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Aluminum, sodium, calcium and rubidium on poly -phenylenevinylene

4 Aluminum, sodium, calcium and rubidium on poly(p-phenylenevinylene) [Pg.109]

The detailed results of a series of studies of the interaction of metal atoms of aluminum, sodium, calcium or rubidium with the spectros- [Pg.109]

The electronic structure of poly(p-phenylenevinylene), or PPV, has several similarities to DP7 hence DP7 is used as a model molecule for PPV34. The VEH band structure of an isolated chain of PPV, and [Pg.110]

Of particular interest is the electronic structure of PPV at lowest binding energy the region of 0 eV to about —8 eV in Fig. 7.18, where 0 in this case is the vacuum level energy. The similarity with the frontier occupied states of DP7 are as follows. In DP7, the electrons [Pg.111]

In Fig. 7.22 are shown the theoretically most energetically favourable structures of the aluminum on poly(p-phenylenevinylene) complex. These occur in the cases when (a) two aluminum atoms interact with a vinylene group and (b) two aluminum atoms interact with a [Pg.114]




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Calcium aluminum and

Calcium poly

Calcium sodium

On poly

Phenylenevinylenes

Poly 1,4-phenylenevinylene

Sodium aluminum

Sodium poly

Sodium rubidium

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