4-amino-methyl benzoate

C14H21NO2 103756-12-3) see Phenindamine methyl 4-[[iV-(l-iminopentyl)amino]methyl]benzoate (C14H20N2O2 /9S065-S0-4) see Eprosartan... 

Preparation of methyl 4-( [3-(4-cyclohexylphenoxy)benzyl]amino methyl) benzoate... 

Tritylthio)oxy]methyl benzoate Ester (TOB OR) 2- [(4-Methoxytritylthio)oxy]methyl benzoate Ester (MOB OR) 2- [Methyl(tritylthio)amino]methyl benzoate Ester (TAB OR) 2- [(4-methoxytrityl)tbio]metbylaniino -nietbyl benzoate (MAB-OR) Ester... 

Synthesis of Ethyl 4-hydroxy-3,5-bis(((2-hydroxyethyl) (pyridin-2-ylmethyl)amino)methyl)benzoate (COzEtHsLl)... 

CN 2-[[l-methyl-2-[3-(trifluoromethyl)phenyl]ethyl]amino]ethanol benzoate (ester) hydrochloride... 

Soil. In unsterilized soils, 58% of C-labeled sulfometuron-methyl degraded after 24 wk. Metabolites identified were 2,3-dihydro-3-oxobenzisosulfonazole (saccharin), methyl-2-(amino-sulfonyl) benzoate, 2-aminosulfonyl benzoic acid, 2-(((aminocarbonyl)amino)sulfonyl) benzoate, and [ C]carbon dioxide. The rate of degradation in aerobic soils was primarily dependent upon pH and soil type (Anderson and Dulka, 1985). The reported half-life in soil was approximately 4 wk (Hartley and Kidd, 1987). 

It is not possible to prepare biaryls containing a free carboxyl group directly by the diazo reaction. No biaryl is formed when (a) diazotized aniline and sodium benzoate, (b) diazotized anthranilic acid and aqueous sodium benzoate, or (c) diazotized anthranilic acid and benzene are used as components in the reaction.13 On the other hand, the reaction proceeds normally if methyl benzoate is used in reaction (a) or when methyl anthranilate replaces the anthranilic acid in (b) and in (c). The success of the diazohydroxide reaction appears to lie in the ability of the non-aqueous liquid to extract the reactive diazo compound from the aqueous layer.4 However, esters and nitriles can be prepared from esters of aromatic amino acids and cyanoanilines and also by coupling with esters of aromatic acids, and from the products the acids can be obtained by hydrolysis. By coupling N-nitrosoacetanilide with ethyl phthalate, ethyl 4-phenylphthalate (VIII) is formed in 37% yield. 

This isotherm model has been used successfully to accoimt for the adsorption behavior of numerous compounds, particularly (but not only) pairs of enantiomers on different chiral stationary phases. For example, Zhou et ah [28] foimd that the competitive isotherms of two homologous peptides, kallidin and bradyki-nine are well described by the bi-Langmuir model (see Figure 4.3). However, most examples of applications of the bi-Langmuir isotherm are found with enantiomers. lire N-benzoyl derivatives of several amino acids were separated on bovine serum albumin immobilized on silica [26]. Figure 4.25c compares the competitive isotherms measured by frontal analysis with the racemic (1 1) mixture of N-benzoyl-D and L-alanine, and with the single-component isotherms of these compounds determined by ECP [29]. Charton et al. foimd that the competitive adsorption isotherms of the enantiomers of ketoprofen on cellulose tris-(4-methyl benzoate) are well accounted for by a bi-Langmuir isotherm [30]. Fornstedt et al. obtained the same results for several jS-blockers (amino-alcohols) on immobilized Cel-7A, a protein [31,32]. 

Addition of ethyl A-benzylideneglycinate to tetraethyl ethenylidenediphosphonate in EtONa/EtOH medium produces tetraethyl 3-amino-3-(ethoxycarbonyl)-l,l-propylidenediphospho-nate in excellent yield after deprotection (95%, Scheme 8.62). A complementary procedure uses DBU in THF. Under these conditions, the reaction of methyl benzoate with tetraethyl ethenylidenediphosphonate proceeds well at 50°C to give tetraethyl 3-phenyl-3-(ethoxycarbonyl)-l,l-propylidenediphosphonate. °... 

SMB parameters Cellulose tris(p-methyl- benzoate) beads Poly(N-acryloyl-amino acid ester) silica CSP Cellulose tris(p-methylbenzoate) coated on silica (Chiralcel OJ) Amylose tris(3,5-dimethylphenyl-carbamate) coated on silica (Chiralpak AD)... 

A CIDNP study of the irradiation of (7) has shown that a-fission occurs on irradiation. The resultant radical (8) eliminates diethyl phosphoric acid and yields the radical cation (9). When irradiation is carried out in methanol this species is trapped as the ether (10). Other products are methyl benzoate and the acetal (II). A laser irradiation study of the reaction of acetophenone with amines constrained in NaY zeolites has been carried out and evidence has been collected that shows that ketyl and amino radicals are formed by hydrogen abstraction pathways. ... 

Thiazolo-[2,3-b]- and -[5,4-d]-thiazoles [C3NS-C3NS]. By means of a method similar to that of the previous reaction, thiazole-2(3//)-thione may be readily converted into anhydro-3 -hydroxy-2 -phenylthiazolo[2,3 -6 Jthiazolium hydroxide (124 X = CH). 2-Acetylamino-5-amino-4-thiocyanatothiazole cyclizes, on heating in methyl benzoate, to give the thiazolo[5,4-c/]thiazole derivative (125). ... 

See Digalloyl trioleate Benzoic acid, 2-((3-(4-(1,1-dimethylethyl) phenyl)-2-methylpropylidene) amino)-, methyl ester. See Lilial methylanthranilate Benzoic acid-n-dipropylene glycol diester. See Dipropylene glycol dibenzoate Benzoic acid, ethanolamine salt. See MEA-benzoate... 

DEN. See N-Nitrosodiethylamine Diethylamine DENA. See N-Nitrosodiethylamine Denatonium benzoate CAS 3734-33-6 (anhyd.) 86398-53-0 (monohydrate) EINECS/ELINCS 223-095-2 Synonyms Ammonium, benzyidiethyl ((2,6-xylylcarbamoyl) methyl)-, benzoate Benzenemethanaminium, N-(2-((2,6-dimethylphenyl) amino)-2-oxoethyl)-N,N-diethyl-, benzoate Benzyidiethyl [(2,6-xylylcarbomoyl) methyl] ammonium benzoate N -[2-[(2,6-Di methyl phenyI) am i no]-2-oxoethyl]-N,N-diethylbenzenemethanaminium benzoate Lignocaine benzyl benzoate Classification Organic compd. 

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