Allyl propionate

The allyl propionate exchange (Equation 4) also involves acetoxy-palladation, and thus its kinetic behavior might be expected to parallel that for vinyl propionate exchange. In its general features it is, in fact, very similar to vinyl ester exchange. The rate profile with sodium acetate concentration is of the same form as Figure 1. 

However the one important difference is that allyl propionate is much better at 7r-complex formation than is vinyl propionate. Thus the vinyl propionate kinetics in the chloride containing system do not exhibit inhibition by vinyl propionate. On the other hand allyl propionate strongly inhibits its own exchange because it forms appreciable amounts of unreactive monomeric ir complex according to Equation 11. Inhibition in the acetate system is more complicated because the equilibrium to form unreactive monomeric ir complex (Equation 27) is slow. Thus, initially only the reactive dimeric w complex is formed (Equation 26). However as the exchange proceeds, more of the monomeric ir complex is formed, and the rate of exchange gradually decreases. 

Allyl Propionate 1 14.15/C6Hio02/ colorless to pale yel liq/ s—prop glycol, veg 1 mL in 1... 

Allyl Propionate 648 (Emulsion-Polymerized Citronellyl Butyrate... 

Acetaldehyde Diethyl Acetal 2-Acetyl Thiazole Allyl Phenoxy Acetate Allyl Propionate Borneol... 

ALDC Activity, 110 Aldehyde C-7, 76 Allura Red AC, 27 Allyl Isothiocyanate, 64 Allyl Phenoxy Acetate, 64, 95 Allyl Propionate, 66, 95 L-2-Amino-5-guanidinovaleric Acid, 5 L-2-Amino-3-hydroxybutyric Acid, 60 DL-2-Amino-3-hydroxypropanoic Acid, 50... 

Acetyl Thiazole, 94 Allyl Phenoxy Acetate, 95 Allyl Propionate, 95 Aspartame-Acesulfame Salt, 96 Borneol, 96... 

Allyl Isovalerate, 452, 605, (S 1)58 4-Allyl-2-methoxyphenol, 496 4-Allyl-2-methoxyphenol Acetate, 498 Allyl Phenoxy Acetate, (S3)64, 95 Allyl Propionate, (S3)66, 95 Almond Oil, Bitter, FFPA, 19, 573 Alpha-Acetolactatedecarboxylase Activity, (S3) 104... 

The analytes used in the evaluation of ring oscillators include octanol and allyl propionate. FigCuPc has a negligible response to both these odorants, whereas the DDa6T is fairly responsive, with the drain current falling in response to both odorants. In this CMOS sensor, upon a 5-sec exposure to octanol, the oscillation... 

The order of decreasing degradative chain-transfer constants for a series of allyl esters has been given as allyl ethyl carbonate > allyl acetate > allyl propionate > allyl laurate > allyl trimethylacetate [20]. 

With a high-temperature initiator such as di-tert-butyl peroxide, copolymers of 1-octene with allyl propionate or allyl butyrate have been prepared in sealed tubes. The reaction conditions included methyl ethyl ketone as a solvent, 0.05% di-tert-butyl peroxide heated in sealed ampoules at 200°C for 4 hr. The molecular weights of the product were in the range of 600 200 [62]. 

Allyl-3-phenylacrylate. See Allyl cinnamate Allyl phosphate. See Triallyl phosphate Allyl propanoate. See Allyl propionate Allyl propionate... 

Propenyl propanoate. See Allyl propionate N-2-propenyl-2-propen-1 -amine. See Diallylamine... 

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