Applications nematic liquid crystal displays

Let the structure of the nematic liquid crystal be called uniform if the director distribution in this structure, and, accordingly, its optical and electrooptical properties are uniform, i.e., do not depend on the coordinates in the plane parallel to the substrates. The first observations of the optical and electrooptical properties of uniform nematic structures were carried out by Mauguin, Tsvetkov, and Prederiks over 50 years ago [1-4]. Since the beginning of the 1970s these structures have attracted growing interest, as they are the most promising ones for practical applications in Liquid Crystal Displays (LCDs). 

The existence or nonexistence of mirror symmetry plays an important role in nature. The lack of mirror symmetry, called chirality, can be found in systems of all length scales, from elementary particles to macroscopic systems. Due to the collective behavior of the molecules in liquid crystals, molecular chirality has a particularly remarkable influence on the macroscopic physical properties of these systems. Probably, even the flrst observations of thermotropic liquid crystals by Planer (1861) and Reinitzer (1888) were due to the conspicuous selective reflection of the helical structure that occurs in chiral liquid crystals. Many physical properties of liquid crystals depend on chirality, e.g., certain linear and nonlinear optical properties, the occurrence of ferro-, ferri-, antiferro- and piezo-electric behavior, the electroclinic effect, and even the appearance of new phases. In addition, the majority of optical applications of liquid crystals is due to chiral structures, namely the ther-mochromic effect of cholesteric liquid crystals, the rotation of the plane of polarization in twisted nematic liquid crystal displays, and the ferroelectric and antiferroelectric switching of smectic liquid crystals. 

Many technological applications of liquid crystals, as in electro-optic display devices, are based on multicomponent mixtures. Such systems offer a route to the desired material properties which cannot be achieved simultaneously for single component systems. Mixtures also tend to exhibit a richer phase behaviour than pure systems with features such as re-entrant nematic phases [3] and nematic-nematic transitions possible. In this section, we describe simulations which have been used to study mixtures of thermotropic calamitic mesogens. 

Thermotropic cholesterics have several practical applications, some of which are very widespread. Most of the liquid crystal displays produced use either the twisted nematic (see Figure 7.3) or the supertwisted nematic electrooptical effects.6 The liquid crystal materials used in these cells contain a chiral component (effectively a cholesteric phase) which determines the twisting direction. Cholesteric LCs can also be used for storage displays utilizing the dynamic scattering mode.7 Short-pitch cholesterics with temperature-dependent selective reflection in the visible region show different colors at different temperatures and are used for popular digital thermometers.8... 

By far the most important commercial applications of nematic liquid crystals are in the a multi-billion dollar display industry. Cholesteric, or chiral nematic liquid crystals have been used in coloured guest-host displays and in thermography/ther-mochromic applications. 

It can be safely predicted that applications of liquid crystals will expand in the future to more and more sophisticated areas of electronics. Potential applications of ferroelectric liquid crystals (e.g. fast shutters, complex multiplexed displays) are particularly exciting. The only LC that can show ferroelectric property is the chiral smectic C. Viable ferroelectric displays have however not yet materialized. Antifer-roelectric phases may also have good potential in display applications. Supertwisted nematic displays of twist artgles of around 240° and materials with low viscosity which respond relatively fast, have found considerable application. Another development is the polymer dispersed liquid crystal display in which small nematic droplets ( 2 gm in diameter) are formed in a polymer matrix. Liquid crystalline elastomers with novel physical properties would have many applications. 

The first application described was as temperature sensors by using a chiral nematic liquid crystal, which displays different colors at different temperatures. It is also worth noting that many common fluids are in fact liquid crystals. Soap, for instance, is a liquid crystal, and forms a variety of liquid crystal phases depending on its concentration in water. 

Afterwards there appeared what has become the main application liquid crystal displays (LCDs) based on the twisted nematic (TN) mode. These are commonly used for flat panel displays (e.g., desk calculators). Thin film transistor (TFT) LCDs enabled a large number of segments (e.g., 640 x 1024) to be used and they had advantages like... 

The application of an electric field between the electrodes results in a realignment of the nematic liquid crystal mixture and the dichroic dye molecules parallel to the electric field resulting in a lower optical density (absorption) and, theoretically, the disappearance of colour assuming an ideal order parameter (S = 1) of the nematic liquid crystal director and the dye molecules. A residual absorption in this state gives rise to a display with a strongly coloured background and weakly coloured information. 

The application of an electric field above the threshold value results in a reorientation of the nematic liquid crystal mixture, if the nematic phase is of negative dielectric anisotropy. The optically active dopant then applies a torque to the nematic phase and causes a helical structure to be formed in the plane of the display. The guest dye molecules are also reoriented and, therefore, the display appears coloured in the activated pixels. Thus, a positive contrast display is produced of coloured information against a white background. The threshold voltage is dependent upon the elastic constants, the magnitude of the dielectric anisotropy, and the ratio of the cell gap to the chiral nematic pitch ... 

Table 4.3 Relationship between the physical properties of nematic liquid crystals and the corresponding application-relevant display properties.

Nematic gels are very interesting systems, thus deserving further study. Actually, these systems are being studied experimentally for applications. Examples are polymer dispersed liquid crystal displays are sometimes dispersed not in a polymer, but in a polymer network. Displays by means of the polymer stabilized cholesteric texture change, are also achieved in crosslinked systems. In addition, the chiral smectic phase has been obtained in such systems as well. Other types of liquid crystal gels have been applied or are expected to be applied in such devices. 

By far the most important application of liquid crystals is display devices. Liquid crystal displays (LCDs) are used in watches, calculators, and laptop computer screens, and for instrumentation in cars, ships, and airplanes. Several types of LCDs exist. In general their value is due to the fact that the orientation of the molecules in a nematic phase substance can be altered by the application of an external electric field, and that liquid crystals are anisotropic fluids, that is, fluids whose physical properties depend on the direction of measurement. It is not pure liquid crystalline compounds that are used in LCDs, but liquid crystal mixtures having optimized properties. 

Nematic liquid crystals are also oriented with their long axes parallel, but they are not separated into layers, and they behave like toothpicks in a box, maintaining their orientation but free to move in any direction. Nematic substances can be aligned by electric and magnetic fields, resulting in a number of characteristics such as the ability in some cases to be electrically switched from clear to opaque. This property gives rise to many technical applications such as in display systems. 

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