Boron metal azides

These compounds contain other ligands besides the azide group principal types of the class are basic azides and azide halides. The former are obtained by hydrolysis when preparing the III A through VIII metal azides in aqueous media hence, the stoichiometry of these products fluctuates with experimental circumstances. Nonetheless, stoichiometric phases of 22 basic azides are established, such as nickel hydroxide azide, (OH)Ni(N3), and holmium hydroxide azide, (HO)2Ho—O—Ho(OH)(N3). Azide halides have been made of the III through VII metals and of some adjacent metalloids examples are, lead(II) azide chloride, ClPb(N3), and boron azide dichloride, Cl2B(N3). 

Carbon tetrafluoride, 1 34 3 178 Carbon tetraiodide, 3 37 Carbonyl azide, formation of, by carbohydrazide, 4 35 Carbonyl fluoride, 6 155 Carbonyls, metal, 2 229 metal, nomenclature of, 2 264 structure of, 2 232 Catalysts, beryllium chloride, 5 25 boron fluoride, 1 23 chromium(III) oxide gel, 2 190... 

AMMONIA GAS (7664-41-7) Anhydrous, compressed gas or cryogenic liquid. Difficult to ignite, but can detonate in confined spaces in fire. Reacts violently with strong oxidizers, acids (nitric, hydrochloric, sulfuric, picric, hydrobromic, hydrochlorous, etc.). Shock-, temperature-, and pressure-sensitive compounds are formed with antimony, chlorine, germanium compounds, halogens, heavy metals, hydrocarbons, mercury oxide, silver compounds (azides, chlorides, nitrates, oxides). Fire and/or explosions may be caused by contact with acetaldehyde, acrolein, aldehydes, alkylene oxides, amides, antimony, boron, boron halides. 

BROME (French) (7726-95-6) A powerful oxidizer. Violent reaction with reducing agents. Can cause fire and explosions in contact with organic or other readily oxidizable materials. Contact with water or steam forms hydrobromic acid and oxygen. Contact with aqueous ammonia, acetaldehyde, acetylene, acrylonitrile, hydrogen may cause violent reactions. Anhydrous material reacts violently with aluminum, titanium, mercury, or potassium wet material reacts with other metals. Incompatible with many materials, including alcohols, antimony, alkali hydroxides, arsenites, azides, boron, calcium nitrite, cesium monoxide, carbonyls, dimethyl formamide, ethyl phosphine, fluorine, ferrous and mercurous salts, metals. 

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