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Alcohols, allylic with copper permanganate

Similar results are obtained with copper permanganate octahydrate, Cu(Mn04)2 8H20. Addition of this salt to a solution of 2-decanol in di-chloromethane results in an exothermic reaction and boiling of the mixture for 5 min. After 10 additional minutes at room temperature, 2-decanone is isolated in 93% yield [894. Allylic alcohols are oxidized in 84-85% yields to a, 3-unsaturated ketones after boiling in dichloromethane for 24 h [894]. [Pg.141]

NITRILO-TRIETHANOL (102-71-6) Combustible liquid or crystalline solid (flash point 354°F/179°C). Aqueous solution is an organic base. Reacts violently with strong oxidizers, permanganates, peroxides, ammonium persulfate, bromine dioxide, sulfuric acid, nitric acid. Incompatible with organic anhydrides, acrylates, alcohols, aldehydes, alkylene oxides, substituted allyls, cellulose nitrate, cresols, caprolactam solution, epichlorohydrin, ethylene dichloride, isocyanates, ketones, glycols, mercury, nitrates, phenols, vinyl acetate. Exothermic decomposition with maleic anhydride. Increases the explosive sensitivity of nitromethane. Corrodes aluminum, copper, its alloys, tin, zinc. [Pg.863]

See other pages where Alcohols, allylic with copper permanganate is mentioned: [Pg.694]    [Pg.1060]    [Pg.36]    [Pg.137]    [Pg.315]    [Pg.375]    [Pg.716]    [Pg.987]    [Pg.183]    [Pg.183]    [Pg.183]    [Pg.1118]    [Pg.1120]    [Pg.1124]    [Pg.1125]    [Pg.1164]    [Pg.1164]    [Pg.1166]    [Pg.1167]    [Pg.1186]    [Pg.1186]    [Pg.1187]    [Pg.1188]    [Pg.1189]    [Pg.1208]    [Pg.56]   
See also in sourсe #XX -- [ Pg.141 ]



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Alcohols permanganate

Alcohols, allylic with permanganates

Copper alcohols

Copper permanganate

Copper with alcohols

With Copper

With permanganate

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