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Face-bridging

A much more subtle case of stabilisation due to the presence of face-bridging ligands is found in the two tetrahedral clusters Co4Cp4(p3-H)4 (dec. ca. 300 °C)134> and Ni4Cp4(p3-H)3 (dec. ca. 320 °C)133h The structure of the last compound is shown in Fig. 2. [Pg.17]

The face-bridging carbonyls in Fe4(CO)4Cp4 are strongly basic and, with Lewis acids, form a number of (9-bonded adducts of the type Fe4(C0)4 Je(C0A)xCp4... [Pg.55]

Whereas edge- and face-bridging hydrogen atoms are associated mainly with metal-metal orbitals already present in the tetrahedral skeleton (see last section) and therefore have limited steric requirements, terminal hydrides occupy a full coordination position. It is not surprising then that the only examples of tetrahedral species with terminal hydrides contain 11 and 10 carbonyls, [Ir4(CO)nH] and [Ir4(CO)ioH2]2 . (The assignment for [Ir4(CO)nH] is based on the structure determination of the analogous [Ir4(CO)nBr] and on the similarity of the ir spectra of the two species (11).)... [Pg.10]

Face-bridging ligands hexahedro-fg3-Xjg-octahedro-A/p 4.6.83 Unsymmetrically bridged octahedro-A/g... [Pg.136]

See other pages where Face-bridging is mentioned: [Pg.1140]    [Pg.1141]    [Pg.1247]    [Pg.133]    [Pg.16]    [Pg.46]    [Pg.72]    [Pg.168]    [Pg.208]    [Pg.265]    [Pg.270]    [Pg.275]    [Pg.276]    [Pg.297]    [Pg.25]    [Pg.49]    [Pg.53]    [Pg.56]    [Pg.67]    [Pg.188]    [Pg.149]    [Pg.52]    [Pg.18]    [Pg.309]    [Pg.69]    [Pg.89]    [Pg.64]    [Pg.29]    [Pg.42]    [Pg.16]    [Pg.68]    [Pg.69]    [Pg.74]    [Pg.1426]    [Pg.561]    [Pg.139]    [Pg.160]    [Pg.65]    [Pg.224]    [Pg.251]    [Pg.41]    [Pg.13]    [Pg.21]   
See also in sourсe #XX -- [ Pg.35 , Pg.37 , Pg.39 ]



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Carbonyl ligand face-bridging

Carbonyls face bridging

Clusters containing face-bridging N-donor ligands

Face-bridging hydride ligands

Face-bridging hydrogen

Face-bridging ligands

Tetrahedral cluster complexes with face-bridging

Transition metal clusters face bridging

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