Carbon tetrachloride thermodynamic properties

Hill, J.O., Worsley, EG., and L.G. Hepler. Calorimetric determination of the distribution coefficient and thermodynamic properties of bromine in water and carbon tetrachloride, J. Phys. Chem., 72(10) 3695-3697, 1968. 

The results established in the preceding paragraph may be verified by comparing the thermodynamic properties and the spectroscopic properties of associated solutions. Let us consider, for example, a solution of ethanol in carbon tetrachloride. The valency vibration of the OH group gives rise to two distinct infra-red absorption bands depending upon whether the OH group is in a monomer or in an associated complex. The fraction of molecules of alcohol which remain in the monomeric state can therefore be determined from measurements... 

Rychlicki, G., Terzyk, A.P., and Zawadzki, J. (1994). The influence of carbon surface oxidation on thermodynamic properties of carbon-tetrachloride adsorbed at different temperatures. Polish J. Chem., 68, 557-63. 

Inoue et al. [150] demonstrated that large amounts of carbon tetrachloride can be absorbed into 1-dimensional tunnels in copper(II) trans-1,4-cyclohexane dicarboxylate (Figure 14) under the saturated vapour pressure at room temperature, and the desorption can be performed easily by evacuation above room temperature. It was also confirmed that the absorption/desorption is reversible. The thermodynamic and structural properties were studied for the empty (non-absorbed) sample and partially-filled (10, 22 and 31% of the fiill carbon tetrachloride-absorbed) samples, using adiabatic calorimetry between 13 and 300 K and by powder XRD with high-energy synchrotron radiation. The heat- capacity anomaly due to the first-order phase transition observed in the empty sample was not observed in the fully-absorbed sample. However, the partially absorbed samples showed smaller heat-capacity anomalies at lower temperatures than the empty sample. Such phenomena were compared with the previous results for toluene-absorbed samples [151-153] and tfie differences were discussed. 

Buchner R, Hefter G (2009) Interactions and dynamics in electrolyte solutions by dielectric spectroscopy. Phys Chem Chem Phys 11 8984—8999 Cabani S, Gianni P, MoUica V, Lepori L (1981) Group contributions to the thermodynamic properties of non-ionic organic solutes in dilute aqueous solutions. 1 Solut Chem 10 563-595 Caldin EF, Bennetto HP (1971) Solvent effects on the kinetics of the nickel(ll) and cobalt(ll) ions with 2,2 -bipyridyl and 2,2, 2"-terpyridyl. J Chem Soc A 1971 2191-2198 Chang T-M, Dang LX (2008) Computational studies of liquid water and diluted water in carbon tetrachloride. J Phys Chem A 112 1694—1700... 

Barker, J. A. Brown, I. Smith, F. Thermodynamic properties of alcohol solutions. The system ethanol + carbon tetrachloride... 

SAN Chemical Properties and Analytical Methods. SAN resins show considerable resistance to solvents and are insoluble in carbon tetrachloride, ethyl alcohol, gasoline, and hydrocarbon solvents. They are swelled by solvents such as benzene, ether, and toluene. Polar solvents such as acetone, chloroform, dioxane, methyl ethyl ketone, and pyridine will dissolve SAN (239). The interactions of various solvents and SAN copolymers containing up to 52% acrylonitrile have been studied, along with their thermodynamic parameters such as the second virial coefficient, free-energy parameter, expansion factor, and intrinsic viscosity (240). 

Otterstedt, J.-E. A. Missen, R. W. Thermodynamic properties of solutions of alcohols and carbon tetrachloride. Part 2. - Heats and entropies of mixing Trans. Faraday Soc. 1962,58, 879-889... 

Papousek, D. Papouskova, Z. Pago, L. Thermodynamic properties offlie carbon tetrachloride - n-propyl alcohol and carbon tetrachloride - iso-propyl alcohol systems at 70.deg.C. Z. Phys. Chem. (Leipzig) 1959, 211, 231-240. 

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