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Carbinol acetates

The a-oxoketene dithioacetal 6.40 is derived from indoxyl (l,2-dihydroindol-3-one), a heterocyclic carbonyl precursor, and its reaction with simple allyl anions will also yield the corresponding Jl-annulation product. Thus when 6.40 was reacted with allyl anions 65 the corresponding carbinol acetals 66 formed insitu underwent smooth BF3.Et20 assisted cyclization to afford the corresponding carbazoles 67 in high yields <99T11563>. [Pg.12]

Interestingly the heteroallyl anion 26 from antipyrine displayed unusual 1,2-mode Type 1 (la) reactivity with 6.40 instead of Type III (3a) reactivity as generally observed in the preceding examples. The carbinol acetal 76 thus formed by 1,2-addition mode was cyclized with BF3.Et20 to afford the corresponding linearly annulated carbazole 77 in 73% yield <99T11563>. [Pg.13]

DIETHYLENE- GLYCOL MONOBUTYL ETHER ACETATE Diglycol Monobutyi Ether Acetate, Butyl Carbinol Acetate, Ektasolve DB Acetate NL 1 0... [Pg.100]

SYNS ACETIC ACID-1,3-DIMETHYLBUTYL ESTER 1,3-DIMETHYLBUTYL ACETATE MAAC METHYL-AMYL ACETATE METHYL AMYL ACETATE (DOT) METHYLISOAMYL ACETATE METHYLISOBUTYL-CARBINOL ACETATE METHYLISOBUTYLCARBINYL ACETATE 4-METHYL-2-PENTANOL, ACETATE 4-METHYL-2-PENTYL ACETATE... [Pg.726]

In a recent very thorough investigation, Behrens and Sharpless studied the possibilities for the selective transformation of 2,3-epoxy-carbinols, -acetals and -amides into azidoalkanols (Scheme 47). The regioselectivity of this process turned out to be strongly dependent on steric as well as electronic parameters it is not possible to discuss details here. [Pg.253]

Synonyms Acetic acid-1,3-dimethylbutyl ester Dimethylbutyl acetate 1,3-Dimethylbulyl acetate s-Hexyl acetate M/tAC Methylisoamyl acetate Methylisobutyl carbinol acetate Methylisobutylcarbinyl acetate 4-Methyl-2-pentanol acetate 4-Methyl-2-pentyl acetate 2-Pentanol, 4-methyl-, acetate En rirical C,H 02 Fmnula CHjCOOCHfCHJC.H,... [Pg.1194]

Amyl-A-valerolactone. See A-Decalactone Amyl vinyl carbinol. See 1-Octen-3-ol Amyl vinyl carbinol acetate Amyl vinyl carbinyl acetate. See 1-Octen-3-yl acetate Amyris. See Amyris (Amyris balsamifera) Amyris (Amyris balsamifera)... [Pg.303]

Methylisobutyl carbinol acetate Methylisobutylcarbinyl acetate. See Methyl amyl acetate... [Pg.2644]

Pentyl propanoate Pentyl propionate n-Pentyl propionate. See Amyl propionate Pentyl salicylate. See Amyl salicylate Pentyltrichlorosilane. See Amyltrichlorosilane Pentyl valerate. See Amyl valerate Pentyl vinyl carbinol. See 1-Octen-3-ol n-Pentyl vinyl carbinol acetate. See 1-Octen-3-yl acetate... [Pg.3251]

Phenethyl methyl ethyl carbinyl acetate CAS 72007-81-9 EINECS/ELINCS 276-282-6 Synonyms 1 -Ethyl-1 -methyl-3-phenylpropyl acetate Phenylethyl methyl ethyl carbinol acetate... [Pg.3286]

Phenylethyl methyl ethyl carbinol. See 1-Phenyl-3-methyl-3-pentanol Phenylethyl methyl ethyl carbinol acetate. See Phenethyl methyl ethyl carbinyl acetate P-Phenylethyl methyl ketone. See Benzyl acetone... [Pg.3319]

METHYL VINYL CARBINOL ACETATE + BUTYLENE GLYCOL... [Pg.595]

Without additional reagents N-Heterocyclic carbinol acetates from N-oxides... [Pg.356]

See other pages where Carbinol acetates is mentioned: [Pg.1456]    [Pg.3]    [Pg.6]    [Pg.18]    [Pg.19]    [Pg.397]    [Pg.140]    [Pg.29]    [Pg.70]    [Pg.1279]    [Pg.1061]    [Pg.58]    [Pg.832]    [Pg.29]    [Pg.72]    [Pg.77]    [Pg.1460]    [Pg.29]    [Pg.1461]    [Pg.1201]    [Pg.825]    [Pg.62]    [Pg.595]    [Pg.133]    [Pg.310]    [Pg.220]   


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Carbinol

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