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Aromatic amines Reactions

The initial increase in the heat capacity signal corresponds to the reaction heat capacity or the change in heat capacity from reactants to products (see arrow in Rg. 2.112). A thermodynamic analysis of the epoxy-aromatic amine reaction revealed that the primary amine-epoxy reaction contributes less to the increase in reaction heat capacity than does the secondary epoxy-amine reaction (Swier and van Mele 2003b). Information specific to the different steps in the reaction mechanism can therefore be deduced from the heat capacity signal, in contrast to the global conversion evolution obtained from the total heat flow signal. [Pg.196]

They are prepared by the action of HNO2 on aromatic amines. The amine is dissolved in excess of mineral acid and sodium nitrite is added slowly until a slight excess of HNO2 is present. The reaction is usually carried out in ice-cold solution. The solution then contains the diazonium salt of the mineral acid used, anhydrous diazonium salts of unpredictable stability may be precipitated with complex anions like PF , SnCl6 BF4 . [Pg.133]

The most important reaction of the diazonium salts is the condensation with phenols or aromatic amines to form the intensely coloured azo compounds. The phenol or amine is called the secondary component, and the process of coupling with a diazonium salt is the basis of manufacture of all the azo dyestuffs. The entering azo group goes into the p-position of the benzene ring if this is free, otherwise it takes up the o-position, e.g. diazotized aniline coupled with phenol gives benzeneazophenol. When only half a molecular proportion of nitrous acid is used in the diazotization of an aromatic amine a diazo-amino compound is formed. [Pg.133]

Doebner-von Miller reaction Condensation of an aromatic amine with an aldehyde or ketone in the presence of hydrochloric acid to form a quinoline derivative. A general method, thus aniline and ethanal give 2-methyl-quinoline (quinaldine) and p-phenetidine. [Pg.145]

SchifT s bases A -Arylimides, Ar-N = CR2, prepared by reaction of aromatic amines with aliphatic or aromatic aldehydes and ketones. They are crystalline, weakly basic compounds which give hydrochlorides in non-aqueous solvents. With dilute aqueous acids the parent amine and carbonyl compounds are regenerated. Reduction with sodium and alcohol gives... [Pg.353]

A halogen atom directly attached to a benzene ring is usually unreactive, unless it is activated by the nature and position of certain other substituent groups. It has been show n by Ullmann, however, that halogen atoms normally of low reactivity will condense with aromatic amines in the presence of an alkali carbonate (to absorb the hydrogen halide formed) and a trace of copper powder or oxide to act as a catalyst. This reaction, known as the Ullmant Condensation, is frequently used to prepare substituted diphenylamines it is exemplified... [Pg.217]

It is convenient to include under Aromatic Amines the preparation of m-nitroaniline as an example of the selective reduction of one group in a polynitro compound. When wt-dinitrobenzene is allowed to react with sodium polysulphide (or ammonium sulphide) solution, only one of the nitro groups is reduced and m-nitroanUine results. Some sulphur separates, but the main reaction is represented by ... [Pg.563]

SULPHONATION OF AROMATIC AMINES If aniline is treated with excess of concentrated sulphuric acid and the resulting mixture, which contains aniline sulphate, is heated at 180° until a test portion when mixed with sodium hydroxide solution no longer liberates aniline, p-aminobenzenesulphonic acid or sulphanilic acid is formed this separates as the dihydrate upon pouring the cooled mixture into water. The reaction prohahly proceeds as follows ... [Pg.585]

Primary aromatic amines differ from primary aliphatic amines in their reaction with nitrous acid. Whereas the latter yield the corresponding alcohols (RNHj — ROH) without formation of intermediate products see Section 111,123, test (i), primary aromatic amines 3neld diazonium salts. Thus aniline gives phcnyldiazonium chloride (sometimes termed benzene-diazonium chloride) CjHbNj- +C1 the exact mode of formation is not known, but a possible route is through the phenjdnitrosoammonium ion tlius ... [Pg.590]

Those reactions which are common to both aliphatic and aromatic amines and have been described under Aliphatic Amines (Section 111,123) will not be repeated in this Section except where differences in experimental technique occur. [Pg.648]

The synthesis can be carried out with most aromatic amines and is usually termed the Skraup reaction. The nitrobenzene is frequently replaced by arsenic acid, as in the prep)aration of 8-nitroquinoline from o-nitroanUine ... [Pg.828]

Quinoline derivatives may be synthesised by heating aii aromatic amine with an aldehyde or a mixture of aldehydes in the presence of concentrated hydrochloric or sulphuric acid this synthesis is known as the Doebner - Miller reaction. Thus aniline and paraldehyde afford 2-methylquinohne or quinaldine. [Pg.831]

This is an example of the Doebner synthesis of quinoline-4-carboxylic acids (cinchoninic acids) the reaction consists in the condensation of an aromatic amine with pyruvic acid and an aldehj de. The mechanism is probably similar to that given for the Doebner-Miller sj nthesis of quinaldiiie (Section V,2), involving the intermediate formation of a dihydroquinoline derivative, which is subsequently dehydrogenated by the Schiff s base derived from the aromatic amine and aldehyde. [Pg.1010]

Some reference to the use of nitrous acid merits mention here. Primary aromatic amines yield diazonium compounds, which may be coupled with phenols to yield highly-coloured azo dyes (see Section IV,100,(iii)). Secondary aromatic amines afford nitroso compounds, which give Liebermann a nitroso reaction Section IV,100,(v). Tertiary aromatic amines, of the type of dimethylaniline, yield p-nitroso derivatives see Section IV,100,(vii). ... [Pg.1073]


See other pages where Aromatic amines Reactions is mentioned: [Pg.107]    [Pg.880]    [Pg.55]    [Pg.659]    [Pg.107]    [Pg.1077]    [Pg.447]    [Pg.456]    [Pg.54]    [Pg.302]    [Pg.908]    [Pg.1314]    [Pg.791]    [Pg.107]    [Pg.880]    [Pg.55]    [Pg.659]    [Pg.107]    [Pg.1077]    [Pg.447]    [Pg.456]    [Pg.54]    [Pg.302]    [Pg.908]    [Pg.1314]    [Pg.791]    [Pg.28]    [Pg.224]    [Pg.529]    [Pg.1038]    [Pg.1058]   
See also in sourсe #XX -- [ Pg.541 ]




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Aldehydes, reaction with aromatic amines

Aromatic amination

Aromatic amines

Aromatic amines photochemical reactions

Aromatic amines reaction with nitrous acid

Aromatic amines reaction with, phosgene

Aromatic amines reactions and characterisation

Aromatic amines reactions with carbonate radical

Aromatic amines reactions with hydroxyl radical

Aromatic amines reactions with hypochlorite

Aromatic amines reactions with ozone

Aromatics amination

Carbonates reaction with aromatic amines

Oxidation of aromatic amines (Boyland-Sims reaction)

Primary aromatic amines reactions and characterisation

Primary aromatic amines, reactions

Primary aromatic amines, reactions table

Quaternization of Aromatic Amines (Menschutkin Reaction)

Reaction CXLII.—Action of Primary Aromatic Amines on Alcohols

Reaction CXLIX.—Intramolecular Rearrangement of Aromatic Amine Sulphates

Reaction XCIII.—Oxidation of Primary Aromatic Amines and their para-substituted Derivatives to Quinones

Reaction with aromatic amines

Reactions and characterisation of aromatic amines

Reactions of Aromatic Amines

Ring Reactions of Aromatic Amines

Secondary aromatic amines reactions and characterisation

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