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Carbon tetrafluoride-hydrogen

Representing a two electron covalent bond by a dash (—) the Lewis structures for hydrogen fluoride fluorine methane and carbon tetrafluoride become... [Pg.13]

Initial attempts at reactions between fluorine and hydrocarbons were described as similar to combustion and the reaction products contained mostly carbon tetrafluoride and hydrogen fluoride ... [Pg.273]

Depending on the ring substituent, trifluoromethoxyben2enes can be made by the sequential chlorination—fluorination of anisole(s) (351—354). A one-step process with commercial potential is the BF (or SbF2)-cataly2ed reaction of phenol with carbon tetrachloride/hydrogen fluoride (355). Aryl trifluoromethyl ethers, which may not be accessible by the above routes,may be made by fluorination of aryl fluoroformates or aryl chlorothioformates with sulfur tetrafluoride (348) or molybdenum hexafluoride (356). [Pg.333]

Because PTFE resins decompose slowly, they may be heated to a high temperature. The toxicity of the pyrolysis products warrants care where exposure of personnel is likely to occur (120). Above 230°C decomposition rates become measurable (0.0001% per hour). Small amounts of toxic perfiuoroisobutylene have been isolated at 400°C and above free fluorine has never been found. Above 690°C the decomposition products bum but do not support combustion if the heat is removed. Combustion products consist primarily of carbon dioxide, carbon tetrafluoride, and small quantities of toxic and corrosive hydrogen fluoride. The PTFE resins are nonflammable and do not propagate flame. [Pg.355]

Caibon has eight electrons in its valence shell in both methane and carbon tetrafluoride. By forming covalent bonds to four other atoms, carbon achieves a stable electron configuration analogous to neon. Each covalent bond in methane and carbon tetrafluoride is quite strong—comparable to the bond between hydrogens in Fl2 in bond dissociation energy. [Pg.13]

Hydrogen fluoride Fluorine Methane Carbon tetrafluoride... [Pg.13]

The anodic oxidation of alkanes on a platinum anode in anhydrous hydrogen fluoride19 at low potentials is accompanied by exhaustive fluorination, with all of the hydrogen atoms being replaced by fluorine. Thus, the major fluorination products of methane and propane are carbon tetrafluoride and octafluoropropane, respectively. [Pg.308]

Adamantanecarboxylic acids with a carboxylic group at a bridgehead position, e.g. adaman-tane-1-carboxylic acid (8),111 react with sulfur tetrafluoride in the conventional way giving high yields of the corresponding trifluoromethyl-substituted adamantanes. l-(Trifluoromethyl)-adamantane (9) can also be formed in one step from adamantane by treatment with a mixture of sulfur tetrafluoride, hydrogen fluoride and formic acid the latter serves as a source of carbon monoxide. The reaction is believed to proceed via carbonylation of an intermediate carbocat-... [Pg.351]

Uranium(VI) fluoride is a colorless solid which sublimes at 56.2°C it does not exist as a liquid at atmospheric pressure. It is soluble in l,l,2-trichloro-l,2,2-trifluorocthane (Freon 113). hydrogen fluoride, and chlorohydrocarbons, although it will react31 slowly with the latter it cleaves some ethers12-13 and reacts vigorously32 with carbon disulfide to give sulfur tetrafluoride, carbon tetrafluoride, bis(trifluoromethyl) disulfide, and bis(trifluoromethyl) trisulfide. [Pg.681]

Since the time of the earliest work concerned with the reaction of hydrocarbons and fluorine in 1890 by Moissan (who isolated fluorine in 1886), numerous difficulties have been reported. According to Lovelace et al the action of fluorine on a carbon compound can be likened to a combustion process where the products are carbon tetrafluoride and hydrogen fluoride (1). [Pg.162]

Carbonyl fluoride can be prepared by any of several methods, including the conversion of carbonyl chloride to the fluoride by such reagents as hydrogen fluoride1 and antimony (III) fluoride.2 The direct combination of carbon monoxide and fluorine is another route to this fluoride, but carbon tetrafluoride is a by-product of the reaction.8 A particularly suitable laboratory preparation of carbonyl fluoride is the fluorination of carbon monoxide by silver (II) fluoride.4 This method, described below, gives directly carbonyl fluoride of rather high purity without recourse to a low-temperature distillation. [Pg.155]


See other pages where Carbon tetrafluoride-hydrogen is mentioned: [Pg.130]    [Pg.283]    [Pg.2]    [Pg.138]    [Pg.292]    [Pg.9]    [Pg.491]    [Pg.114]    [Pg.137]    [Pg.308]    [Pg.316]    [Pg.318]    [Pg.994]    [Pg.311]    [Pg.101]    [Pg.1060]    [Pg.558]    [Pg.114]    [Pg.137]    [Pg.134]    [Pg.499]    [Pg.812]    [Pg.14]    [Pg.176]    [Pg.178]    [Pg.169]    [Pg.5]   
See also in sourсe #XX -- [ Pg.265 ]




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