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Protonated benzene, preparation

George Olah published a perspective in which he provided an overview of the research of his group over five decades.1 Christopher Reed surveyed the chemistry of carborane acids, the strongest pure Brpnsted acids known, with a conjugate base that engages in little chemistry.2 These acids are employed to prepare highly acidic carbocations, including protonated benzene, protonated C6o, tertiary carbocations, vinyl cations, and silylium ions. The synthesis and properties of unusual... [Pg.179]

The chemistry of mass-selected ionized halobenzenes toward ammonia in a quadrupole collision cell pointed out that the CA spectra of the m/z 94 ions, i.e. protonated aniline, prepared in each of these conditions are qualitatively similar, since all the fragmentations are common. The major observed differences concern the relative intensities of the peaks associated with charge stripping and ammonia loss. In this context, substituted benzenes protonated on a ring carbon atom are more prone to undergo double ionization than substituted benzenes protonated on a substituent. [Pg.96]

The 1.4-dihydro-l,4-diazocines prepared from iyn-benzene diimines (Section 1.4.1.2.) can be transformed to other derivatives by exchange of the substituents at nitrogen. For this purpose, the dipotassium salt of 1,4-diazocine is generated and then reacted with appropriate electrophiles. For example, reduction of the bistosyl derivative 3 gives a relatively stable dianion, a lOrr-electron system analogous to cyclooctatetraene dianion, which on protonation clearly gives the parent l,4-dihydro-l,4-diazocine (4, E = H) as the only product. [Pg.536]

Several formylfuranboronic acids and similar compounds have been prepared by regular methods and studied with respect to their 13C and H NMR spectra. As in the benzene series, the protons ortho to the boron are deshielded and the meta protons are shielded. Good conjugation exists between the furan ring (donor) and both the boron atom and the carbonyl group (acceptors). A Hammett-Jaffe analysis yielded ap+ + 0.256 for the B(OH)2 group.234... [Pg.214]

NMR spectra of the compound 13a showed a broad singlet at 4.41 for the clibyl protons, whereas compound 13b showed two multiplets. Conversion of bridgehead carboxylic acids to the corresponding halides using Pb(OAc)4 and iodine in refluxing benzene under illumination is reported. This is considered to be an alternative to Barton s method, because of its simplicity and ease of preparation, but it involves toxic lead compounds. [Pg.29]

One of the most versatile methods for the preparation of 1,1-disubstituted X -phosphorins 124 was discovered by Stade who found that X -phosphorins 2 can be oxidized (mercuric acetate gives the best results) in the presence of alcohols or phenols in benzene to 1.1-dialkoxy- or l.l-diphenoxy-X -phosphorins 124. The first step is probably a reaction of the soft X -phosphorin- jr-system with the soft acid Hg which by electron transfer leads to the weakly electrophilic radical cation 58. This is then attacked by alcohol or phenol - or as Hettche has found by other nucleophiles such as an amine to form by loss of a proton the neutral X -phosphorin radical 59. This radical is oxidized once again by mercury ions leading to the formation of elemental mercury and the strongly electrophilic, short-lived X -phosphorin cation 127, which is immediately attacked by alcohol, phenol or amine. Loss of a proton then leads to the X -phosphorin 124. It is also conceivable that 59 can couple directly with a radical to form 124 (Method E, p. 82). [Pg.84]

The infrared spectra of the coal and the various extracts were recorded on a Baird, Model GY-1 (Ireland Mine vitrain concentrate) and on a Perkin Elmer Model 337 spectrophotometer (Bruceton coal). The samples were prepared by the potassium bromide pellet technique. The high resolution proton NMR spectrum of the benzene soluble extract from Ireland Mine vitrain concentrate was recorded on a Varian A-60 spectrometer in 10% deuterated chloroform (CDCh) solution, using tetrametnylsilane internal standard. [Pg.447]


See other pages where Protonated benzene, preparation is mentioned: [Pg.123]    [Pg.109]    [Pg.96]    [Pg.192]    [Pg.61]    [Pg.214]    [Pg.107]    [Pg.225]    [Pg.791]    [Pg.103]    [Pg.105]    [Pg.65]    [Pg.36]    [Pg.75]    [Pg.539]    [Pg.368]    [Pg.319]    [Pg.162]    [Pg.169]    [Pg.25]    [Pg.83]    [Pg.904]    [Pg.328]    [Pg.357]    [Pg.98]    [Pg.149]    [Pg.194]    [Pg.617]    [Pg.643]    [Pg.647]    [Pg.114]    [Pg.801]    [Pg.219]    [Pg.391]    [Pg.539]    [Pg.9]    [Pg.24]    [Pg.606]    [Pg.160]    [Pg.661]    [Pg.61]    [Pg.539]    [Pg.912]    [Pg.312]   
See also in sourсe #XX -- [ Pg.179 ]




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