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Butane, chemicals from oxidation

Prior to 1975, benzene was catalytically oxidized to produce maleic anhydride, an intermediate in synthesis of polyester resins, lubricant additives, and agricultural chemicals. By 1986 all commercial maleic anhydride was derived from oxidation of / -butane. It is expected that / -butane will remain the feedstock of choice for both economic and environmental reasons. [Pg.49]

For many years the catalytic air oxidation of benzene was the main source of maleic anhydride. Obviously, two carbons from each ring are wasted as carbon dioxide in this process. Although some is still made that way, most modem maleic anhydride plants are based on butane oxidation. Because butane is forecast to be plentiful and low-cost, new routes to four-carbon chemicals from maleic anhydride are under active development. [Pg.144]

The most recent entrant-to the. club of commodity chemicals is 1,4-butanediol (BDO), a petrochemical used in some of the more specialized applications such as chemical intermediates for the production of tetrahydro-furane and gama-butyrolactone, polybutylene terephthalate, and the more familiar polyurethanes. Traditionally, the Reppe process was the primary route to BDO, based bn acetylene and formaldehyde feeds. More recently, the share of BDO from butane and propylene oxide based production has grown rapidly. [Pg.208]

There are two major areas of commercial application of acetic add today food-grade vinegar, which is largely the product of bacterial oxidative conversion of diluted purified alcohol or alcoholic mashes from various fruits and grains, and chemically synthesized industrial acetic acid, 62 % of which is produced by carbonylation of methanol and the rest by oxidation of -butane. Chemically synthesized acetic acid is a commodity chemical that has become a major feedstock for the United States and worldwide chemical industry. O Figure 1.5 displays the major chemicals derived from acetic acid and their commercial applications. [Pg.12]

Diol Components. Ethylene glycol (ethane 1,2-diol) is made from ethylene by direct air oxidation to ethylene oxide and ring opening with water to give 1,2-diol (40) (see Glycols). Butane-1,4-diol is stiU made by the Reppe process acetylene reacts with formaldehyde in the presence of catalyst to give 2-butyne-l,4-diol which is hydrogenated to butanediol (see Acetylene-DERIVED chemicals). The ethynylation step depends on a special cuprous... [Pg.293]

The conversion of a chemical with a given molecular formula to another compound with the same molecular formula but a different molecular structure, such as from a straight-chain to a branched-chain hydrocarbon or an alicyclic to an aromatic hydrocarbon. Examples include the isomerization of ethylene oxide to acetaldehyde (both C2H40) and butane to isobutane (both C4H10). [Pg.152]

The solids analysis described above can be taken to yet another level by correlating the color measurement to chemical properties. An excellent model system is vanadium pyrophosphate (VPO), which is a well-known catalyst for butane oxidation to maleic anhydride. During the synthesis of the catalyst precursor, solid V2O5 particles are dispersed in a mixture of benzyl alcohol and i-butanol. In this slurry phase, the vanadium is partly reduced. Addition of phosphoric acid leads to a further reduction and the formation of the VPO structure. With a diffuse reflectance (DR) UV-vis probe by Fiberguide Ind., the surface of the suspended solid particles could be monitored during this slurry reaction. Four points can be noted from Figure 4.4 ... [Pg.97]

Beginning in the fifties, acetic acid was predominantly obtained from paraffin oxidation, especially n-butane W. Acetic acid s chemical history has been rich and varied. [Pg.62]

Few chemicals have experienced as long and as successful a career us acetic acid, Acetic acid reluins its importance in (he production of vinyl and cellulose acetates Acetic acid is made industrially by oxidation of acetaldehyde or butane in air, or from methanol and carbon monoxide. [Pg.15]

The synthesis of intermediates and monomers from alkanes by means of oxidative processes, in part replacing alkenes and aromatics as the traditional building blocks for the chemical industry [2]. Besides the well-known oxidation of n-butane to maleic anhydride, examples of processes implemented at the industrial level are (i) the direct oxidation of ethane to acetic acid, developed by Sabic (ii) the ammoxidation of propane to acrylonitrile, developed by INEOS (former BP) and by Mitsubishi, and recently announced by Asahi to soon become commercial (iii) the partial oxidation of methane to syngas (a demonstration unit is being built by ENI). Many other reactions are currently being investigated, for example, (i) the... [Pg.289]

C-4 Chemistry (Butanes, Butylenes, Butadiene). Maleic anhydride is the main chemical made from w-butane. A complex catalyst is used for the oxidation reaction. The major uses for maleic anhydride are the making of unsaturated polyester resins (by reaction with glycol and phthalic anhydride) and tetrahydrofuran (by hydrogenation). [Pg.228]


See other pages where Butane, chemicals from oxidation is mentioned: [Pg.69]    [Pg.382]    [Pg.69]    [Pg.499]    [Pg.69]    [Pg.45]    [Pg.88]    [Pg.838]    [Pg.163]    [Pg.400]    [Pg.294]    [Pg.392]    [Pg.94]    [Pg.281]    [Pg.198]    [Pg.623]    [Pg.110]    [Pg.131]    [Pg.392]    [Pg.253]    [Pg.298]    [Pg.322]    [Pg.486]    [Pg.294]    [Pg.223]    [Pg.694]    [Pg.349]    [Pg.265]    [Pg.457]    [Pg.225]    [Pg.287]    [Pg.148]    [Pg.119]    [Pg.222]    [Pg.280]   
See also in sourсe #XX -- [ Pg.384 ]




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