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Angular delta function

The transformation is carried out by introducing the angular delta function 52(Q li )> which is defined... [Pg.368]

The angular delta function 52 may be used to define the source S(r,0) which appears in the integral of (7.180). For this purpose we introduce... [Pg.368]

When deriving this expression for the average composition distribution, authors of paper [74] entirely neglected its instantaneous constituent, having taken (as is customary in the quantitative theory of radical copolymerization [3,84]) the Dirac delta-function < ( -X) as the instantaneous composition distribution. Its averaging over conversions, denoted hereinafter by angular brackets, leads to formula (Eq. 101). Note, this formula describes the composition distribution only provided copolymer composition falls in the interval between X(0) and X(p). Otherwise, this distribution function vanishes at all values of composition lying outside the above-mentioned interval. [Pg.194]

The delta function corresponds to Einstein s equation, which says that the kinetic energy of the emitted electron Ef equals the difference of the photon energy h(a and the energy level of the initial state of the sample, The final state is a plane wave with wave vector k, which represents the electrons emitted in the direction of k. Apparently, the dependence of the matrix element 1 j) on the direction of the exit electron, k, contains information about the angular distribution of the initial state on the sample. For semiconductors and d band metals, the surface states are linear combinations of atomic orbitals. By expressing the atomic orbital in terms of spherical harmonics (Appendix A),... [Pg.106]

Here, the angular brackets denote an ensemble average, which is the same as time average from the ergodic hypothesis. 8ap and 8,- are Kronecker delta, and 8(f — t ) is Dirac s delta function. [Pg.54]

Here, (> and /> are initial and final states of the supermolecular complex, 11 is the induced incremental polarizability (a second-rank tensor), fio and fij are unit vectors in the direction of the electric polarization of incident and scattered waves, which are often specified in the form of subscripts V and H, for vertical and horizontal, (aif = (Ej- — Ei)lh is the energy difference of initial and final state in units of angular frequency, Pi T) is the population of the initial state (a function of temperature), <5 (to) is Dirac s delta function, and the summation is over all initial and final states of the collisional complex. [Pg.441]

Bragg s law is essentially a three-dimensional case of the Dirac delta function, seen in Chapter 4, in that it specifies the diffracted radiation to be identically zero except for a discrete set of angular relationships between two variables k and ko, or more precisely, for specific values of their difference, s. Cast in terms of vectors, where d is the plane normal and has length equal to X/dhu the diffracted ray may be written as... [Pg.102]

Here angular brackets denote statistical averaging, 5 t—t ) is the delta-function which reflects mathematically the absence of correlations in the action of random... [Pg.37]

The mass-velocity term is therefore the lowest-order term from the relativistic Hamiltonian that comes from the variation of the mass with the velocity. The second relativistic term in the Pauli Hamiltonian is called the Darwin operator, and has no classical analogue. Due to the presence of the Dirac delta function, the only contributions for an atom come from s functions. The third term is the spin-orbit term, resulting from the interaction of the spin of the electron with its orbital angular momentum around the nucleus. This operator is identical to the spin-orbit operator of the modified Dirac equation. [Pg.326]

STOs have a number of features that make them attractive. The orbital has the correct exponential decay with increasing r, the angular component is hydrogenic, and the Is orbital has, as it should, a cusp at the nucleus (i.e., it is not smooth). More importantly, from a practical point of view, overlap integrals between two STOs as a function of interatomic distance are readily computed (Mulliken Rieke and Orloff 1949 Bishop 1966). Thus, in contrast to simple Huckel theory, overlap matrix elements in EHT are not assumed to be equal to the Kronecker delta, but are directly computed in every instance. [Pg.134]


See other pages where Angular delta function is mentioned: [Pg.34]    [Pg.36]    [Pg.34]    [Pg.36]    [Pg.688]    [Pg.142]    [Pg.209]    [Pg.179]    [Pg.164]    [Pg.367]    [Pg.223]    [Pg.79]    [Pg.24]    [Pg.45]    [Pg.32]    [Pg.6158]    [Pg.115]    [Pg.142]    [Pg.209]    [Pg.160]    [Pg.167]    [Pg.182]    [Pg.292]    [Pg.621]    [Pg.626]    [Pg.688]    [Pg.980]    [Pg.6157]    [Pg.23]    [Pg.45]    [Pg.150]    [Pg.169]    [Pg.169]    [Pg.29]    [Pg.57]    [Pg.153]    [Pg.79]    [Pg.334]    [Pg.116]    [Pg.359]    [Pg.812]    [Pg.43]   
See also in sourсe #XX -- [ Pg.368 ]




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