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Amine oxides infrared spectrum

The reactions of arenediazonium ions with 7V-alkyl- or 7V-arylhydroxylamines were investigated by Bamberger (1920b, and earlier papers). Mitsuhashi et al. (1965) showed that the l,3-diaryl-3-hydroxytriazenes are tautomeric with 1,3-diaryltriazene-3-oxides (Scheme 6-16). Oxidation of 1,3-diaryltriazenes with peroxybenzoic acid in ether yields the same product as that from diazonium salts and TV-arylhydroxyl-amine. The infrared spectrum of the product obtained by coupling diazotized relabeled aniline with A/-phenylhydroxylamine indicates that the diaryltriazene-oxide is the preponderant tautomer. [Pg.121]

Primary amines may be readily distinguished from secondary and tertiary analogues by the presence of two absorption bands in the infrared spectrum between 3320 and 3500 cm-1 (symmetric and antisymmetric NH str.). Secondary amines exhibit a single absorption band at about 3350 cm-1 (NH str.). In both cases deformation modes for the NH bond appear at about 1600 cm-1. There is no satisfactory absorption to allow a definitive characterisation in the case of tertiary amines. In the nuclear magnetic resonance spectrum of primary and secondary amines, the nitrogen-bound hydrogens are recognisable by their replaceability on the addition of deuterium oxide. [Pg.1215]

The pure crystalline bis(9-borabicyclo[3.3.1]nonane) melts at 148°15 and has a b.p. at 12 torr of 195°.16 The compound, in contrast to the simple tetraalkyldiboranes, has a definite structure. Its infrared spectrum shows vBH2b at 1567 cm.-1. The completely pure compound is stable at room temperature even with air access for long periods. However, storage and handling of the compound should be carried out in an inert-gas atmosphere. Water and alcohols react with it even at room temperature, with evolution of hydrogen. Alcoholysis is well suited for determination of the B—H content. The quantitative BC determination proceeds very well by a variant of the trimethyl-amine N-oxide oxidation method.13... [Pg.148]

Elimination is thought to be catalyzed by basic materials, such as magnesium oxide, which are commonly included in commercial formulations. Elimination takes place rapidly and probably occurs during milling when a diamine curing system is used.. Evidence for the presence of unsaturation in amine-treated vinylidene fluoride-hexafluoropropylene copolymer comes from the infrared spectrum of the material. [Pg.146]


See other pages where Amine oxides infrared spectrum is mentioned: [Pg.242]    [Pg.1215]    [Pg.124]    [Pg.640]    [Pg.257]    [Pg.128]    [Pg.305]    [Pg.351]   
See also in sourсe #XX -- [ Pg.285 ]




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Amines infrared spectra

Amines spectra

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