Butane chloroethane

Acrylonitrile, Alachlor. Allyl chloride, Allyl alcohol. Benzene, Butane, Chloroethane, Cyclohexene, Chloroprene, Cvclonentene. Dazomet. 1,1-Dichloroethylene, s/m-Dichloromethyl ether, Dimethylamine, A,lV-Dimethylaniline, 2,3-Dimethylbutane, 1,4-Dioxane, Epichlorohydrin,... 

Acetone, bromoethane, butane, chloroethane, 2-chloropropane, 1,3-cyclopenta-diene, dibromodifluoromethane, 1,1-dichloroethane, 1,1-dichloroethene, 1,2-di-chloro-l,l,2,2-tetra luoroethane, diethylether, dimethoxymethane, dimethylpro-pane, 1,3-epoxypropane, ethyl formate, glyoxal, methyl acetate, methylbutane, methyl formate, methylpropane, -pentane, propanal. 

Alkanes appear to react with platinum(IV) in an identical manner to benzene (34, 84) chloromethane and chloroethane can be detected as the reaction products from methane and ethane, respectively. When propane, butane, or hexane is the reactant, the terminal chloro isomers predominate over the internal isomers. This was interpreted to mean that primary C—H bonds are the most reactive (34), but a more detailed study has shown that this conclusion does not necessarily follow from the experimental results (84). When cyclohexane is the reactant, dehydrogenation (or chlorination and then dehydrohalogenation) occurs to give benzene as one of the reaction products (29, 34, 84). 

Other catalytic reactions carried out in fluidized-bed reactors are the oxidation of naphthalene to phthalic anhydride [2, 6, 80] the ammoxidation of isobutane to mcthacrylonitrilc [2] the synthesis of maleic anhydride from the naphtha cracker C4 fraction (Mitsubishi process [81, 82]) or from n-butane (ALMA process [83], [84]) the reaction of acetylene with acetic acid to vinyl acetate [2] the oxychlorination of ethylene to 1,2-di-chloroethane [2, 6, 85, 86] the chlorination of methane [2], the reaction of phenol with methanol to cresol and 2,6-xylenol [2, 87] the reaction of methanol to gasoline... 

Alcohols and phenols are quite different from the hydrocarbons and alkyl halides we ve studied thus far. Not only is their chemistry much richer, their physical properties are different as well. Figure 17.1, which provides a comparison of the boiling points of some simple alcohols, alkanes, and chloroalkanes, shows that alcohols have much higher boiling points. For example, 1-propanol (MW = 60), butane (MW - 58), and chloroethane (MW = 65) have similar molecular weights, yet 1-propanol boils at 97"C, compared to 0.5°C tor the alkane and 12.5°C for the chloroalkane. 

Acetophenone, 428 p-Anisic acid, 433 Benzaldehyde, 425 Benzene, 414 Benzonitrile, 439 Benzyl alcohol, 421 Bicyclo[2.2.1]heptane, 410 l-Bromo-2-chloroethane, 445 1-Bromohexane, 441 Butane, 406... 

The Wurtz reaction constitutes the direct coupling of the nucleophilic carbon of an alkylsodium compound and the electrophilic carbon in a haloalkane. It is an unselective reaction. There is no way to control it to prevent coupling of two like alkyl groups while attempting to couple two different ones. In other words, the reaction between chloroethane and 1-chloropropane gives a statistical mixture of butane (from two ethyls), pentane (from an ethyl and a propyl), and hexane (from two propyls). 

Chloroethane, butane and propan-l-ol have boiling points of 286 K, 272 K and 371 K, respectively. 

Impurities such as methane, ethane, propane, isobutane, butane, chloromethane, chloroethane, hydrogen chloride, silicon tetrachloride and methyltrichlorosilane can be determined in trichlorosilane by separation on a glass column (4.5 metres x 4mm) packed with silanized silica gel operated at 50 C using nitrogen as carrier gas and flame ionization or thermal conductivity detectors. 

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