyl chloride Ethylthiol chloroformate Formic acid, chlorothio-, S-ethyl ester HSDB 5906 S-(Ethyl)chlorothioformic acid S-Ethyl carbonochloridothioate S-Ethyl chlorothiocarbonate UN2826,... 

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