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Calibration Behavior in Charge Detection

The charge detector contains both anion- and cation-exchange membranes in a configuration to deionize the influent coming from the suppressor. Strongly dissociated ionic species such as hydrochloric acid are removed completely by the [Pg.776]

40 °C eluent 26mmol/L MSA (EG) flow rate lOpL/min injection volume 0.4 pL peaks  [Pg.779]

MSA (EG) flow rate lOpL/min injection volume 0.4 pU detection suppressed conductivity and charge detection (retention time shifted to align sodium peaks) sample primary wastewater effluent peaks (1) sodium, (2) ammonium, [Pg.782]

In contrast to RPLC, UV detection is of minor importance in ion chromatography, but is considered a welcome supplement to conductometric detection. It is a disadvantage of direct UV detection that most inorganic anions do not possess an appropriate chromophore. Thus, they generally absorb at wavelengths below 220 nm [38]. This was corroborated by the works of Reeve [39] and Leuenberger et al. [40], who separated inorganic anions on a chemically bonded cyano- or [Pg.782]

One of the most important applications of UV/Vis detection is photometric determination after derivatization of the column effluent First of all, this includes the determination of transition metals after reaction with 4-(2-pyridylazo)-resorcinol (PAR). [Pg.783]


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