Atmospheric condition effect

Cooling-Tower Plumes. An important consideration in the acceptabiHty of either a mechanical-draft or a natural-draft tower cooling system is the effect on the environment. The plume emitted by a cooling tower is seen by the surrounding community and can lead to trouble if it is a source of severe ground fog under some atmospheric conditions. The natural-draft tower is much less likely to produce fogging than is the mechanical-draft tower. Nonetheless, it is desirable to devise techniques for predicting plume trajectory and attenuation. 

The effective stack height (equivalent to the effective height of the emission) is the sum of the actual stack height, the plume rise due to the exhaust velocity (momentum) of the issuing gases, and the buoyancy rise, which is a function of the temperature of the gases being emitted and the atmospheric conditions. 

The only model ever published in the literature is poor. The fact, for instance, that burning speed is taken as proportional to wind speed implies that, under calm atmospheric conditions, burning velocities become improbably small, and flash-fire duration proportionately long. The effect of view factors, which change continuously during flame propagation, requires a numerical approach. 

Selection and care of the hydraulic fluid for a machine will have an important effect on how it performs and on the life of the hydraulic components. During the design of equipment that requires fluid power, many factors are considered in selecting the type of system to be used-hydraulic, pneumatic, or a combination of the two. Some of the factors required are speed and accuracy of operation, surrounding atmospheric conditions, economic conditions, availability of replacement fluid, required pressure level, operating temperature range, contamination possibilities, cost of transmission lines, limitations of the equipment, lubricity, safety to the operators, and expected service life of the equipment. 

The degree of drying desired will vary with the pneumatic equipment and application involved. The aim is to eliminate further condensation in the airlines and pneumatic tools or devices. Prevailing atmospheric conditions also have an influence on the approach that is most effective. In many 100-psig installations, a dew point at line pressure of from 500°F to 350°F is adequate. Other applications, such as instrument air systems, will require dew points of minus 500°F. 

Plants have evolved and adapted to suit the atmospheric conditions in which they find themselves. This atmosphere may contain traces of gases which we would classify as pollutants. However, in many cases these may be necessary for the plants existence. Near to industrial centers, the relative concentrations of the various gases change, and this can have an adverse effect on the plants development. 

Weather conditions at the time of initial exposure of zinc and steel have a large influence on the protective nature of the initial corrosion products This can still be detected some months after initial exposure. Finally, rust on steel contains a proportion of ferrous sulphate which increases with increase in SO2 pollution of the atmosphere. The effect of this on corrosion rate is so strong that mild steel transferred from an industrial atmosphere to a rural one corrodes for some months as though it was still exposed to the industrial environment. ... 

It should be recognized that tensile properties would most likely vary with a change of speed of the pulling jaws and with variation in the atmospheric conditions. Figure 2-14 shows the variation in a stress-strain curve when the speed of testing is altered also shown are the effects of temperature changes on the stress-strain curves. When the speed of pulling force is increased, the material reacts like brittle material when the temperature is increased, the material reacts like ductile material. 

Chemical interactions also occur in the condensed phases. Some of these are expected to be quite complex, e.g., the reactions of free radicals on the surfaces of or within aerosol particles. Simpler sorts of interactions also exist. Perhaps the best understood is the acid-base relationship of NH3 with strong acids in aerosol particles and in liquid water (see Chapter 16). Often, the main strong acid in the atmosphere is H2SO4, and one may consider the nature of the system consisting of H2O (liquid), NH3, H2SO4, and CO2 under realistic atmospheric conditions. Carbon dioxide is not usually important to the acidity of atmospheric liquid water (Charlson and Rodhe, 1982) the dominant effects are due to NH3 and H2SO4. The sensitivity the pH of cloud (or rainwater produced from it) to NH3 and... 

A more practical, atom-economic and environmentally benign aziridination protocol is the use of chloramine-T or bromamine-T as nitrene source, which leads to NaCl or NaBr as the sole reaction by-product. In 2001, Gross reported an iron corrole catalyzed aziridination of styrenes with chloramine-T [83]. With iron corrole as catalyst, the aziridination can be performed rmder air atmosphere conditions, affording aziridines in moderate product yields (48-60%). In 2004, Zhang described an aziridination with bromamine-T as nitrene source and [Fe(TTP)Cl] as catalyst [84]. This catalytic system is effective for a variety of alkenes, including aromatic, aliphatic, cyclic, and acyclic alkenes, as well as cx,p-unsaturated esters (Scheme 28). Moderate to low stereoselectivities for 1,2-disubstituted alkenes were observed indicating the involvement of radical intermediate. 

Batchelor, R. F. Wilson, A. D. (1969). Zinc oxide eugenol cements. I. The effect of atmospheric conditions on rheological properties. Journal of Dental... 

The high temperatures and pressures created during transient cavitation are difficult both to calculate and to determine experimentally. The simplest models of collapse, which neglect heat transport and the effects of condensable vapor, predict maximum temperatures and pressures as high as 10,000 K and 10,000 atmospheres. More realistic estimates from increasingly sophisticated hydrodynamic models yield estimates of 5000 K and 1000 atmospheres with effective residence times of <100 nseconds, but the models are very sensitive to initial assumptions of the boundary conditions (30-32). 

Incidentally, the water in the bucket is essential for generating the effect of theatrical smoke because the large volumes of CC>2(g) entrap minute particles of water (which forms a colloid see Chapter 10.2). This colloidal water is visible because it creates the same atmospheric condition known as fog, which is opaque. 

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