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Double bond structure

The structures and nomenclature for the common pine resin acids based on the abietane skeleton (abietic-type acids) are given in Fig. 8. The abietic, neoabietic, palustric and levopimaric acids differ only in tbe location of tbeir two double bonds. All double bonds are endocyclic, except in the neoabietic acid in which one is exocyclic. [Pg.599]

Commonly used in biology as a tissue preservative, formaldehyde, CIDO, contains a carbon -oxygen double bond. Draw the line-bond structure of formaldehyde, and indicate the hybridization of the carbon atom. [Pg.16]

Both of these structures satisfy the formal valence rules for carbon, but each has a serious fault. Each structure shows three of the carbon-carbon bonds as double bonds, and three are shown as single bonds. There is a wealth of experimental evidence to indicate that this is not true. Any one of the six carbon-carbon bonds in benzene is. the same as any other. Apparently the fourth bond of each carbon atom is shared equally with each adjacent carbon. This makes it difficult to represent the bonding in benzene by our usual line drawings. Benzene seems to be best represented as the superposition or average of the two structures. For simplicity, chemists use either one of the structures shown in (30) usually expressed in a shorthand form (SI) omitting the hydrogen atoms ... [Pg.343]

In this reaction, called bromination, one of the hydrogen atoms has been replaced by a bromine atom. Notice that the double bond structure is not affected—this is not an addition reaction. Nitric acid causes a similar reaction, called nitration ... [Pg.344]

The X-ray structure of JV,iV,7,9-tetramethyl-2-phenyl-3//-l,3,4-benzotriazcpin-5- amine shows that the seven-membered ring is severely puckered and that the N1-C2 and N4-C5 bonds possess double-bond character.351... [Pg.462]

A single shared pair of electrons is called a single bond. Two electron pairs shared between two atoms constitute a double bond, and three shared electron pairs constitute a triple bond. A double bond, such as C 0, is written C=0 in a Lewis structure. Similarly, a triple bond, such as C C, is written G C. Double and triple bonds are collectively called multiple bonds. The bond order is the number of bonds that link a specific pair of atoms. The bond order in H, is 1 in the group C=0, it is 2 and, for O C in a molecule such as ethyne, C2H2, the bond order is 3. [Pg.190]

Three years ago it was pointed out2 that observed values of interatomic distances provide useful information regarding the electronic structures of molecules and especially regarding resonance between two or more valence bond structures. On the basis of the available information it was concluded that resonance between two or more structures leads to interatomic distances nearly as small Us the smallest of those for the individual structures. For example, in benzene each carbon-carbon bond resonates about equally between a single bond and a double bond (as given by the two Kekul6 structures) the observed carbon-carbon distance, 1.39 A., is much closer to the carbon-carbon double bond distance, 1.38 A., than to the shrgle bond distance, 1.54 A. [Pg.203]

The determination of values of interatomic distances in molecules has been found to provide much information regarding electronic structure, especially in the case of substances which resonate among two or more valence-bond structures. The interpretation of interatomic distances in terms of the types of bonds involved is made with use of an empirical function formulated originally for single bond-double bond resonance of the carbon-carbon bond.1 There are given in this... [Pg.657]

This is very different from the case with single bonds, which are freely rotating aU of the time. But a double bond is the result of overlapping p orbitals, and double bonds cannot freely rotate at room temperature (if you had trouble with this concept when you first learned it, you should review the bonding structure of a double bond in your textbook or notes). So there are two ways to arrange the atoms in space cis and trans. If you compare which atoms are connected to each other in each of the two possibilities, yon will notice that all of the atoms are connected in the same order. The difference is how they are connected in 3D space. This is why they are called stereoisomers (this type of isomerism stems from a difference of orientation in space— stereo ). [Pg.94]

The structural formulas used to represent molecules are based on valence bond theory. Double and triple bonds are just additional... [Pg.92]

Fig. 27. A view parallel to the double-sheet hydrogen-bonded structure formed by BulSi(OH)3, showing the hydrophilic interior and the hydrophobic exterior of the sheet. Hydrogen atoms are omitted for clarity. Drawn using coordinates taken from the Cambridge Crystallographic Database. Fig. 27. A view parallel to the double-sheet hydrogen-bonded structure formed by BulSi(OH)3, showing the hydrophilic interior and the hydrophobic exterior of the sheet. Hydrogen atoms are omitted for clarity. Drawn using coordinates taken from the Cambridge Crystallographic Database.
Recently, Schleyer and co-workers reported a theoretical study on the stabilities and geometries of a series of carbonyl type compounds, R2M=0 (M = C, Si, Ge, Sn, Pb R = H, CH3), and those of carbene type isomers [R(RO)M ] as shown in Table II.15 These results show that in (CH3)2 M=0 series the carbene type structure is more stable than the double bond type structure in the case of germanium, tin, and lead, unlike the case of carbon in which the double bond structure is preferred. [Pg.126]

Certain types of bond, whilst nominally being considered as single , have in fact, sufficient double bond character , to render rotation about their axis, restricted . The one you are most likely to encounter, is the amide bond. Partial double bond character exists between the carbonyl, and the nitrogen, and may be represented as in Structure 6.12 ... [Pg.78]


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Condensed structures containing double bond

Double 33 structure

Double bond, electronic structure

Double bond, electronic structure length

Double bond, electronic structure molecular orbitals

Double bond, electronic structure strength

Double bonds Lewis structure

Double bonds resonance structures

Double-bond compounds electronic structure

Double-bond equivalents, structure

Double-bond equivalents, structure spectroscopy

Double-bonded structures, nonaromatic

Double-helical structure, hydrogen-bonde

Heteroatomic structures carbon-heteroatom double bonds

Molecular Structure Molecules with Double Bonds

Poly double bond structure

Resonance structures conjugated double bonds

Structure of the Carbon-Oxygen Double Bond

Structures involving two double bonds or a triple bond

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