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Azobisisobutyronitril

In discussing mechanism (5.F) in the last chapter we noted that the entrapment of two reactive species in the same solvent cage may be considered a transition state in the reaction of these species. Reactions such as the thermal homolysis of peroxides and azo compounds result in the formation of two radicals already trapped together in a cage that promotes direct recombination, as with the 2-cyanopropyl radicals from 2,2 -azobisisobutyronitrile (AIBN),... [Pg.352]

Compounds with active hydrogen add to the carbonyl group of acetone, often followed by the condensation of another molecule of the addend or loss of water. Hydrogen sulfide forms hexamethyl-l,3,5-trithiane probably through the transitory intermediate thioacetone which readily trimerizes. Hydrogen cyanide forms acetone cyanohydrin [75-86-5] (CH2)2C(OH)CN, which is further processed to methacrylates. Ammonia and hydrogen cyanide give (CH2)2C(NH2)CN [19355-69-2] ix.orn. 6<55i the widely used polymerization initiator, azobisisobutyronitrile [78-67-1] is made (4). [Pg.93]

Free-radical polymerization processes are used to produce virtually all commercial methacrylic polymers. Usually free-radical initiators (qv) such as azo compounds or peroxides are used to initiate the polymerizations. Photochemical and radiation-initiated polymerizations are also well known. At a constant temperature, the initial rate of the bulk or solution radical polymerization of methacrylic monomers is first-order with respect to monomer concentration, and one-half order with respect to the initiator concentration. Rate data for polymerization of several common methacrylic monomers initiated with 2,2 -azobisisobutyronitrile [78-67-1] (AIBN) have been deterrnined and are shown in Table 8. [Pg.263]

Free-Radical Gopolymerization. Examples of the types of copolymers formed by free-radical copolymerizations are shown ia equations 18—20, where S = styrene [100-42-5] B = butadiene [106-99-0] and AIBN = azobisisobutyronitrile [78-67-1] (see Initiators) (27—29). [Pg.179]

Figure 2.18. Rate of polymerisation of methyl methacrylate with azobisisobutyronitrile at 60°C as measured by various workers. (Copyright 1955 by the American Chemical Society and reprinted by permission of the copyright owner)... Figure 2.18. Rate of polymerisation of methyl methacrylate with azobisisobutyronitrile at 60°C as measured by various workers. (Copyright 1955 by the American Chemical Society and reprinted by permission of the copyright owner)...
The user should be aware though of the presence of other functions in the matrix of the packing the initiator used, azobisisobutyronitrile, leaves a small amount of CN functions in the packings. Also, small amounts of alcohol functions cannot be excluded, especially as the packing ages. For most applications, these small amounts of residual side functions are of little concern. [Pg.327]

Treatment of l-arylsulfonyl-2-(l-iodoalkyl)piperidines 48 (R = H) with 2.7 equiv. of BusSnH in the presence of azobisisobutyronitrile (ABIN) furnished a mixture of 7,8,9,10,10u,ll-hexahydropyrido[l,2-ft][l,2]ben-zothiazine 5,5-dioxides 50, 2-benzylpiperidines 51 and l-arylsulfonyl-2-alkylpiperidines 52 in a radical process (Scheme 6) (77TL631,78JCS(CC)166, 80JCS(CC)142). The yield of 7,8,9,10,10u,ll-hexahydropyrido[l,2-6][l,2]... [Pg.233]

A) The preparation of [H-chloroethoxyjchloromethyl]phosphonic acid Acetaldehyde (1.1 mol) and hydroxymethylphosphonlc acid (1 mol) in 500 ml of benzene are saturated with hydrogen chloride gas at 10°C to 15°C. The mixture is aged at 25°C for 24 hr, the solvent distilled out in vacuo and the residue flushed three times with benzene to remove all traces of hydrogen chloride. The residue is taken up in benzene (500 ml), treated with tert-butyl hypochlorite (0.8 mol) and azobisisobutyronitrile (0.8 mm) at 40°C until titration shows the absence of hypochlorite and the solution is then evaporated to yield [(1-chloro-ethoxy)chloromethyll phosphonic acid in the form of an oil. [Pg.703]

In the presence of radical initiators such as benzoyl peroxide (BPO), azobisisobutyronitrile (AIBN), persulfates (S208 ), etc., grafting of vinyl monomers onto polymeric backbones involves generation of free radical sites by hydrogen abstraction and chain transfer processes as described below ... [Pg.483]

The hydrogen abstraction from —SH groups is faster than from —OH groups. Hebeish et al. [9] and Misra et al. [10,11] reported the chain-transfer method of initiation of graft copolymerization onto cellulosic substrates with azobisisobutyronitrile (AIBN) and benzoyl peroxide (BPO) as initiators. [Pg.503]

Macroazoinitiators have generally been obtained from a polyethylene glycol (PEG) and an azoinitiator 4,4 -azobisisobutyronitril (AIBN) [21-23] and 4,4 -azobiscy-anopentanoyl chloride (ACPC) [24]. [Pg.728]

To incorporate a labile azo group as the essential active site to MAI, a series of azo compounds such as 2,2 azobisisobutyronitrile (AIBN), 4,4 -azobis(4-cyanopen-tanoyl chloride) (ACPC), 2,2 azobis (2-cyanopropanol) (ACPO), 2,2 azobis [2-methyl-N-(2-hydroxyethyl)prop-ionamide] (AHPA), etc., were used as starting materials for polycondensation with various diols, diamines, diacids, or diisocyanates. [Pg.756]

