Allyl Phenoxy Acetate

Allyl Phenoxy Acetate 192.21/C11H1203/ colorless to pale yel liq/ ss—prop glycol 1 mL in 1... 

Allyl Phenoxy Acetate 648 Butadiene-Styrene 75/25 Rubber Citronellyl Acetate... 

Allyl Phenoxy Acetate View Flavor Chemical... 

Acetaldehyde Diethyl Acetal 2-Acetyl Thiazole Allyl Phenoxy Acetate Allyl Propionate Borneol... 

ALDC Activity, 110 Aldehyde C-7, 76 Allura Red AC, 27 Allyl Isothiocyanate, 64 Allyl Phenoxy Acetate, 64, 95 Allyl Propionate, 66, 95 L-2-Amino-5-guanidinovaleric Acid, 5 L-2-Amino-3-hydroxybutyric Acid, 60 DL-2-Amino-3-hydroxypropanoic Acid, 50... 

Acetyl Thiazole, 94 Allyl Phenoxy Acetate, 95 Allyl Propionate, 95 Aspartame-Acesulfame Salt, 96 Borneol, 96... 

Allyl Isovalerate, 452, 605, (S 1)58 4-Allyl-2-methoxyphenol, 496 4-Allyl-2-methoxyphenol Acetate, 498 Allyl Phenoxy Acetate, (S3)64, 95 Allyl Propionate, (S3)66, 95 Almond Oil, Bitter, FFPA, 19, 573 Alpha-Acetolactatedecarboxylase Activity, (S3) 104... 

Using catalysis by palladium systems, allylic halides show little tendency to add. However, with nickel(O) catalysts [e.g., Ni(cod)2] allylic halides add to norbornene. in contrast to vinyl and aryl halides9. The palladium system also catalyzes the coaddition of alkynes and benzylic halides to strained bicyclic alkenes10- u. Thus, addition of methyl 2-[3-(chloromethyl)phenoxy]acetate and optically pure (S)-l-octyn-3-ol to norbornene, norbornadiene or 7-oxanorbornene 4 leads to diastereomeric adducts 5, used as precursors of interphenylene prostaglandin endoperoxides, in 34-58% yield. No diastereomeric ratios were reported. 

C5H5)2RQ (X = chloride, formate, acetate, benzoate, methoxy, phenoxy, iodide) (Q = methyl, phenyl, phenylacetylide, allyl)... 

The photodissociative pathway was confirmed by Meyer and Hammond, who foimd that essentially no o- or p-hydroxyacetophenone was formed in the photolysis of phenyl acetate in the gas phase. Instead, all products could be rationalized by recombination of phenoxy and methyl radicals (formed from decarbonylation of acyl radicals). Similarly, a photodissociative mechanism for the photo-Claisen reaction was supported by observation of products expected from the recombination of radicals produced by photodissociation of 3-methyl-l-phenoxybut-2-ene (113, Table 12.6). In addition to phenol, products of the reaction are the rearranged ether 114, the two y,y-dimethylallyl phenols 115 and 116, and the two rearranged allyl phenols... 

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