Architecture Effects

Liu S, Kiick KL (2008) Architecture effects on the binding of cholera toxin by helical glycopolypeptides. Macromolecules 41 764—772... 

Yakushiji, T, Sakai, K., Kikuchi, A., Aoyagi, T, Sakurai, Y, and Okano, T. Graft architectural effects on thermo-responsive wettability changes of poly(A-isopropylacrylamidej-modified surfaces, Langmuire, 1998, 14, 4657-4662. 

Drug Class Mechanism of Action Half- Life (T>/2) (hours) Metabolism Onset of Action/Peak Level (min) Drug-Drug Interactions Sleep Architecture Effects... 

The use of nonbiological nucleobases to enhance oligonucleotide duplex stability is widespread, and an exhaustive exploration of this field is beyond the scope of this review. At the same time, recent studies exist that go beyond this goal with the aim of understanding the function of base interactions in duplex stability and the impact of unusual nucleobases on both conformation and assembly. Herein, we focus on a few of these examples as representatives of the field and to highlight how modifications at nucleobase sites that are remote from the backbone can have profound architectural effects on... 

Architecture. By curving the timber during manufacture, a variety of architectural effects can be obtained from glulam that are impossible or difficult with other materials. The degree of curvature is determined by the thickness of the laminations. Beams with curvature are generally made with 19 mm (nominal 1 in.) timber, while 13 mm (1/2-in.) or thinner material may be required for very sharp curves. 

The star architecture effects are more important for I q 0) than for Dc because the ratio of the corresponding correction terms, k / k — k, is large when k k. Nevertheless, the experimental Dc c/c reveals a stronger speed-up of Dc with concentration in multiarm stars compared to the semidilute linear polymer solutions. The hard core contribution to the osmotic pressure is essentially hidden in the inhomogeneous density profile and the thermodynamic properties of the star solutions are primarily determined by their polymeric character. 

Our work on the synthesis of model ionomer systems by anionic polymerization is continuing. The architectural effects of these ionomers having controlled structures are being compared with their random counterparts. 

May PA (2013) Polymer architecture effects on mechanochemical reactions. University of Illinois at Urbana-Champaign, Urbana... 

Ryu, C. Y., Ruokolainen, J., Fredrickson, G. H., Kramer, E. J., and Hahn, S. F. (2002) Chain architecture effects on deformation and fracture of block copolymers with unentangled matrixes, Macromolecules, 35, 2157-2166. 

Dorgan J.R., Williams J.S., Lewis D.N., Melt rheology of poly(lactic cid) Entanglement and chain architecture effects, J. RheoL, 43(5), 1999,1141-1155. 

Bricks that are intentionally flashed make possible pleasing architectural effects. Flashed glass-ware is made by... 

Structural tricks could be harnessed to architectural effect. The hanging keystone trope is here combined with filigree stonework and slender turned pillars. The attenuated structure relies on the surrounding mass for its stability. 

The dome of St Peter s, completed in 1624 to the designs of Michelangelo Buonarroti (1495-1564), is a product of Gothic practice fully infiltrated by Renaissance ideals. Directly comparable In size to the crossing of Florence cathedral, the design no longer allowed construction rationale to precede architectural effect (figure 5.3). The shell s... 

Dorgan, J. R., Williams, J. S. Lewis, D. N. (1999). Melt rheology of pely(lactic add) Entanglement and chain architecture effects. Journal of Rheology 43(5) 1141-1155. 

Nasongkla, N., Chen, B., Macaraeg, N. etal. (2009) Dependence of pharmokinetics and biodistribution on polymer architecture Effect of cyclic versus linear polymers. Journal of the American Chemical Society, 131,3842-3843. 

Pointing is used to protect the joints of masonry, and is made by mixing cement and sand with a minimum of water. The joint is first cut out to the depth of from one half to one inch, carefully brushed clean, moistened with water, and fiUed with the moftar, which is well rubbed uith a steel tool. To give architectural effect, plaster of Paris (Gypsum) is sometimes used in pointing. 

In the next paper, architectural effects of ladder-like polymer on glass transition temperature (Tg) were examined. Also in this case, the template (PHEMA) was synthesized by ATRP and was converted to multimonomer (PMOEM) by esterification with methacryloyl chloride. PMOEM was then polymerized by ATRP method and ladder-type polymer was obtained with a different percentage of ladder-type rmits dependent on the time of reaction. Additionally, the product with maximum ladder-type units (more than 70%) was hydrolyzed. It was found that glass transition temperature inaeases substantially when the degree of ladder in the product of template polymerization is more than 60%. According to the authors, the formation of a ladder-type sequence in the polymer was effective for improving the thermal stability with a small fraction of ladder-like sequence. 

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