It is important to emphasize that the hydroxy dithioketal cyclization can be conducted under mild reaction conditions and can be successfully applied to a variety of substrates.15 However, the utility of this method for the synthesis of didehydrooxocane-contain-ing natural products requires the diastereoselective, reductive removal of the ethylthio group. Gratifyingly, treatment of 13 with triphenyltin hydride and a catalytic amount of the radical initiator, azobisisobutyronitrile (AIBN), accomplishes a homolytic cleavage of the C-S bond and furnishes didehydrooxocane 14 in diastereo-merically pure form (95 % yield), after hydrogen atom transfer. [Pg.736]

AIBN 2,2 azobisisobutyronitrile HPLC high-pressure liquid chromatography... [Pg.809]

As an example, consider the polymerization of methyl methacrylate, initiated by a,a -azobisisobutyronitrile.4 The dependence of the initial rate on the concentration of the initiator is displayed in Fig. 1-1, which shows them on a double logarithmic scale. The points define a straight line with a least-squares slope of0.496. Clearly the reaction is half-order with respect to the concentration of the initiator. [Pg.6]

A plot of the initial reaction rate versus concentration, on logarithmic scales. The reaction is the polymerization of methyl methacrylate, and the concentration is that of the initiator, azobisisobutyronitrile. The slope is 0.496, showing that the reaction is half-order with respect to the initiator concentration. [Pg.6]

Radical Diels-Alder reactions have been used mainly to synthesize polycyclic molecules. These reactions, like those that involve cations and anions as components, proceed quickly but generally do not give high yields. Thus, the tricyclic enone 14 is the result of an intramolecular Diels-Alder reaction of quenched vinyl radical intermediate 13 obtained by treating the iododienynone 12 with n-tributyltin hydride/2,2 -azobisisobutyronitrile (AIBN) [28] (Equation 1.11). [Pg.8]

Konig et al. have achieved thioether functionalization of T8[CH = CH2]8 via the radical addition of thiols such as thiophenol, cyclohexylthiol, and 2-mercaptopyridine in the presence of azobisisobutyronitrile (AIBN) as a radical initiator (Table 13), while Gao et al. have also used this method to prepare very highly functionalized POSS by reacting T8[CH = CH2]8 with thiol-terminated glycosides giving glycoclusters in 70% yield (Figure 22). [Pg.40]

The reactions are radical chain processes (Scheme 3) and, therefore, the initial silyl radicals are generated by some initiation. The most popular thermal initiator is azobisisobutyronitrile (AIBN), with a half-life of 1 h at 81 °C. Other azocompounds are used from time to time depending on the reaction conditions. EtsB in the presence of very small amounts of oxygen is an excellent initiator for lower temperature reactions (down to —78°C). The procedures and examples for reductive removal of functional groups by (TMSlsSiH are numerous and have recently been summarized in the book Organosilanes in Radical Chemistry. ... [Pg.126]

The monomers used in chain polymerisations are unsaturated, sometimes referred to as vinyl monomers. In order to carry out such polymerisations a small trace of an initiator material is required. These substances readily fragment into free radicals either when heated or when irradiated with electromagnetic radiation from around or just beyond the blue end of the spectrum. The two most commonly used free radical initiators for these reactions are benzoyl peroxide and azobisisobutyronitrile (usually abbreviated to AIBN). They react as indicated in Reactions 2.1 and 2.2. [Pg.24]


See other pages where Azobisisobutyronitril is mentioned: [Pg.48]    [Pg.351]    [Pg.82]    [Pg.203]    [Pg.213]    [Pg.88]    [Pg.165]    [Pg.524]    [Pg.496]    [Pg.254]    [Pg.100]    [Pg.297]    [Pg.206]    [Pg.273]    [Pg.569]    [Pg.73]    [Pg.325]    [Pg.73]    [Pg.174]    [Pg.542]    [Pg.789]    [Pg.51]    [Pg.587]    [Pg.596]    [Pg.560]    [Pg.3]    [Pg.29]    [Pg.353]    [Pg.104]    [Pg.89]   
See also in sourсe #XX -- [ Pg.13 ]




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2,2-Azobisisobutyronitrile , radical

2,2-Azobisisobutyronitrile , radical initiator

AIBN—See Azobisisobutyronitrile

Azobisisobutyronitrile

Azobisisobutyronitrile

Azobisisobutyronitrile , photoinitiation

Azobisisobutyronitrile AIBN)

Azobisisobutyronitrile as initiator

Azobisisobutyronitrile catalyst

Azobisisobutyronitrile chain transfer

Azobisisobutyronitrile continued

Azobisisobutyronitrile controlled radical

Azobisisobutyronitrile decomposition

Azobisisobutyronitrile decomposition mechanism

Azobisisobutyronitrile decomposition products

Azobisisobutyronitrile free radical polymerization

Azobisisobutyronitrile in a Dilatometer

Azobisisobutyronitrile polymerization

Azobisisobutyronitrile preparation

Azobisisobutyronitrile synthesis

Azobisisobutyronitrile thermolysis

Azobisisobutyronitrile toxicity

Azobisisobutyronitrile, photolysis

Azobisisobutyronitrile, poly

Azobisisobutyronitrile, radical reactions

Azobisisobutyronitrile-initiated graft

Azobisisobutyronitrile-initiated graft copolymerization

Azobisisobutyronitriles

Azobisisobutyronitriles

Bulk Polymerization of Styrene with 2,2-Azobisisobutyronitrile in a Dilatometer

C-Glycosyl compounds 2,2-azobisisobutyronitrile

Controlled radical polymerization azobisisobutyronitrile

Initiator azobisisobutyronitrile

Methyl methacrylate grafting azobisisobutyronitrile

Oxidants azobisisobutyronitrile

Polymerization of Methyl Methacrylate with 2,2-Azobisisobutyronitrile in Bulk

Thiophenol-Azobisisobutyronitrile

Tributyltin hydride-2,2 -azobisisobutyronitril

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