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Attractive charge forces

The most frequent type of interaction between solid and species in solution would be electrostatic adsorption (ion exchange), due to the action of attractive coulomb forces between charged particles in solution and the solid surfaces. This process would also be concentration dependent. [Pg.286]

When electrons are in the region between two nuclei, attractive electrical forces exceed repulsive electrical forces, leading to the stable arrangement of a chemical bond. Remember that electrons are not point charges but are spread out over a relatively large volume. [Pg.573]

Charge-transfer from ketone to olefin would only increase the propensity toward a concerted reaction, since the interaction of a positively charged carbonyl compound for a negatively-charged olefin would give rise to an attractive Coulombic force. For the orientation problem, total jr-charges after CT are shown in structure 6, with the resultant molecular... [Pg.160]

One of the more profound manifestations of quantum mechanics is that this curve does not accurately describe reality. Instead, because the motions of electrons are correlated (more properly, the electronic wave functions are correlated), the two atoms simultaneously develop electrical moments that are oriented so as to be mutually attractive. The force associated with tills interaction is referred to variously as dispersion , the London force, or the attractive van der Waals force. In the absence of a permanent charge, the strongest such interaction is a dipole-dipole interaction, usually referred to as an induced dipole-induced dipole interaction, since the moments in question are not permanent. Such an interaction has an inverse sixtli power dependence on the distance between the two atoms. Thus, the potential energy becomes increasingly negative as the two noble gas atoms approach one another from infinity. [Pg.28]

Ionic bond A chemical bond in which an attractive electric force holds ions of opposite charge together. [Pg.212]

An alpha particle undergoes an acceleration due to mutual electric repulsion as soon as it is out of the nucleus and away from the attracting nuclear force. This is because it has the same sign of charge as the nucleus. Like charges repel. [Pg.685]

Tn the Rohr model of the hydrogen atom, the proton is a massive positive point charge about which the electron moves. By placing quantum mechanical conditions upon an otherwise classical planetary motion of the electron, Bohr explained the lines observed in optical spectra as transitions between discrete quantum mechanical energy states. Except for hvperfine splitting, which is a minute decomposition of spectrum lines into a group of closely spaced lines, the proton plays a passive role in the mechanics of the hydrogen atom, It simply provides the attractive central force field for the electron,... [Pg.1378]

Close proximity of the oppositely charged functional groups can be achieved in ion exchangers with covalently bonded zwitterionic molecules in which two or three methylene chains separate the carboxylate or sulfonate and quaternary ammonium groups [ 13-151. This arrangement results in the establishment of a combination of repulsion and attraction electrostatic forces and such stationary phases have been used for the separation of seven or eight anions and cations [13,141. [Pg.1216]

Each ionic molecule has a cation end and an anion end. The oppositely charged ends of different molecules are naturally attracted to each other because opposites attract. This force can hold ionically bonded molecules together in an ionic solid. [Pg.26]

It is noted that the rate of electrification is not constant. Once the tendency is established for an electron to escape from the solid particle by thermionic emission, the charge buildup occurs on the particle, which then attempts to recapture the to-be-freed electron by the attracting Coulomb force. Therefore, the equilibrium of thermal electrification of solid particles in a finite space is possible. Details on the equilibrium and the rate of electrification concerning the thermionic emission are available in Soo (1990). [Pg.119]

Chemical bonds and population analysis Most metals of interest in the context of polymer-based electronic devices form some kind of chemical bond to the polymer upon interaction with a polymer surface. Population analysis, based on the electronic structure, is used to determine the character of this bond. According to the commonly used chemical terminology, bonds are classified as ionic if the bonded atoms are oppositely charged and held together by the attractive Coulomb force, and covalent if the two atoms are neutral but share the same pair of electrons. In the latter case, much of the electron density is located between the bonded atoms whereas for the ionic bond the charge density is concentrated at the atomic sites. [Pg.27]

If both molecules are polar, then opposite charges on the two are drawn together by electrostatic forces. These forces are called orientation forces because the two molecules must be oriented such that the opposite charges are close enough for attraction. These forces are of major importance in polar substances. [Pg.25]


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See also in sourсe #XX -- [ Pg.12 , Pg.17 , Pg.51 , Pg.60 , Pg.69 , Pg.82 , Pg.129 , Pg.137 ]




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