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Carbonic acid dichlorides mixed

Mixed orthocarbonic acid esters from carbonic acid dichlorides... [Pg.326]

The solvents most commonly employed are water, ethyl and methyl alcohol, ether, benzene, petroleum ether, acetone, glacial acetic acid also two or three solvents may be mixed to get the desired effect as described later. If you still cannot dissolve the compound, try some of these chloroform, carbon disulfide, carbon tetrachloride, ethyl acetate, pyridine, hydrochloric acid, sulfuric acid (acids are usually diluted first), nitrobenzene, aniline, phenol, dioxan, ethylene dichloride, di, tri, tetrachloroethylene, tetrachloroethane, dichloroethyl ether, cyclohexane, cyclohexanol, tetralin, decalin, triacetin, ethylene glycol and its esters and ethers, butyl alcohol, diacetone alcohol, ethyl lactate, isopropyl ether, etc. [Pg.10]

It is known that dissolving chlorine in water leads to a solution that contains hypochlorous acid (HOCl) and bromine dissolved in water contains hypobromous acid (HOBr). In one experiment, 1-pentene is mixed with chlorine and water (HOCl in aqueous media) and the major product is l-chloro-2-pentanol (48), in 43% isolated yield. ° In the previous section, chlorine reacted with 1-pentene in a nonaqueous solvent such as carbon tetrachloride to give a dichloride. To ascertain why this reaction is different, the first useful observation is that HOCl is in solution rather than Cl-Cl. The polarization of HOCl is HO -Cl, where chlorine is the electrophilic atom. The 7t-bond of an alkene should react with the positive chlorine atom, and cleavage of the Cl-H bond will give hydroxide ion, which is a... [Pg.440]


See other pages where Carbonic acid dichlorides mixed is mentioned: [Pg.133]    [Pg.314]    [Pg.1014]    [Pg.133]    [Pg.239]    [Pg.41]    [Pg.877]    [Pg.314]    [Pg.45]    [Pg.415]    [Pg.596]    [Pg.309]    [Pg.280]    [Pg.280]    [Pg.43]    [Pg.314]   
See also in sourсe #XX -- [ Pg.17 , Pg.258 ]




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Carbon mix

Carbonic acid dichlorides

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